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The properties of a hard-sphere fluid in contact with hard spherical and cylindrical walls are studied. Rosenfeld's density functional theory (DFT) is applied to determine the density profile and surface tension $\gamma$ for wide ranges of…

Statistical Mechanics · Physics 2007-05-23 P. Bryk , R. Roth , K. R. Mecke , S. Dietrich

This paper reviews the theoretical work undertaken using density functional theory (DFT) to explore graphene's interactions with its surroundings. We look at the impact of substrates, gate dielectrics and edge effects on the properties of…

Mesoscale and Nanoscale Physics · Physics 2012-07-31 Priyamvada Jadaun , Bhagawan R. Sahu , Leonard F. Register , Sanjay K. Banerjee

The effect of surface curvature on the law relating frictional forces F with normal load L is investigated by molecular dynamics simulations as a function of surface symmetry, adhesion, and contamination. Curved, non-adhering, dry,…

Materials Science · Physics 2009-10-31 Ludger Wenning , Martin H. Muser

Computer experiments concerning interactions between a graphite surface and the rigid pyramidal nanoasperity of a friction force microscope tip when it is brought close to and retracted from the graphitic sample are presented. Covalent…

Statistical Mechanics · Physics 2010-10-19 A. V. Khomenko , N. V. Prodanov

We investigate theoretically the adhesion and electronic properties of graphene on a muscovite mica surface using the density functional theory (DFT) with van der Waals (vdW) interactions taken into account (the vdW-DF approach). We found…

Mesoscale and Nanoscale Physics · Physics 2011-01-25 A. N. Rudenko , F. J. Keil , M. I. Katsnelson , A. I. Lichtenstein

Sodium atoms and clusters (N<5) on graphite (0001) are studied using density functional theory, pseudopotentials and periodic boundary conditions. A single Na atom is observed to bind at a hollow site 2.45 A above the surface with an…

Atomic and Molecular Clusters · Physics 2009-11-10 K. Rytkonen , J. Akola , M. Manninen

Curvature plays a central organizational role in active polymer dynamics. Using large-scale Langevin-dynamics simulations, we study active semiflexible filaments confined to smooth curved surfaces and map how curvature, bending rigidity,…

Soft Condensed Matter · Physics 2026-02-18 Giulia Janzen , Euan D. Mackay , Rastko Sknepnek , D. A. Matoz-Fernandez

We determine the structure and melting behavior of supported metallic clusters using an ab initio density-functional-based treatment of intracluster interactions and an approximate treatment of the surface as an idealized smooth plane…

Mesoscale and Nanoscale Physics · Physics 2012-10-02 S. A. Blundell , Soumyajyoti Haldar , D. G. Kanhere

Silver chromate ($\mathrm{Ag_{2}CrO_{4}}$) has attracted considerable attention in recent years due to its promising photocatalytic performance, which strongly depends on the crystallographic orientation of its exposed surfaces. A detailed…

Materials Science · Physics 2026-05-20 Augusto Facundes , Thiago T. Dorini , Theodora W. von Zuben , Miguel A. San-Miguel

We outline a Kohn-Sham-Dirac density-functional-theory (DFT) scheme for graphene sheets that treats slowly-varying inhomogeneous external potentials and electron-electron interactions on an equal footing. The theory is able to account for…

Strongly Correlated Electrons · Physics 2008-09-23 Marco Polini , Andrea Tomadin , Reza Asgari , A. H. MacDonald

We study orbital and spin-orbit proximity effects in graphene adsorbed to the Cu(111) surface by means of density functional theory (DFT). The proximity effects are caused mainly by the hybridization of graphene $\pi$ and copper d orbitals.…

Mesoscale and Nanoscale Physics · Physics 2016-04-27 Tobias Frank , Martin Gmitra , Jaroslav Fabian

In this paper we study the formation of nanodrops on curved surfaces (both convex and concave) by means of molecular dynamics simulations, where the particles interact via a Lennard-Jones potential. We find that the contact angle is not…

Fluid Dynamics · Physics 2017-07-14 Shantanu Maheshwari , Martin van der Hoef , Detlef Lohse

In this work, we investigate dispersion interactions in a selection of atomic, molecular, and molecule-surface systems, comparing high-level correlated methods with empirically-corrected density functional theory (DFT). We assess the…

Chemical Physics · Physics 2021-01-27 Tyler J. Hughes , Robert A. Shaw , Salvy P. Russo

The conductance through a quantum point contact created by a sharp and hard metal tip on the graphite surface has features which to our knowledge have not been encountered so far in metal contacts or in nanowires. In this paper we first…

Materials Science · Physics 2009-10-31 C. Kilic , H. Mehrez , S. Ciraci

The DFT/vdW-WF2s1 method based on the generation of localized Wannier functions, recently developed to include the van der Waals interactions in the Density Functional Theory and describe adsorption processes on metal surfaces by taking…

Chemical Physics · Physics 2016-04-06 Pier Luigi Silvestrelli , Alberto Ambrosetti

Surface properties of mixtures of charged platelike colloids and salt in contact with a charged planar wall are studied within density functional theory. The particles are modeled by hard cuboids with their edges constrained to be parallel…

Soft Condensed Matter · Physics 2011-09-14 Markus Bier , Ludger Harnau , S. Dietrich

We explore the pressure of active particles on curved surfaces and its relation to other interfacial properties. We use both direct simulations of the active systems as well as simulations of an equilibrium system with effective (pair)…

Soft Condensed Matter · Physics 2019-05-14 René Wittmann , Frank Smallenburg , Joseph M. Brader

Interfacial adhesion between graphene and a SiO2 substrate is studied by density functional theory (DFT) with dispersion corrections. The results demonstrate the van der Waals (vdW) interaction as the predominate mechanism for the…

Materials Science · Physics 2015-06-19 Wei Gao , Penghao Xiao , Graeme Henkelman , Kenneth M. Liechti , Rui Huang

The evolution of fractal surface structures with flattening of asperities was investigated using isotropically roughened aluminium surfaces loaded in compression. It was found that asperity amplitude, mean roughness and fractal dimension…

Soft Condensed Matter · Physics 2013-08-23 Dorian A H Hanaor , Yixiang Gan , Itai Einav

Equations of the magnetization dynamics are derived for an arbitrary curved 2D surface. General static solutions are obtained in the limit of a strong anisotropy of both signs (easy-surface and easy-normal cases). It is shown that the…

Strongly Correlated Electrons · Physics 2013-12-06 Yuri Gaididei , Volodymyr P. Kravchuk , Denis D. Sheka
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