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We use density functional theory (DFT) to study the thermodynamic stability and migration of copper ions and small clusters embedded in amorphous silicon dioxide. We perform the calculations over an ensemble of statistically independent…

Materials Science · Physics 2015-06-11 David M. Guzman , Nicolas Onofrio , Alejandro Strachan

CdTe and its alloy CdTeSe are widely used in optoelectronic devices, such as radiation detectors and solar cells, due to their superior electrical properties. However, the formation of defects and defect complexes in these materials can…

Materials Science · Physics 2024-08-29 Xiaofeng Xiang , Yijun Tong , Aaron Gehrke , Scott Dunham

A class of silicon carbide cage clusters with two carbon atoms inside the silicon cage and with high stabilities are presented. The theoretical formalism used is Hartree-Fock theory followed by second order many body perturbation theory to…

Atomic and Molecular Clusters · Physics 2009-11-10 M. N. Huda , A. K. Ray

We present a systematic methodology for the accurate calculation of defect structures in supercells which we illustrate with a study of the neutral vacancy in silicon. This is a prototypical defect which has been studied extensively using…

Materials Science · Physics 2009-11-10 M. I. J. Probert , M. C. Payne

We studied the influence of defect states on the laser excitation process in silicon using time-dependent density functional theory. We assumed two types of point defects: interstitial oxygen and silicon vacancies. We found that the…

Materials Science · Physics 2024-08-16 Tomohito Otobe , Eiyu Gushiken

We present a new efficient way to perform hybrid density functional theory (DFT) based electronic structure calculation. The new method uses an interpolative separable density fitting (ISDF) procedure to construct a set of numerical…

Computational Physics · Physics 2017-07-31 Wei Hu , Lin Lin , Chao Yang

A systematic study of the structural, electronic, and optical properties of cage-like boron clusters, with the number of constituent atoms ranging from 20 to 122, has been carried out within the framework of density-functional theory (DFT),…

Materials Science · Physics 2025-12-24 Kashinath T. Chavan , Ihsan Boustani , Alok Shukla

This paper presents a detailed study of the hydrogen adsorption properties of small silicon-lithium binary nanoclusters. The stabilities of H2 adsorbed binary clusters are assured by maximum hardness and minimum electrophilicity principle.…

Applied Physics · Physics 2022-06-28 Ankita Jaiswal , Sridhar Sahu

Using a hydrogen molecule as a test system we demonstrate how to compute the effective potential according to the formalism of the new density functional theory (DFT), in which the basic variable is the set of spherically averaged densities…

Chemical Physics · Physics 2020-09-22 K. Kokko , Á. Nagy , J. Huhtala , T. Björkman , L. Vitos

Principal structural defects in graphene layers, synthesized on a carbon-terminated face, i.e. the SiC(000) face of a 4H-SiC substrate, are investigated using microscopic methods. Results of high-resolution transmission electron microscopy…

The controlled generation and manipulation of atom-like defects in solids has a wide range of applications in quantum technology. Although various defect centres have displayed promise as either quantum sensors, single photon emitters or…

Density functional theory (DFT) can run into serious difficulties with localized states in elements such as transition metals with occupied-d states and oxygen. In contrast, Hartree-Fock (HF) method can be a better approach for such…

Materials Science · Physics 2018-08-01 Hengxin Tan , Yuanchang Li , S. B. Zhang , Wenhui Duan

Defects in silicon carbide are of intense and increasing interest for quantum-based applications due to this material's properties and technological maturity. We calculate the multi-particle symmetry adapted wave functions of the negatively…

Mesoscale and Nanoscale Physics · Physics 2016-03-23 Ö. O. Soykal , Pratibha Dev , Sophia E. Economou

We developed a framework for predicting the energies and ground state configurations of native point defects, extrinsic dopants and impurities, and defect complexes across zinc blende-phase Cd/Zn-Te/Se/S compounds, important for CdTe-based…

Materials Science · Physics 2026-05-26 Md Habibur Rahman , Maitreyo Biswas , Arun Mannodi-Kanakkithodi

The crucial step in density-corrected Hartree-Fock density functional theory (DC(HF)-DFT) is to decide whether the density produced by the density functional for a specific calculation is erroneous and hence should be replaced by, in this…

Chemical Physics · Physics 2023-09-20 Daniel Graf , Alex J. W. Thom

Density functional theory calculations have been performed on Indium nanoclusters (Inn, n= 3 to 10) to explore the relative stability among their different isomers and interaction with H2. Geometry optimizations starting from initial…

Chemical Physics · Physics 2017-06-07 Mirza Wasif Baig , Akhtar Hussain , Idrees Ahmad , Muhammad Siddiq

Molybdenum clusters, characterised by their unique structure and intriguing catalytic properties, have gained significant attention in recent years. In several existing studies density functional theory (DFT) methods have been used to find…

Materials Science · Physics 2023-10-03 Yao Wei , Lev Kantorovich

The hydrogen atom theory is developed for the de Sitter and anti de Sitter spaces on the basis of the Klein-Gordon-Fock wave equation in static coordinates. In both models, after separation of the variables, the problem is reduced to the…

Mathematical Physics · Physics 2014-12-30 O. V. Veko , K. V. Kazmerchuk , E. M. Ovsiyuk , V. M. Red'kov , A. M. Ishkhanyan

Cubic hafnia (HfO$_2$) is of great interest for a number of applications in electronics because of its high dielectric constant. However, common defects in such applications degrade the properties of hafina. We have investigated the…

Materials Science · Physics 2019-07-31 Raghuveer Chimata , Hyeondeok Shin , Anouar Benali , Olle Heinonen

The interaction of silicene with Si, C, H, O, Ti atoms along with H$_2$, H$_2$O and O$_2$ molecules are investigated and the induced functionalities thereof are analyzed using first principles density functional theory. Si adatom initially…

Materials Science · Physics 2013-11-27 V. Ongun Özçelik , S. Ciraci
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