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Graphene is an excellent candidate for the next generation of electronic materials due to the strict two-dimensionality of its electronic structure as well as the extremely high carrier mobility. A prerequisite for the development of…

Materials Science · Physics 2009-10-01 Isabella Gierz , Christian Riedl , Ulrich Starke , Christian R. Ast , Klaus Kern

Controlling the type and density of charge carriers by doping is the key step for developing graphene electronics. However, direct doping of graphene is rather a challenge. Based on first-principles calculations, a concept of overcoming…

Mesoscale and Nanoscale Physics · Physics 2011-07-26 Bing Huang , Hongjun Xiang , Su-Huai Wei

Graphene is a promising candidate to succeed silicon based devices and doping holds the key to graphene electronics. Conventional doping methods through surface functionalization or lattice modification are effective in tuning carrier…

Mesoscale and Nanoscale Physics · Physics 2016-11-16 Yangbo Zhou , Jakub Jadwiszczak , Darragh Keane , Ying Chen , Dapeng Yu , Hongzhou Zhang

Electronic devices using epitaxial graphene on Silicon Carbide require encapsulation to avoid uncontrolled doping by impurities deposited in ambient conditions. Additionally, interaction of the graphene monolayer with the substrate causes…

A method for determining the type of charge carrier, electron or hole, which is transferred from metal contacts to graphene, is described. The Dirac point is found to shift toward more negative (positive) gate voltages for electron (hole)…

Materials Science · Physics 2011-02-16 Ryo Nouchi , Tatsuya Saito , Katsumi Tanigaki

Combining scanning tunneling microscopy and angle-resolved photoemission spectroscopy, we demonstrate how to tune the doping of epitaxial graphene from p to n by exploiting the structural changes that occur spontaneously on the Ge surface…

Doping is one of the most prominent techniques to alter properties of a given material. Herein, the influence of the electron- and hole-doping on the selected superconducting properties of graphene are considered. In details, the…

Superconductivity · Physics 2023-04-12 Ewa A. Drzazga-Szczęśniak , Adam Z. Kaczmarek

We perform a phenomenological analysis of the problem of the electronic doping of a graphene sheet by deposited transition metal atoms, which aggregate in clusters. The sample is placed in a capacitor device such that the electronic doping…

Strongly Correlated Electrons · Physics 2015-03-19 Jaime E. Santos , Nuno M. R. Peres , Joao M. B. Lopes dos Santos , Antonio H. Castro Neto

Controlling the metal-insulator transition in graphene-based material is a crucial topic as it directly impacts its potential applications. Inspired by recent experiments, we study the effects of doping and bond disorder on metal-insulator…

Strongly Correlated Electrons · Physics 2024-01-24 Kaiyi Guo , Ying Liang , Tianxing Ma

We investigate the doping of AA-stacked graphene bilayers. Applying a mean field theory at zero temperature we find that, at half-filling, the bilayer is an antiferromagnetic insulator. Upon doping, the homogeneous phase becomes unstable…

Strongly Correlated Electrons · Physics 2013-03-05 A. O. Sboychakov , A. L. Rakhmanov , A. V. Rozhkov , Franco Nori

Controlling doping is key to optimizing graphene for high-speed electronic and optoelectronic devices. However, its impact on non-equilibrium carrier lifetimes remains debated. Here, we systematically tune the doping level of…

Mesoscale and Nanoscale Physics · Physics 2025-04-09 Leonard Weigl , Johannes Gradl , Peter Richter , Thomas Seyller , Domenica Convertino , Stiven Forti , Camilla Coletti , Isabella Gierz

We investigate molecular adsorption doping by electron withdrawing NO2 and electron donating NH3 on epitaxial graphene grown on C-face SiC substrates. Amperometric measurements show conductance changes upon introduction of molecular…

Materials Science · Physics 2012-01-24 B. K. Daas , W. K. Nomani , K. M. Daniels , T. S. Sudarshan , Goutam Koley , M. V. S. Chandrashekhar

Atomic-scale fabrication is an outstanding challenge and overarching goal for the nanoscience community. The practical implementation of moving and fixing atoms to a structure is non-trivial considering that one must spatially address the…

Epitaxial graphene on SiC(0001) suffers from strong intrinsic n-type doping. We demonstrate that the excess negative charge can be fully compensated by non-covalently functionalizing graphene with the strong electron acceptor…

This work reports information on the transience of hole doping in epitaxial graphene devices when nitric acid is used as an adsorbent. Under vacuum conditions, desorption processes are monitored by electrical and spectroscopic means to…

We study the effects of metallic doping on the electronic properties of graphene using density functional theory in the local density approximation in the presence of a local charging energy (LDA+U). The electronic properties are sensitive…

Materials Science · Physics 2009-11-13 B. Uchoa , C. -Y. Lin , A. H. Castro Neto

While graphene is a semi-metal, recently synthesized hydrogenated graphene called graphane, turns out to be an insulator. We have probed the metal insulator Transition in graphene-graphane system within the framework of density functional…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Prachi Chandrachud , Bhalchandra S. Pujari , D. G. Kanhere

In recent years, various doping methods for epitaxial graphene have been demonstrated through atom substitution and adsorption. Here we observe by angle-resolved photoemission spectroscopy (ARPES) a coupling-induced Dirac cone…

While the mechanical distortions change the electronic properties of graphene significantly, the effects of electronic manipulation on its mechanical properties have not been known. Using first-principles calculation methods, we show that,…

Materials Science · Physics 2013-02-20 S. J. Woo , Young-Woo Son

We simulate the optical and electrical responses in gallium-doped graphene. Using density functional theory with a local density approximation, we simlutate the electronic band structure and show the effects of impurity doping (0-3.91\%) in…

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