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The structural, optical and magnetic properties of the Zn1-xMnxO (0 < x < 0.05) thin films synthesized by sol-gel technique have been analyzed in the light of modification of the electronic structure and disorder developed in the samples…

Materials Science · Physics 2015-06-11 R. Karmakar , S. K. Neogi , Aritra Banerjee , S. Bandyopadhyay

Anatase Ti0.96Co0.04O2 films were grown epitaxially on SrTiO3 (001) substrates by using plused laser deposition with in-situ reflection high-energy electron diffraction. The oxygen partial pressure, PO2, during the growth was systematically…

Materials Science · Physics 2009-11-07 D. H. Kim , J. S. Yang , K. W. Lee , S. D. Bu , T. W. Noh , S. -J. Oh , Y. -W. Kim , J. -S. Chung , H. Tanaka , H. Y. Lee , T. Kawai

In recent years there has been an intense search for room temperature ferromagnetism in doped dilute semiconductors, which have many potentially applications in spintronics and optoelectronics. We report here the unexpected observation of…

Cobalt-doped ZnO (Co2+:ZnO) films were studied by magnetic circular dichroism (MCD) spectroscopy. A broad 300 K ferromagnetic MCD signal was observed between 1.4 and 4.0 eV after introducing shallow donor states by exposure of paramagnetic…

Materials Science · Physics 2007-05-23 Kevin R. Kittilstved , Jialong Zhao , William K. Liu , J. Daniel Bryan , Daniel R. Gamelin

First principles calculations of the O surfaces of Co-ZnO show that substitutional Co ions develop large magnetic moments which long-range coupling depends on their mutual distance. The local spin polarization induced at the O atoms is…

Materials Science · Physics 2009-11-13 N. Sanchez , S. Gallego , M. C. Munoz

In the last decade, transition-metal-doped ZnO has been intensively investigated as a route to room-temperature diluted magnetic semiconductors (DMSs). However, the origin for the reported ferromagnetism in ZnO-based DMS remains…

Materials Science · Physics 2009-08-05 Shengqiang Zhou , K. Potzger , J. von Borany , R. Groetzschel , W. Skorupa , M. Helm , J. Fassbender

BiFeO$_3$ (BFO) shows both ferroelectricity and magnetic ordering at room temperature but its ferromagnetic component, which is due to spin canting, is negligible. Substitution of transition-metal atoms such as Co for Fe is known to enhance…

The observed correlation of oxygen vacancies and room temperature ferromagnetic ordering in Co doped ZnO1-o nanoparticles reported earlier (Naeem et al Nanotechnology 17, 2675-2680) has been further explored by transport and optical…

Materials Science · Physics 2007-12-10 M. Naeem , S. K. Hasanain , A. Mumtaz

We have studied the electronic structure and the magnetism of Cu-doped ZnO nanowires, which have been reported to show ferromagnetism at room temperature [G. Z. Xing ${et}$ ${al}$., Adv. Mater. {\bf 20}, 3521 (2008).], by x-ray…

We observe remarkably strong room temperature ferromagnetism (~1.5 Bohr Magneton/Mn) in optically transparent Mn(II)-doped indium tin oxide (ITO) films. The nanocrystalline films with average grain size 10-22 nm and thickness 150-350 nm are…

Materials Science · Physics 2009-11-13 Susmita Kundu , Dipten Bhattacharya , Jiten Ghosh , Pintu Das , Prasanta K. Biswas

We have studied the influence of intrinsic and extrinsic defects in the magnetic and electrical transport properties of Co-doped ZnO thin films. X ray absorption measurements show that Co substitute Zn in the ZnO structure and it is in the…

In this work, we studied cobalt nitride (Co-N) thin films deposited using a dc magnetron sputtering method at a substrate temperature (\Ts) of 523\,K. We find that independent of the reactive gas flow (\pn) used during sputtering, the…

Materials Science · Physics 2017-02-15 Nidhi Pandey , Mukul Gupta , Rachana Gupta , Sujay Chakravarty , Neeraj Shukla , Anton Devishvili

We report on the results of x-ray absorption (XAS), x-ray magnetic circular dichroism (XMCD), and photoemission experiments on {\it n}-type Zn$_{1-x}$Co$_x$O ($x=0.05$) thin film, which shows ferromagnetism at room temperature. The XMCD…

We report a surfactant assisted synthesis of Mn doped ZnO polycrystalline samples showing robust room temperature ferromagnetism as characterized by X-ray diffraction analysis, Transmission Electron Microscopy, Electron Paramagnetic…

Materials Science · Physics 2011-11-09 O. D. Jayakumar , I. K. Gopalakrishnan , C. Sudakar , R. M. Kadam , S. K. Kulshreshtha

We have studied the electronic structure of Zn$_{0.9}$Fe$_{0.1}$O nano-particles, which have been reported to show ferromagnetism at room temperature, by x-ray photoemission spectroscopy (XPS), resonant photoemission spectroscopy (RPES),…

The effect of electron doping on the structural, transport, and magnetic properties of Mn (IV) - rich Ca1-xYxMnO3 (x < 0.2) samples have been investigated using neutron diffraction, neutron depolarization, magnetization and resistivity…

Materials Science · Physics 2016-02-09 Neetika Sharma , A. Das , C. L. Prajapat , Amit Kumar , M. R. Singh

We report the successful synthesis of ZnO:Cu thin films doped with holes, resulting in room temperature ferromagnetism. Hole doping is achieved by As-diffusion from the GaAs substrate into ZnO films, assisted by thermal annealing. The…

Mesoscale and Nanoscale Physics · Physics 2011-06-30 Abhinav Pratap Singh , B. -G. Park , Ik-Jae Lee , Kyu Joon Lee , Myung-Hwa Jung , Jinhee Kim , J. -Y. Kim

Compressed Pr0.5Ca0.5MnO3 films (250nm) deposited on LaAlO3 have been studied by Electron Spin Resonance technique under high frequency and high magnetic field. We show evidences for the presence of a ferromagnetic phase (FM) embedded in…

Strongly Correlated Electrons · Physics 2009-11-10 S. de Brion , G. Storch , G. Chouteau , A. Janossy , W. Prellier , E. Rauwel Buzin

Magnetometry, x-ray, and neutron scattering have been used to study the structural and magnetic properties of a TbMnO3 thin film grown on a [001] SrTiO3 substrate by pulsed laser deposition. Although bulk TbMnO3 is a low temperature…

Materials Science · Physics 2009-11-13 B. J. Kirby , D. Kan , A. Luykx , M. Murakami , D. Kundaliya , I. Takeuchi

Cobalt and silver co-doping has been undertaken in ZnO thin films grown by pulsed laser deposition in order to investigate the ferromagnetic properties in ZnO-based diluted magnetic materials and to understand the eventual relation between…