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Using evolutionary crystal structure prediction algorithm USPEX, we showed that at pressures of the Earth's lower mantle CaAl2O4 is the only stable calcium aluminate. At pressures above 7.0 GPa it has the CaFe2O4-type structure and space…

Materials Science · Physics 2022-10-31 Ekaterina I. Marchenko , Artem R. Oganov , Efim A. Mazhnik , Nikolay N. Eremin

We report first-principles calculations of the frequency dependent linear and second-order optical properties of the two probable extended-solid phases of CO$_2$--V, i.e. $I\bar42d$ and $P2_12_12_1$. Compared to the parent $Cmca$ phase the…

Materials Science · Physics 2009-11-10 S. Sharma , J. K. Dewhurst , C. Ambrosch-Draxl

Spatial profiles of the pressure have been measured in atomic Fermi gases with primarily 2D kinematics. The in-plane motion of the particles is confined by a gaussian-shape potential. The two-component deeply-degenerate Fermi gases are…

Quantum Gases · Physics 2016-09-05 Kirill Martiyanov , Tatiana Barmashova , Vasiliy Makhalov , Andrey Turlapov

We have determined the crystal structures and superconducting transition temperatures of La1.48Nd0.4Sr0.12CuO4 under nearly hydrostatic pressures in diamond anvil cells to 5.0 GPa and 19.0 GPa, respectively. Synchrotron x-ray powder…

Room temperature angle-dispersive x-ray diffraction measurements on zircon-type YPO4 and ErPO4, and monazite-type GdPO4, EuPO4, NdPO4, and LaPO4 were performed in a diamond-anvil cell up to 27 GPa using neon as pressure-transmitting medium.…

Materials Science · Physics 2010-05-04 R. Lacomba-Perales , D. Errandonea , Y. Meng , M. Bettinelli

Thin films of Co-TiO2 are deposited on silicon and quartz substrates using Pulse Laser Deposition (PLD) process at various oxygen partial pressures ranging from 6.6 x 10-3 Pascals (Pa) to 53 Pa. Crystal structure, transport and magnetic…

Materials Science · Physics 2007-05-23 Bakhtyar Ali , Abdul K Rumaiz , S. Ismat Shah , Arif Ozbay , Edmund R Nowak

The simple alkali metal Na, that crystallizes in a body-centred cubic structure at ambient pressure, exhibits a wealth of complex phases at extreme conditions as found by experimental studies. The analysis of the mechanism of stabilization…

Materials Science · Physics 2009-09-25 V F Degtyareva , O Degtyareva

Computational searches for stable and metastable structures of water ice and other H:O compositions at TPa pressures have led us to predict that H$_2$O decomposes into H$_2$O$_2$ and a hydrogen-rich phase at pressures of a little over 5…

Materials Science · Physics 2013-06-25 Chris J. Pickard , Miguel Martinez-Canales , Richard J. Needs

Changes in atomic coordination numbers at high pressures are fundamental to condensed-matter physics because they initiate the emergence of unexpected structures and phenomena. Silicon is capable of forming eight-, nine-, and…

Materials Science · Physics 2021-07-08 Shicong Ding , Pan Zhang , Kang Yang , Cailong Liu , Jian Hao , Wenwen Cui , Jingming Shi , Yinwei Li

We present a theoretical study of the impact of oxygen diffusion in oxide crystals on metal dopants ionic state and the conduction type under thermal equilibrium. Oxygen vacancy formation acting as a shallow, double-electronic donor is…

Materials Science · Physics 2018-06-06 Misha Sinder , Zeev Burshtein , Joshua Pelleg

SrAl2Si2 crystallizes into either a semimetallic, CaAl2Si2-type, \alpha phase or a superconducting, BaZn2P2-type, \beta phase. We explore possible \alpha --Pc;Tc--> \beta transformations by employing pressure- and temperature-dependent…

Two-dimensional electron systems with fascinating properties exist in multilayers of standard semiconductors, on helium surfaces, and in oxides. Compared to the two-dimensional (2D) electron gases of semiconductors, the 2D electron systems…

Strongly Correlated Electrons · Physics 2016-06-22 J. Zabaleta , V. S. Borisov , R. Wanke , H. O. Jeschke , S. C. Parks , B. Baum , A. Teker , T. Harada , K. Syassen , T. Kopp , N. Pavlenko , R. Valentí , J. Mannhart

The temperature dependence of the real and imaginary parts of magnetic susceptibility of YBa2Cu3O7-{\delta} superconducting thin films were researched at the electron irradiation with the energy of 2{\cdot}10<4> eV in the magnetic field of…

Superconductivity · Physics 2012-06-26 Viktor O. Ledenyov , Dimitri O. Ledenyov , Oleg P. Ledenyov

A novel allotrope of carbon with $P2/m$ symmetry was identified during an \emph{ab-initio} minima-hopping structural search which we call $M10$-carbon. This structure is predicted to be more stable than graphite at pressures above 14.4 GPa…

The structure of La$_{1-x}$Ca$_{x}$MnO$_{3}$ solid solutions (x=0, 0.25, 0.50, 0.67, 1) under high pressure (up to 40-45 GPa) has been investigated by synchrotron X-ray powder diffraction (XRD) in order to characterize their volume…

Strongly Correlated Electrons · Physics 2007-05-23 A. Sani , C. Meneghini , S. Mobilio , Sugata Ray , D. D. Sarma , J. A. Alonso

Atomic metallic hydrogen with a lattice with FDDD symmetry is shown to have a stable phase under hydrostatic compression in the range of pressure 350 - 500 GPa.

Superconductivity · Physics 2017-08-23 Nikolay Degtyarenko , Evgeny Mazur , Constantin Grishakov

Old and novel layered structures are attracting increasing attention for their physical, electronic, and frictional properties. SiS$_2$, isoelectronic to SiO$_2$, CO$_2$ and CS$_2$, is a material whose phases known experimentally up to 6…

Chemical Physics · Physics 2016-09-13 Dušan Plašienka , Roman Martoňák , Erio Tosatti

The high-pressure properties of fluorine and chlorine are not yet well understood because both are highly reactive and volatile elements, which has made conducting diamond anvil cell and x-ray diffraction experiments a challenge. Here we…

Materials Science · Physics 2020-08-12 Mark A. Olson , Shefali Bhatia , Paul Larson , Burkhard Militzer

The phase diagram of binary mixtures of particles interacting via a pair potential of parallel dipoles is computed at zero temperature as a function of composition and the ratio of their magnetic susceptibilities. Using lattice sums, a rich…

Soft Condensed Matter · Physics 2009-11-13 Lahcen Assoud , René Messina , Hartmut Löwen

The application of high pressure can fundamentally modify the crystalline and electronic structures of elements as well as their chemical reactivity, which could lead to the formation of novel materials. Here, we explore the reactivity of…

Chemical Physics · Physics 2017-05-12 Yang-Mei Chen , Hua Y. Geng , Xiao-Zhen Yan , Zi-Wei Wang , Xiang-Rong Chen , Qiang Wu