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X-ray resonant scattering has been used to measure the magnetic order of the Dy ions below 40K in multiferroic DyMn$_{2}$O$_{5}$. The magnetic order has a complex behaviour. There are several different ordering wavevectors, both…

Strongly Correlated Electrons · Physics 2008-04-21 R. A. Ewings , A. T. Boothroyd , D. F. McMorrow , D. Mannix , H. C. Walker , B. M. R. Wanklyn

The magnetic order, spin dynamics, and crystal structure of the multiferroic Sr0.56Ba0.44MnO3 have been investigated using neutron and x-ray scattering. Ferroelectricity develops at TC=305 K with a polarization of 4.2 microC/cm2 associated…

Single crystal neutron diffraction reveals two distinct components to the magnetic ordering in geometrically frustrated SrEr$_2$O$_4$. One component is a long-range ordered ${\bf k}=0$ structure which appears below $T_N = 0.75$ K. Another…

Strongly Correlated Electrons · Physics 2014-08-15 T. J. Hayes , G. Balakrishnan , P. P. Deen , P. Manuel , L. C. Chapon , O. A. Petrenko

Magnetism in the orthorhombic metal CaFe$_4$As$_3$ was examined through neutron diffraction for powder and single crystalline samples. Incommensurate (${\bm q}_{\rm m}\approx (0.37-0.39)\times{\bm b}^{\ast}$) and predominantly…

Apart from being so far the only known binary multiferroic compound, CuO has a much higher transition temperature into the multiferroic state, 230 K, than any other known material in which the electric polarization is induced by spontaneous…

(NH$_4$)$_2$[FeCl$_5$(H$_2$O)], a member of the family of antiferromagnetic $A_2$[Fe$X_5$(H$_2$O)] compounds ($X$ = halide ion, $A$ = alkali metal or ammonium ion) is classified as a new multiferroic material. We report the onset of…

Strongly Correlated Electrons · Physics 2015-06-16 M. Ackermann , D. Brüning , T. Lorenz , P. Becker , L. Bohatý

Cu3Nb2O8 is an unusual multiferroic compound that undergoes a series of magnetic ordering at low temperatures. Concurrent development of electric polarization has been reported at TN1 ~25 K corresponding to a non-collinear helicoidal…

Strongly Correlated Electrons · Physics 2015-06-22 G. Sharma , J. Saha , S. D. Kaushik , V. Siruguri , S. Patnaik

We report remarkable multiferroic effects in polycrystalline Bi2Fe4O9. High-resolution X-ray diffraction shows that this compound has orthorhombic structure. Magnetic measurements confirm an antiferromagnetic transition around 260 K. A…

Materials Science · Physics 2009-11-13 A. K. Singh , S. D. Kaushik , Brijesh Kumar , A. Venimadhav , P. K. Mishra , V. Siriguri , S. Patnaik

Electron microdiffraction study of phase transition in La2/3Ca1/3MnO3 revealed temperature dependent (h+1/2,0,l) diffraction spots. Their intensity peaks at Tc. Quantitative electron diffraction intensity analysis shows that they come from…

Strongly Correlated Electrons · Physics 2009-10-31 J. M. Zuo , J. Tao

We report an infrared reflection spectroscopy study of La$_{1/2}$Ca$_{1/2}$MnO$_3$ over a broad frequency range and temperature interval which covers the transitions from the high temperature paramagnetic to ferromagnetic and, upon further…

Strongly Correlated Electrons · Physics 2009-11-10 A. P. Litvinchuk , M. N. Iliev , M. Pissas , C. W. Chu

We report coupling between magnetic and electric orders for antiferromagnetic polycrystalline FeVO4 in which magnetism-induced polarization has been recently found in noncollinear antiferromagnetic state below the second antiferromagnetic…

Materials Science · Physics 2009-11-17 Bohdan Kundys , Christine Martin , Charles Simon

The unusual magnetic properties of a novel low-dimensional quantum ferrimagnet Cu$_2$Fe$_2$Ge$_4$O$_{13}$ are studied using bulk methods, neutron diffraction and inelastic neutron scattering. It is shown that this material can be described…

Strongly Correlated Electrons · Physics 2009-11-10 T. Masuda , A. Zheludev , B. Grenier , S. Imai , K. Uchinokura , E. Ressouche , S. Park

The crystal and magnetic structure of multiferroic LiFe(WO$_4$)$_2$ were investigated by temperature and magnetic-field dependent specific heat, susceptibility and neutron diffraction experiments on single crystals. Considering only the two…

Strongly Correlated Electrons · Physics 2021-04-21 S. Biesenkamp , D. Gorkov , D. Brüning , A. Bertin , T. Fröhlich , X. Fabrèges , A. Gukasov , M. Meven , P. Becker , L. Bohatý , T. Lorenz , M. Braden

Motivated by the recent observations of incommensurate magnetic order and electric polarization in YBaCuFeO5 up to temperatures TN2 as high as 230K [1,2] we report here for the first time a model for the incommensurate magnetic structure of…

Current scenario in multiferroics demands a breakthrough discovery of promising materials after BiFeO3. Recently, the controversial discovery of room temperature ferroelectricity (FE) in SmFeO3 [PRL 107, 117201 (2011); 113, 217203 (2014)]…

Materials Science · Physics 2020-01-01 K. Dey , A. Indra , S. Mukherjee , S. Majumdar , J. Strempfer , O. Fabelo , E. Mossou , 5 T. Chatterji , S. Giri

Using a joint approach of density functional theory and model calculations, we demonstrate that a prototypical charge ordered half-doped manganite, La$_{1/2}$Ca$_{1/2}$MnO$_3$ is multiferroic. The combination of a peculiar charge-orbital…

Materials Science · Physics 2010-07-15 Gianluca Giovannetti , Sanjeev Kumar , Jeroen van den Brink , Silvia Picozzi

Using a combination of Density Functional Theory, mean-field analysis and exact diagonalization calculations we reveal the emergence of a dimerized charge ordered state in TMTTF$_2$-PF$_6$ organic crystal. The interplay between charge and…

Strongly Correlated Electrons · Physics 2015-03-19 Gianluca Giovannetti , Sanjeev Kumar , Jean-Paul Pouget , Massimo Capone

We have observed a diffuse component to the low-energy magnetic excitation spectrum of stripe-ordered La5/3Sr1/3NiO4 probed by neutron inelastic scattering. The diffuse scattering forms a square pattern with sides parallel and perpendicular…

Strongly Correlated Electrons · Physics 2009-11-10 A. T. Boothroyd , P. G. Freeman , D. Prabhakaran , A. Hiess , M. Enderle , J. Kulda , F. Altorfer

In this contribution to the special issue on multiferroics we focus on multiferroicity driven by different forms of charge ordering. We will present the generic mechanisms by which charge ordering can induce ferroelectricity in magnetic…

Materials Science · Physics 2011-07-22 Jeroen van den Brink , Daniel I. Khomskii

The high-pressure synthesized quasi-one-dimensional compounds NaMn$_2$O$_4$ and Li$_{0.92}$Mn$_2$O$_4$ are both antiferromagnetic insulators, and here their atomic and magnetic structures were investigated using neutron powder diffraction.…

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