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The electronic structure of epitaxial films on LaCoO3(LCO) has been studied within first principle electronic structure calculations. A spin state transition is found to take place as a function of lattice strain which freezes in the…

Strongly Correlated Electrons · Physics 2009-01-05 Kapil Gupta , Priya Mahadevan

Ferromagnetic insulators play a crucial role in the development of low-dissipation quantum magnetic devices for spintronics. Epitaxial LaCoO3 thin film is a prominent ferromagnetic insulator, in which the robust ferromagnetic ordering…

Materials Science · Physics 2022-06-17 Dongwon Shin , Sangmoon Yoon , Sehwan Song , Sungkyun Park , Ho Nyung Lee , Woo Seok Choi

Using spectroscopic ellipsometry, we studied the optical conductivity of LaCoO$_3$ with various degrees of strain. The optical response of the compressively strained \lco\ film is qualitatively similar to the one of the unstrained LaCoO$_3$…

Strongly Correlated Electrons · Physics 2025-03-13 F. Abadizaman , M. Kiaba , A. Dubroka

The origin of insulating ferromagnetism in epitaxial LaCoO3 films under tensile strain remains elusive despite extensive research efforts have been devoted. Surprisingly, the spin state of its Co ions, the main parameter of its…

Using soft x-ray absorption spectroscopy and magnetic circular dichroism at the Co-$L_{2,3}$ edge we reveal that the spin state transition in LaCoO$_{3}$ can be well described by a low-spin ground state and a triply-degenerate high-spin…

The ferromagnetic properties of epitaxial La$_{0.5}$Sr$_{0.5}$CoO$_3$ thin films have been studied. The magnetic transition is affected by both strain and finite thickness. We have used a series of films of different thickness and on…

Materials Science · Physics 2009-11-13 Changkun Xie , J. I. Budnick , B. O. Wells , J. C. Woicik

We investigated the magnetic transitions in BiFeO$_3$ at low temperature (5-300 K) and observed nearly 90$^o$ rotation of magnetic domains (imaged by vertical magnetic force microscopy) across 150 K in an epitaxial thin film of thickness…

The spin transition in LaCoO3 is investigated by temperature-dependent resonant soft X-ray emission spectroscopy near the Co 2p absorption edges. This element-specific technique is more bulk sensitive with respect to the temperature induced…

Strongly Correlated Electrons · Physics 2011-12-30 M. Magnuson , S. M. Butorin , C. Såthe , J. Nordgren , P. Ravindran

The spin states of Co$^{3+}$ ions in perovskite-type LaCoO$_3$, governed by complex interplay between the electron-lattice interactions and the strong electron correlations, still remain controversial due to the lack of experimental…

Strongly Correlated Electrons · Physics 2018-05-23 Y. Yokoyama , Y. Yamasaki , M. Taguchi , Y. Hirata , K. Takubo , J. Miyawaki , Y. Harada , D. Asakura , J. Fujioka , M. Nakamura , H. Daimon , M. Kawasaki , Y. Tokura , H. Wadati

Epitaxial strain imposed in complex oxide thin films by heteroepitaxy is recognized as a powerful tool for identifying new properties and exploring the vast potential of materials performance. A particular example is LaCoO3, a zero spin,…

We investigate the structure and magnetic properties of thin films of the LaCoO$_{3}$ compound. Thin films are deposited by pulsed laser deposition on various substrates in order to tune the strain from compressive to tensile. Single-phase…

Strongly Correlated Electrons · Physics 2015-05-18 A. D. Rata , A. Herklotz , L. Schultz , K. Doerr

With local density approximation + Hubbard $U$ (LDA+$U$) calculations, we show that the ferromagnetic (FM) insulating state observed in tensile-strained LaCoO$_3$ epitaxial thin films is most likely a mixture of low-spin (LS) and high-spin…

Strongly Correlated Electrons · Physics 2022-05-20 Han Hsu , Peter Blaha , Renata M. Wentzcovitch

LaCoO3 thin films grown under epitaxial tensile strain exhibit a robust ferromagnetic insulating state that is absent in the bulk. Despite many studies, both experimental and computational, the microscopic origin of this phenomenon is not…

Materials Science · Physics 2026-04-08 Ali Barooni , Murod Mirzhalilov , Mohit Randeria , Patrick M. Woodward , Maryam Ghazisaeidi

Epitaxial strain in transition-metal oxides can induce dramatic changes in electronic and magnetic properties. A recent study on the epitaxially strained SrCoO$_3$ thin films revealed persistent ferromagnetism even across a metal-insulator…

The impact of epitaxial strain on the structural, electronic, and thermoelectric properties of p-type transparent Sr-doped LaCrO3 thin films has been investigated. For this purpose, high-quality fully strained La0.75Sr0.25CrO3 (LSCO)…

SrTiO$_3$ thin films were used as a model system to study the effects of strain and epitaxial constraint on structural phase transitions of perovskite films. The basic phenomena revealed will apply to a variety of important structural…

Other Condensed Matter · Physics 2007-05-23 Feizhou He , B. O. Wells , S. M. Shapiro

The structural properties of LaCoO3 were studied by means of high-resolution neutron powder diffraction in the temperature range 5<T<1000 K. Changes of the Co+3 spin states in this temperature interval are shown to affect not only the unit…

Strongly Correlated Electrons · Physics 2009-11-07 Paolo G. Radaelli , Sang-Wook Cheong

We report an investigation of transverse Hall resistance and longitudinal resistance on Pt thin films sputtered on epitaxial LaCoO$_3$ (LCO) ferromagnetic insulator films. The LaCoO$_3$ films were deposited on several single crystalline…

Strongly Correlated Electrons · Physics 2015-10-14 T. Shang , Q. F. Zhan , H. L. Yang , Z. H. Zuo , Y. L. Xie , Y. Zhang , L. P. Liu , B. M. Wang , Y. H. Wu , S. Zhang , Run-Wei Li

We present a study of the structure, the electric resistivity, the magnetic susceptibility, and the thermal expansion of La$_{1-x}$Eu$_x$CoO$_3$. LaCoO$_3$ shows a temperature-induced spin-state transition around 100 K and a metal-insulator…

Strongly Correlated Electrons · Physics 2009-11-10 J. Baier , S. Jodlauk , M. Kriener , A. Reichl , C. Zobel , H. Kierspel , A. Freimuth , T. Lorenz

Epitaxial strain in thin films can yield surprising magnetic and electronic properties not accessible in bulk. One materials system destined to be explored in this direction are orthoferrites with two intertwined spin systems where strain…

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