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Present paper is a review of results, obtained in the framework of semiclassical approach in nanophysics. Semiclassical description, based on Electrostatics and Thomas-Fermi model was applied to calculate dimensions of the electronic shell…

Materials Science · Physics 2011-03-01 Yuri Kornyushin

Spin-polarized DFT has been used to perform a comprehensive study of the geometric structures and electronic properties for isolated M4X4 nano-clusters between their two stable isomers - a planar rhombus-like 2D structure and a cubane-like…

Mesoscale and Nanoscale Physics · Physics 2015-12-29 Soumendu Datta , Badiur Rahaman

A crystalline form of LiBC is known which has been predicted to be superconducting, with a Tc comparable to that of MgB_2. In both compounds, superconductivity is enhanced by the presence of two electronic bands, one of which is close to a…

Atomic and Molecular Clusters · Physics 2007-05-23 G. M. Lombardo , A. Grassi , G. Forte , G. G. N. Angilella , R. Pucci , N. H. March

The atomic and band structures of the (6,0) zigzag carbon nanotube at its axial elongation are calculated by semiempirical molecular orbital and by tight-binding methods. The ground state of the nanotube is found to have a Kekule structure…

The atomic structure, stacking sequences and electronic structure of folded graphene nanoribbons (FGNRs) are investigated by first-principles calculations. It reveals that the common configurations of all FGNRs are racket-like structures…

Mesoscale and Nanoscale Physics · Physics 2016-01-20 Wenjin Yin , Yuee Xie , Li-Min Liu , Yuanping Chen , Ru-Zhi Wang , Xiao-Lin Wei , Leo Lau

In this work, we use density functional theory (DFT) to investigate the structural and electronic properties of B$_7$Y$_2$ clusters -- boron frameworks doped with two yttrium atoms. Our results show that the most stable configuration adopts…

Materials Science · Physics 2025-04-29 Peter Ludwig Rodríguez-Kessler

We present all-electron density functional study of the geometry, electronic structure, vibrational modes, polarizabilities as well as the infrared and Raman spectra of fullerene-like arsenic cages. The stability of As$_n$ cages for sizes…

Atomic and Molecular Clusters · Physics 2009-11-10 Tunna Baruah , Mark R. Pederson , Rajendra R. Zope , M. R. Beltran

By means of ab initio calculations within the density functional theory, we have found that B80 fullerenes can condense to form stable face-centered-cubic fcc solids. It is shown that when forming a crystal, B80 cages are geometrically…

Materials Science · Physics 2009-11-13 Qing-Bo Yan , Qing-Rong Zheng , Gang Su

We aim to understand the formation of cloud condensation nuclei in oxygen-rich substellar atmospheres by calculating fundamental properties of the energetically most favorable vanadium oxide molecules and clusters. A hierarchical…

Earth and Planetary Astrophysics · Physics 2024-10-02 Helena Lecoq-Molinos , David Gobrecht , J. P. Sindel , Christiane Helling , Leen Decin

Graphynes and graphdiynes are generic names for families of two-dimensional carbon allotropes, where acetylenic groups connect benzenoid-like hexagonal rings, with the co-existence of sp and sp2 hybridized carbon atoms. The main differences…

Mesoscale and Nanoscale Physics · Physics 2018-03-02 Daniel Solis , Daiane D. Borges , Cristiano F. Woellner , Douglas S. Galvao

We studied the structural and the electronic properties of ionized and neutral small Au clusters via plane wave pseudopotential calculations. All except the anionic heptamer favor one-dimensional zigzag structures or two-dimensional…

Materials Science · Physics 2016-02-17 Byeong June Min , Won Chul Shin , Jae Ik Park

The electronic structure of finite-length armchair carbon nanotubes has been studied using several ab-initio and semi-empirical quantum computational techniques. The additional confinement of the electrons along the tube axis leads to the…

Materials Science · Physics 2007-05-23 Alain Rochefort , Dennis R. Salahub , Phaedon Avouris

Fundamental theories and models of many-body physics can be probed in experiments on ultracold atoms held in place by electromagnetic fields. In particular, of considerable interest are systems under curved confinement, since they can yield…

Quantum Gases · Physics 2026-03-06 Fabio Cinti , Matteo Ciardi , Santi Prestipino , Giuseppe Pellicane

We study theoretically the equilibrium structure, as well as the response under external load, of characteristic carbon-based materials. The materials considered include diamond, amorphous carbon (a-C), ``amorphous diamond'' and…

The freezing behavior of gold nanoclusters was studied by employing molecular dynamics simulations based on a semi-empirical embedded-atom method. Investigations of the gold nanoclusters revealed that, just after freezing, ordered…

Atomic and Molecular Clusters · Physics 2009-11-07 H. -S. Nam , Nong M. Hwang , B. D. Yu , J. -K. Yoon

We study the phase behaviour of a binary mixture of colloidal hard spheres and freely-jointed chains of beads using Monte Carlo simulations. Recently Panagiotopoulos and coworkers predicted [Nat. Commun. 5, 4472 (2014)] that the hexagonal…

Soft Condensed Matter · Physics 2016-08-24 John R Edison , Tonnishtha Dasgupta , Marjolein Dijkstra

Confinement can have a considerable effect on the behavior of particle systems, and is therefore an effective way to discover new phenomena. A notable example is a system of identical bosons at low temperature under an external field…

Quantum Gases · Physics 2024-01-10 Matteo Ciardi , Fabio Cinti , Giuseppe Pellicane , Santi Prestipino

Using a systematic search algorithm we identify several types of point defects in the boron fullerene with 80 atoms. All these point defect leave the cage structure intact. In addition the cage structure is also very stable with respect to…

Materials Science · Physics 2009-02-11 Kuo Bao , Stefan Goedecker , Luigi Genovese , Alexey Neelov , S. Alireza Ghasemi , Thierry Deutsch

Based on first-principles calculations we show that the oxidation of ultrathin films of Ca$_2$N electrides, electrenes, drives a hexagonal$\rightarrow$tetragonal structural transition. The ground state configuration of the oxidized…

Materials Science · Physics 2020-05-06 Pedro H. Souza , José E. Padilha , Roberto H. Miwa

This paper presents a new highly stable periodic approximant to the Al-based F-type icosahedral quasicrystals, i-Al-Pd-TM (TM=transition metals). The structure of this intermetallic Al-Pd-Cr-Fe compound is determined ab initio using…

Materials Science · Physics 2013-04-23 Nobuhisa Fujita , Hikari Takano , Akiji Yamamoto , An-Pang Tsai