English
Related papers

Related papers: Comparison of three different self-interaction cor…

200 papers

Perdew-Zunger self-interaction correction (PZ-SIC) offers a route to remove self-interaction errors on an orbital-by-orbital basis. A recent formulation of PZ-SIC by Pederson, Ruzsinszky and Perdew proposes restricting the unitary…

Chemical Physics · Physics 2021-12-07 Carlos M. Diaz , Tunna Baruah , Rajendra R. Zope

By combining the Self-Interaction Correction (SIC) with pseudopotential perturbation theory, the role of self-interaction errors inherent to the Local Density Approximation (LDA) to Density Functional Theory is estimated in the…

mtrl-th · Physics 2009-10-28 Jorge M. Pacheco , Walter Ekardt , Wolf-Dieter Schoene

Recently developed locally scaled self-interaction correction (LSIC) is a one-electron SIC method that, when used with a ratio of kinetic energy densities (z$_\sigma$) as iso-orbital indicator, performs remarkably well for both…

Chemical Physics · Physics 2024-01-31 Rajendra R. Zope , Yoh Yamamoto , Tunna Baruah

We calculate the electronic structure of several atoms and small molecules by direct minimization of the Self-Interaction Corrected Local Density Approximation (SIC-LDA) functional. To do this we first derive an expression for the gradient…

Condensed Matter · Physics 2009-10-28 S. Goedecker , C. J. Umrigar

We extend some of the well established self-interaction correction (SIC) schemes of density-functional theory to the case of systems with noncollinear magnetism. Our proposed SIC schemes are tested on a set of molecules and metallic…

Chemical Physics · Physics 2023-10-31 Nicolas Tancogne-Dejean , Martin Lüders , Carsten A. Ullrich

We present applications of the recently introduced ``Generalized SIC-Slater'' scheme which provides a simple Self-Interaction Correction approximation in the framework of the Optimized Effective Potential. We focus on the computation of…

Quantum Physics · Physics 2015-05-13 J. Messud , Z. Wang , P. M. Dinh , P. -G. Reinhard , E. Suraud

The Perdew-Zunger self-interaction correction cures many common problems associated with semilocal density functionals, but suffers from a size-extensivity problem when Kohn-Sham orbitals are used in the correction. Fermi-L\"{o}wdin-orbital…

Computational Physics · Physics 2017-06-30 Zeng-hui Yang , Mark R. Pederson , John P. Perdew

Accurate prediction of spin-state energy difference is crucial for understanding the spin crossover (SCO) phenomena and is very challenging for the density functional approximations, especially for the local and semi-local approximations,…

Chemical Physics · Physics 2023-02-22 Selim Romero , Tunna Baruah , Rajendra R. Zope

Perdew-Zunger self-interaction correction (PZSIC) reintroduces an exact constraint to approximate density functional theory (DFT), but can paradoxically degrade performance and is not systematically improvable. We use the Adiabatic…

Chemical Physics · Physics 2023-05-16 Benjamin G. Janesko

The approximate atomic self-interaction corrections (ASIC) method to density functional theory is put to the test by calculating the exchange interaction for a number of prototypical materials, critical to local exchange and correlation…

Materials Science · Physics 2009-11-13 A. Akande , S. Sanvito

We present a fully variational locally scaled self-interaction corrected (SIC) energy functional using complex optimal orbitals. This represents an important milestone for fully variational SIC energy functionals, which have been shown to…

(Semi)-local density functional approximations (DFAs) suffer from self-interaction error (SIE). When the first ionization energy (IE) is computed as the negative of the highest-occupied orbital (HO) eigenvalue, DFAs notoriously…

Despite the success of density functional approximations (DFAs) in describing the electronic properties of many-electron systems, the most widely used approximations suffer from self-interaction errors (SIE) that limit their predictive…

Chemical Physics · Physics 2020-01-08 Yoh Yamamoto , Carlos M. Diaz , Luis Basurto , Koblar A. Jackson , Tunna Baruah , Rajendra R. Zope

Fermi-L\"owdin orbital self-interaction-correction (FLOSIC) method uses symmetric orthogonalized Fermi orbitals as localized orbitals in one-electron SIC schemes. In FLOSIC, a set of Fermi orbital descriptors (FOD) that define the FLOs is…

Chemical Physics · Physics 2025-08-08 Selim Romero , Yoh Yamamoto , Tunna Baruah , Rajendra R. Zope

Self-consistent calculations using the Perdew-Zunger self-interaction correction (PZ-SIC) to local density and gradient dependent energy functionals are presented for the binding energy and equilibrium geometry of small molecules as well as…

Atomic and Molecular Clusters · Physics 2013-08-30 Simon Klüpfel , Peter Klüpfel , Hannes Jónsson

We propose a method to obtain an improved Hamiltonian (action) for the Ising universality class in three dimensions. The improved Hamiltonian has suppressed leading corrections to scaling. It is obtained by tuning models with two coupling…

High Energy Physics - Lattice · Physics 2009-10-31 M. Hasenbusch , K. Pinn , S. Vinti

Local-spin-density functional calculations may be affected by severe errors when applied to the study of magnetic and strongly-correlated materials. Some of these faults can be traced back to the presence of the spurious self-interaction in…

Materials Science · Physics 2009-11-10 Alessio Filippetti , Nicola Spaldin

The pairing interaction is one of the most important contribution of the residual interaction and then, it is of major importance for the study of many-body systems. One can get solutions of the pairing Hamiltonian throught the…

Nuclear Theory · Physics 2017-10-23 R. M. Id Betan

Similarity transformation of the Hubbard Hamiltonian using a Gutzwiller correlator leads to a non-Hermitian effective Hamiltonian, which can be expressed exactly in momentum-space representation, and contains three-body interactions. We…

Strongly Correlated Electrons · Physics 2019-08-12 Werner Dobrautz , Hongjun Luo , Ali Alavi

The configuration interaction (CI) method for calculating the exact eigenstates of a quantum-mechanical few-body system is problematic when applied to particles interacting through contact forces. In dimensions higher than one the approach…

Mesoscale and Nanoscale Physics · Physics 2017-03-28 M. Rontani , G. Eriksson , S. Åberg , S. M. Reimann