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Markov chain Monte Carlo (MCMC) simulation methods are widely used to assess parametric uncertainties of hydrologic models conditioned on measurements of observable state variables. However, when the model is CPU-intensive and…

Optimization and Control · Mathematics 2018-06-18 Jiangjiang Zhang , Jun Man , Guang Lin , Laosheng Wu , Lingzao Zeng

A process, carried out in a stepwise manner, becomes quasi-static when the number of intermediate steps tends to infinity. Usually, the net entropy production approaches zero under this limiting condition. Hence, such cases are termed…

Chemical Physics · Physics 2009-11-30 Debasis Mukhopadhyay , Kamal Bhattacharyya

Standard MCMC methods can scale poorly to big data settings due to the need to evaluate the likelihood at each iteration. There have been a number of approximate MCMC algorithms that use sub-sampling ideas to reduce this computational…

Computation · Statistics 2020-09-29 Joris Bierkens , Paul Fearnhead , Gareth Roberts

A new computational method for finite-temperature properties of strongly correlated electrons is proposed by extending the variational Monte Carlo method originally developed for the ground state. The method is based on the path integral in…

Strongly Correlated Electrons · Physics 2016-06-10 Kensaku Takai , Kota Ido , Takahiro Misawa , Youhei Yamaji , Masatoshi Imada

We propose a new approach concerning the introduction of time-irreversibility in statistical mechanics. It is based on a transition function defined in terms of path integral and verifying a time-irreversible equation. We show first how…

Statistical Mechanics · Physics 2015-03-02 J. P. Badiali

We propose a new Markov chain Monte Carlo method in which trial configurations are generated by evolving a state, sampled from a prior distribution, using a Markov transition matrix. We present two prototypical algorithms and derive their…

Statistical Mechanics · Physics 2023-01-09 Joel Mabillard , Isha Malhotra , Bortolo Matteo Mognetti

A generalization of the Gibbs entropy postulate is proposed based on the BBGKY hierarchy as the nonequilibrium entropy for a system of N interacting particles. This entropy satisfies the basic principles of thermodynamics in the sense that…

Statistical Mechanics · Physics 2007-05-23 A. Perez-Madrid

Starting at the mesoscopic level with a general formulation of stochastic thermodynamics in terms of Markov jump processes, we identify the scaling conditions that ensure the emergence of a (typically nonlinear) deterministic dynamics and…

Statistical Mechanics · Physics 2025-05-26 Gianmaria Falasco , Massimiliano Esposito

We present a generic reweighting method for nonequilibrium Markov processes. With nonequilibrium Monte Carlo simulations at a single temperature, one calculates the time evolution of physical quantities at different temperatures, which…

Statistical Mechanics · Physics 2009-11-10 Hwee Kuan Lee , Yutaka Okabe

By monitoring the sampling of states with different magnetizations in transition matrix procedures a family of accurate and easily implemented techniques are constructed that automatically control the variation of the temperature or energy…

Statistical Mechanics · Physics 2017-05-24 David Yevick , Yong Hwan Lee

We prove explicit, i.e. non-asymptotic, error bounds for Markov chain Monte Carlo methods. The problem is to compute the expectation of a function f with respect to a measure {\pi}. Different convergence properties of Markov chains imply…

Probability · Mathematics 2020-04-07 Daniel Rudolf

The canonical form of Matrix Product States (MPS) and the associated fundamental theorem, which relates different MPS representations of a state, are the theoretical framework underlying many of the analytical results derived through MPS,…

Quantum Physics · Physics 2018-04-17 Gemma De las Cuevas , J. Ignacio Cirac , Norbert Schuch , David Perez-Garcia

In terms of the stochastic process of quantum-mechanical version of Markov chain Monte Carlo method (the MCMC), we analytically derive macroscopically deterministic flow equations of order parameters such as spontaneous magnetization in…

Disordered Systems and Neural Networks · Physics 2015-05-18 Jun-ichi Inoue

In the context of Bayesian inversion for scientific and engineering modeling, Markov chain Monte Carlo sampling strategies are the benchmark due to their flexibility and robustness in dealing with arbitrary posterior probability density…

Computation · Statistics 2021-12-07 Han Lu , Mohammad Khalil , Thomas Catanach , Jiefu Chen , Xuqing Wu , Xin Fu , Cosmin Safta , Yueqin Huang

Markov chain Monte Carlo is an inherently serial algorithm. Although likelihood calculations for individual steps can sometimes be parallelized, the serial evolution of the process is widely viewed as incompatible with parallelization,…

Computation · Statistics 2013-12-31 Douglas N. VanDerwerken , Scott C. Schmidler

We point out that the high-q Potts model on a regular lattice at its transition temperature provides an example of a non-robust - in the sense recently proposed by Pemantle and Steif- phase transition.

Mathematical Physics · Physics 2015-06-26 Aernout C. D. van Enter

We consider the Microcanonical Variational Principle for the vortex system in a bounded domain. In particular we are interested in the thermodynamic properties of the system in domains of second kind, i.e. for which the equivalence of…

Mathematical Physics · Physics 2023-12-27 Dario Benedetto , Emanuele Caglioti , Margherita Nolasco

We examine stochastic processes that are used to model nonequilibrium processes (e.g, pulling RNA or dragging colloids) and so deliberately violate detailed balance. We argue that by combining an information-theoretic measure of…

Statistical Mechanics · Physics 2009-11-13 R. A. Blythe

Thermodynamic process at zero-entropy-production (EP) rate has been regarded as a reversible process. A process achieving the Carnot efficiency is also considered as a reversible process. Therefore, the condition, `Carnot efficiency at…

Statistical Mechanics · Physics 2020-02-12 Jae Sung Lee , Sang Hoon Lee , Jaegon Um , Hyunggyu Park

Even though irreversibility is one of the major hallmarks of any real life process, an actual understanding of irreversible processes remains still mostly semiempirical. In this paper we formulate a thermodynamic uncertainty principle for…

Statistical Mechanics · Physics 2021-03-17 Rudolf Hanel , Petr Jizba