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We investigate the phase diagram of a self-avoiding walk model of a 3-star polymer in two dimensions, adsorbing at a surface and being desorbed by the action of a force. We show rigorously that there are four phases: a free phase, a…

Statistical Mechanics · Physics 2019-05-14 C J Bradly , E J Janse van Rensburg , A L Owczarek , S G Whittington

We investigate the existence and location of the surface phase known as the "Surface-Attached Globule" (SAG) conjectured previously to exist in lattice models of three-dimensional polymers when they are attached to a wall that has a short…

Soft Condensed Matter · Physics 2009-11-13 A. L. Owczarek , A. Rechnitzer , J. Krawczyk , T. Prellberg

We investigate the effects of topological constraints (entanglements) on two dimensional polymer loops in the dense phase, and at the collapse transition (Theta point). Previous studies have shown that in the dilute phase the entangled…

Soft Condensed Matter · Physics 2009-11-10 Andreas Hanke , Ralf Metzler , Paul G. Dommersnes , Yacov Kantor , Mehran Kardar

There have been separate studies of the polymer collapse transition, where the collapse was induced by two different types of attraction. In each case, the configurations of the polymer were given by the same subset of random walks being…

Statistical Mechanics · Physics 2015-06-17 Andrea Bedini , Aleksander L Owczarek , Thomas Prellberg

Interest in the protein folding problem has motivated a wide range of theoretical and experimental studies of the kinetics of the collapse of flexible homopolymers. In this Paper a phenomenological model is proposed for the kinetics of the…

Soft Condensed Matter · Physics 2009-10-31 A. Halperin , Paul M. Goldbart

We study how solidification of model freely rotating polymers under athermal quasistatic compression varies with their bond angle $\theta_0$. All systems undergo two discrete, first-order-like transitions: entanglement at $\phi =…

Soft Condensed Matter · Physics 2020-05-01 Joseph D. Dietz , Robert S. Hoy

We use complete enumeration and Monte Carlo techniques to study two-dimensional self-avoiding polymer chains with quenched ``charges'' $\pm 1$. The interaction of charges at neighboring lattice sites is described by $q_i q_j$. We find that…

Soft Condensed Matter · Physics 2009-10-30 Ido Golding , Yacov Kantor

We study an ensemble of branched polymers which are embedded on other branched polymers. This is a toy model which allows us to study explicitly the reaction of a statistical system on an underlying geometrical structure, a problem of…

High Energy Physics - Theory · Physics 2015-06-26 Bergfinnur Durhuus , Thordur Jonsson

In this work we present the general phase behavior of short tubelike flexible polymers. The geometric thickness constraint is implemented through the concept of the global radius of curvature. We use sophisticated Monte Carlo sampling…

Soft Condensed Matter · Physics 2009-07-20 Thomas Vogel , Thomas Neuhaus , Michael Bachmann , Wolfhard Janke

We explore the effect of an attractive interaction between parallel-aligned polymers, which are perpendicularly grafted on a substrate. Such an attractive interaction could be due to, e.g., reversible cross-links. The competition between…

Soft Condensed Matter · Physics 2013-10-08 Panayotis Benetatos , Eugene M. Terentjev , Annette Zippelius

We study the phase behavior of a symmetric binary polymer blend which is confined into a thin film. The film surfaces interact with the monomers via short range potentials. We calculate the phase behavior within the self-consistent field…

Statistical Mechanics · Physics 2009-10-31 M. Mueller , E. V. Albano , K. Binder

We show that by coupling complex three-state systems to branched-polymer like ensembles we can obtain models with gamma-string different from one half. It is also possible to study the interpolation between dynamical and crystalline graphs…

High Energy Physics - Lattice · Physics 2009-10-30 Joao D. Correia , Behrouz Mirza , John F. Wheater

A polymer folding model on the square lattice is constructed with attractive contact interactions of strength 1/c^2, 0<c<1. The corresponding model on a dynamical random lattice, with freely fluctuating co-ordination number at each vertex,…

Condensed Matter · Physics 2016-08-31 S. Dalley

The phase diagram for a two-dimensional self-avoiding walk model on the square lattice incorporating attractive short-ranged interactions between parallel sections of walk is derived using numerical transfer matrix techniques. The model…

Statistical Mechanics · Physics 2009-11-07 D. P. Foster , F. Seno

The dynamical response of a tethered semiflexible polymer with self-attractive interactions and subjected to an external force field is numerically investigated by varying stiffness and self-interaction strength. The chain is confined in…

Soft Condensed Matter · Physics 2022-11-09 A. Lamura

Recent work on the mechanism of polymer crystallization has led to a proposal for the mechanism of thickness selection which differs from those proposed by the surface nucleation theory of Lauritzen and Hoffman and the entropic barrier…

Condensed Matter · Physics 2007-05-23 Jonathan Doye , Daan Frenkel

We examine the phase transition of polymer adsorption as well as the underlying kinetics of polymer binding from dilute solutions on a structureless solid surface. The emphasis is put on the properties of regular multiblock copolymers,…

Soft Condensed Matter · Physics 2009-09-03 A. Milchev , V. Rostiashvili , S. Bhattacharya , T. Vilgis

We report molecular dynamics simulations of a system of repulsive, polymer-tethered colloidal particles. We use an explicit polymer model to explore how the length and the behavior of the polymer (ideal or self-avoiding) affect the ability…

Soft Condensed Matter · Physics 2015-05-14 Behnaz Bozorgui , Maya Sen , William L. Miller , Josep C. Pamies , Angelo Cacciuto

We present a minimal dynamical model for randomly branched isotropic polymers, and we study this model in the framework of renormalized field theory. For the swollen phase, we show that our model provides a route to understand the well…

Statistical Mechanics · Physics 2015-05-27 Hans-Karl Janssen , Olaf Stenull

The structural arrest of a polymeric suspension might be driven by an increase of the cross--linker concentration, that drives the gel transition, as well as by an increase of the polymer density, that induces a glass transition. These…

Statistical Mechanics · Physics 2014-06-20 Nagi Khalil , Antonio Coniglio , Antonio de Candia , Annalisa Fierro , Massimo Pica Ciamarra
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