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Boltzmann's entropy is slightly modified to make it suitable for discussing phase transitions in finite systems. As an example it is shown that the pendulum undergoes a second order phase transition when passing from a vibrational to a…

Statistical Mechanics · Physics 2015-06-24 Jan Naudts

The relationship between the intrinsic motion of gravity, light, and time is explored in terms of the principles of entropy, causality, energy, and symmetry conservation. A conceptual mechanism for gravity and the gravitational connection…

General Relativity and Quantum Cosmology · Physics 2009-07-02 John A. Gowan

Herein we consider various concepts of entropy as measures of the complexity of phenomena and in so doing encounter a fundamental problem in physics that affects how we understand the nature of reality. In essence the difficulty has to do…

Statistical Mechanics · Physics 2007-05-23 Paolo Allegrini , Martina Giuntoli , Paolo Grigolini , Bruce J. West

To address the observation of Max Born (M. Born 1969) that the Newton's second law can emerge from a purely statistical perspective, we derive the evolution equation about the statistical distribution for dilute gas based solely on…

Statistical Mechanics · Physics 2024-10-23 Hong Yuan , Chang-Pu Sun

In classical phenomenological thermodynamics the first and second laws can be regarded as independent statements. Statistical mechanics provides a microscopic substratum that explains thermodynamics in probabilistic terms via a microstate…

Statistical Mechanics · Physics 2007-05-23 A. Plastino , E. M. F. Curado

The aim of the present paper is to present a careful and accessible discussion of the formal aspects of Boltzmann-Gibbs and Tsallis entropies. We begin with a brief overview of Boltzmann-Gibbs entropy, highlighting its main properties and…

Statistical Mechanics · Physics 2025-10-23 Kelvin dos Santos Alves , Rogerio Teixeira Cavalcanti

The basic notions of statistical mechanics (microstates, multiplicities) are quite simple, but understanding how the second law arises from these ideas requires working with cumbersomely large numbers. To avoid getting bogged down in…

Physics Education · Physics 2015-02-27 Thomas A. Moore , Daniel V. Schroeder

Statistical mechanics descriptions of the second law of thermodynamics generally imply point-like particles driven by a dissipative overall mechanism for their simultaneous time-evolution. As the number of involved particles grows larger,…

General Physics · Physics 2016-02-16 Hans R. Moser

We investigate the behavior in $N$ of the $N$--particle entropy functional for Kac's stochastic model of Boltzmann dynamics, and its relation to the entropy function for solutions of Kac's one dimensional nonlinear model Boltzmann equation.…

Probability · Mathematics 2008-08-26 E. A. Carlen , M. C. Carvalho , J. Le Roux , M. Loss , C. Villani

In classical Hamiltonian theories, entropy may be understood either as a statistical property of canonical systems, or as a mechanical property, that is, as a monotonic function of the phase space along trajectories. In classical mechanics,…

General Relativity and Quantum Cosmology · Physics 2016-10-14 Marius Oltean , Luca Bonetti , Alessandro D. A. M. Spallicci , Carlos F. Sopuerta

I present a generalization of the Ehrenfest urn model that is aimed at simulating the approach to equilibrium in a dilute gas. The present model differs from the original one in two respects: 1) the two boxes have different volumes and are…

Statistical Mechanics · Physics 2009-11-10 S. Prestipino

The present paper is meant to give a simple introduction to the problem of the connection between microscopic dynamics and statistical laws. For sake of simplicity, we mostly refer to non-dissipative dynamics, since dissipation adds…

Statistical Mechanics · Physics 2014-10-02 Sergio Chibbaro , Lamberto Rondoni , Angelo Vulpiani

Meixner's historical remark in 1969 "... it can be shown that the concept of entropy in the absence of equilibrium is in fact not only questionable but that it cannot even be defined...." is investigated from today's insight. Several…

Statistical Mechanics · Physics 2018-10-17 Wolfgang Muschik

Entropic dynamics is a framework for defining dynamical systems that is aligned with the principles of information theory. In an entropic dynamics model for motion on a statistical manifold, we find that the rate of changes for expected…

Dynamical Systems · Mathematics 2021-07-15 Pedro Pessoa

We review with a tutorial scope the information theory foundations of quantum statistical physics. Only a small proportion of the variables that characterize a system at the microscopic scale can be controlled, for both practical and…

Statistical Mechanics · Physics 2007-05-23 R. Balian

It exists a large class of systems for which the traditional notion of extensivity breaks down. From experimental examples we induce two general hypothesis concerning such systems. In the first the existence of an internal coordinate system…

Statistical Mechanics · Physics 2015-03-09 J-P. Badiali , A. El Kaabouchi

In nonlinear dynamics, basins of attraction link a given set of initial conditions to its corresponding final states. This notion appears in a broad range of applications where several outcomes are possible, which is a common situation in…

Unlike most other laws of nature, the second law of thermodynamics is of a statistical nature, according to Boltzmann, meaning that its reliability arises from the vast number of particles present in macroscopic systems. This means that…

General Physics · Physics 2019-07-22 Ian von Hegner

Many theoretical expressions of dissipation along non-equilibrium processes have been proposed. However, they have not been fully verified by experiments. Especially for systems strongly interacting with environments the connection between…

Statistical Mechanics · Physics 2019-12-03 Ketan Goyal , Xian He , Ryoichi Kawai

The development of stochastic thermodynamics during the last decades prompted the discovery of novel nonequilibrium relations refining our understanding of the second law in small fluctuating systems and its connection with information…

Physics and Society · Physics 2025-11-19 Luis Irisarri , Lucas Trigal , Raúl Toral , Gonzalo Manzano