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Related papers: Intrinsic Hyperpolarizabilities as a Figure of Mer…

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Because of the potentially large number of important applications of nonlinear optics, researchers have expended a great deal of effort to optimize the second-order molecular nonlinear-optical response, called the hyperpolarizability. The…

Optics · Physics 2015-03-17 David S. Watkins , Mark G. Kuzyk

Device figures of merit are commonly employed to assess bulk material properties for a particular device class, yet these properties ultimately originate in the linear and nonlinear susceptibilities of the material which are not independent…

Optics · Physics 2016-11-03 Sean Mossman , Rick Lytel , Mark G. Kuzyk

The scaling of the fundamental limits of the second hyperpolarizability is used to define the intrinsic second hyperpolarizability, which aids in identifying material classes with ultralarge nonlinear-optical response per unit of molecular…

Optics · Physics 2016-11-03 Javier Perez-Moreno , Shoresh Shafei , Mark G. Kuzyk

Plasmonic chirality exhibits great potential for novel nanooptical devices due to the generation of a strong chiroptical response. Previous reports on plasmonic chirality explanations are mainly based on phase retardation and coupling. We…

Mesoscale and Nanoscale Physics · Physics 2016-05-05 Li Hu , Yingzhou Huang , Yurui Fang

The development of high-performance multifunctional polymer-based electronic circuits is a major step towards future flexible electronics. Here, we demonstrate a tunable approach to fabricate such devices based on rationally designed…

We optimize the first and second intrinsic hyperpolarizabilities for a 1D piecewise linear potential dressed with Dirac delta functions for $N$ non-interacting electrons. The optimized values fall rapidly for $N>1$, but approach constant…

Chemical Physics · Physics 2016-08-24 Christopher J. Burke , Joseph Lesnefsky , Rolfe G. Petschek , Timothy J. Atherton

We report on a series of chromophores that have been synthesized with a modulated conjugation path between donor and acceptor. Hyper-Rayleigh scattering measurements of the best molecule show an enhanced intrinsic hyperpolarizability that…

Chemical Physics · Physics 2009-11-13 Javier Pérez-Moreno , Yuxia Zhao , Koen Clays , Mark G. Kuzyk

We demonstrate a coherent quantum measurement for the determination of the degree of polarization (DOP). This method allows to measure the DOP in the presence of fast polarization state fluctuations, difficult to achieve with the typically…

Quantum Physics · Physics 2009-11-10 M. Legre , M. Wegmuller , N. Gisin

In-line polarimeters perform non-destructive polarization measurements of optical signals, and play a critical role in monitoring and controlling the polarization environment in for example optical networks. While current in-line…

Optics · Physics 2015-12-10 J. P. Balthasar Müller , Kristjan Leosson , Federico Capasso

The dielectric properties of molecules or nanostructures are usually modified in a complex manner, when assembled into a condensed phase. We propose a first-principles method to compute polarizabilities of sub-entities of solids and…

Chemical Physics · Physics 2018-09-10 Ding Pan , Marco Govoni , Giulia Galli

The effective quasistatic conductivity of composite polymeric electrolytes is studied in terms of a hard-core--penetrable-layer model. Used to incorporate the interface phenomena (such as amorphization of the polymer matrix around filler…

Materials Science · Physics 2019-11-05 M. Ya. Sushko , A. K. Semenov

Previous studies have used numerical methods to optimize the hyperpolarizability of a one-dimensional quantum system. These studies were used to suggest properties of one-dimensional organic molecules, such as the degree of modulation of…

Optics · Physics 2015-05-18 Urszula B. Szafruga , Mark G. Kuzyk , David S. Watkins

We discuss a novel application of matter wave interferometry to characterize the scalar optical polarizability of molecules at 532 nm. The interferometer presented here consists of two material absorptive gratings and one central optical…

Recent years have seen increased interest to plasmonic enhancement of nonlinear optical effects, yet there remains an uncertainty of what are the limits of this enhancement. We present a simple and physically transparent theory of plasmonic…

Optics · Physics 2017-07-26 Jacob B Khurgin , Greg Sun

We use numerical optimization to study the properties of (1) the class of one-dimensional potential energy functions and (2) systems of point charges in two-dimensions that yield the largest hyperpolarizabilities, which we find to be within…

Optics · Physics 2009-11-13 Juefei Zhou , Urszula B. Szafruga , David S. Watkins , Mark G. Kuzyk

Photonic molecules, i.e. artificial structures composed of coherently coupled optical cavities, are paradigmatic systems for investigating fundamental phenomena across photonics, quantum optics and topological physics. In recent years,…

Optics · Physics 2026-05-06 Tiantong Li , Katia Gallo

The studies of topological phases of matter have been extended from condensed matter physics to photonic systems, resulting in fascinating designs of robust photonic devices. Recently, higher-order topological insulators (HOTIs) have been…

Mesoscale and Nanoscale Physics · Physics 2019-06-19 Bi-Ye Xie , Guang-Xu Su , Hong-Fei Wang , Hai Su , Xiao-Peng Shen , Peng Zhan , Ming-Hui Lu , Zhen-Lin Wang , Yan-Feng Chen

In this paper we present the parameterization of a new interionic potential for stoichiometric, reduced and doped CeO$_2$. We use a dipole-polarizable potential (DIPPIM) and optimize its parameters by fitting them to a series of DFT…

Small organic molecules with a {\pi}-conjugated system that consists of only a few double or triple bonds can have significantly smaller optical excitation energies when equipped with donor- and acceptor groups, which raises the quantum…

Materials Science · Physics 2024-05-17 Ivan Biaggio

Non-classical joint measurements can hugely improve the efficiency with which certain figures of merit of quantum systems are measured. We use such a measurement to determine a particular figure of merit, the purity, for a polarization…

Quantum Physics · Physics 2009-11-13 R. B. A. Adamson , L. K. Shalm , A. M. Steinberg
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