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The first discussion of basis sets consisting of exponentially decaying Coulomb Sturmian functions for modelling electronic structures is presented. The proposed basis set construction selects Coulomb Sturmian functions using separate upper…

Chemical Physics · Physics 2019-01-23 Michael F. Herbst , James Emil Avery , Andreas Dreuw

Relativistic correction to the Coulomb interaction is considered for strongly correlated electron orbitals. The atomic representation of the Coulomb-Breit interaction and its physical origin are clarified, to generalize a concept of the…

Strongly Correlated Electrons · Physics 2023-11-10 Shintaro Hoshino

Range-separated density-functional theory is an alternative approach to Kohn-Sham density-functional theory. The strategy of range-separated density-functional theory consists in separating the Coulomb electron-electron interaction into…

Chemical Physics · Physics 2015-02-20 Odile Franck , Bastien Mussard , Eleonora Luppi , Julien Toulouse

Using the newly developed VASP2WANNIER90 interface we have constructed maximally localized Wannier functions (MLWFs) for the e_g states of the prototypical Jahn-Teller magnetic perovskite LaMnO3 at different levels of approximation for the…

Strongly Correlated Electrons · Physics 2015-06-03 C. Franchini , R. Kovacik , M. Marsman , S. Sathyanarayana Murthy , J. He , C. Ederer , G. Kresse

We report density functional theory (DFT) band structure calculations on the transparent conducting oxides CuAlO2, CuGaO2, CuInO2 and CuCrO2. The use of the hybrid functional sX-LDA leads to considerably improved electronic properties…

Strongly Correlated Electrons · Physics 2013-04-10 Roland Gillen , John Robertson

We report a first-principles projector augmented wave (PAW) study on Na$_{0.5}$CoO$_2$. With the sodium ion ordered insulating phase being identified in experiments, pure density functional calculations fail to predict an insulating ground…

Materials Science · Physics 2007-05-23 Zhenyu Li , Jinlong Yang , J. G. Hou , Qingshi Zhu

Ab initio calculation of the electronic properties of materials is a major challenge for solid state theory. Whereas the experience of forty years has proven density functional theory (DFT) in a suitable, e.g. local approximation (LDA) to…

Strongly Correlated Electrons · Physics 2009-11-13 K. Held , O. K. Andersen , M. Feldbacher , A. Yamasaki , Y. -F. Yang

We use the Gutzwiller variational theory to calculate the ground-state phase diagram and quasi-particle bands of LaOFeAs. The Fe3d--As4p Wannier-orbital basis obtained from density-functional theory defines the band part of our eight-band…

Strongly Correlated Electrons · Physics 2014-10-07 Tobias Schickling , Florian Gebhard , Jörg Bünemann , Lilia Boeri , Ole K. Andersen , Werner Weber

The ground-state properties of C$_{20}$ fullerene clusters are determined in the framework of the Hubbard model by using lattice density-functional theory (LDFT) and scaling approximations to the interaction-energy functional. Results are…

Strongly Correlated Electrons · Physics 2009-11-11 R. Lopez-Sandoval , G. M. Pastor

We use core-valence-valence (CVV) Auger spectra to probe the Coulomb repulsion between holes in the valence band of Fe pnictide superconductors. By comparing the two-hole final state spectra to density functional theory calculations of the…

The magnetic properties of CrI$_3$ monolayers, which were recently measured, have been investigated considering electronic repulsion and localization effects in Cr 3d orbitals. In this study, we propose a DFT approach using Hubbard U…

Mesoscale and Nanoscale Physics · Physics 2025-12-16 Diego Lauer , Jhon W. González , Eric Suárez Morell , Andrés Ayuela

The strength and effect of Coulomb correlations in the (superconducting when hydrated) x~1/3 and ``enhanced'' x~2/3 regimes of Na(x)CoO2 are evaluated using the correlated band theory LDA+U method. Our results, neglecting quantum…

Strongly Correlated Electrons · Physics 2009-11-10 K. -W. Lee , J. Kunes , W. E. Pickett

Correlations between electrons and the effective dimensionality are crucial factors that shape the properties of an interacting electron system. For example, the onsite Coulomb repulsion, U, may inhibit, or completely block the intersite…

Strongly Correlated Electrons · Physics 2007-05-23 T. Valla , P. D. Johnson , Z. Yusof , B. Wells , Q. Li , S. M. Loureiro , R. J. Cava , M. Mikami , Y. Mori , M. Yoshimura , T. Sasaki

The electronic states of the Fe2As2 plane in iron-based superconductors are investigated on the basis of the two-dimensional 16-band d-p model which includes the Coulomb interaction on a Fe site: the intra- and inter-orbital direct terms U…

Strongly Correlated Electrons · Physics 2009-11-13 Yuki Yanagi , Youichi Yamakawa , Yoshiaki Ōno

We used ab-initio quantum chemical methods, treating explicitly the strong correlation effects within the cobalt 3d shell, as well as the screening effects on the effective integrals, for accurately determining on-site and nearest-neighbor…

Strongly Correlated Electrons · Physics 2009-11-11 Sylvain Landron , Marie-Bernadette Lepetit

The one-particle density of states (1P-DOS) in a system with localized electron states vanishes at the Fermi level due to the Coulomb interaction between electrons. Derivation of the Coulomb gap uses stability criteria of the ground state.…

Disordered Systems and Neural Networks · Physics 2012-04-05 A. L. Efros , Brian Skinner , B. I. Shklovskii

While LDA+U method is well established for strongly correlated materials with well localized orbitals, its application to weakly correlated metals is questionable. By extending the LDA Stoner approach onto LDA+U, we show that LDA+U enhances…

Strongly Correlated Electrons · Physics 2009-11-07 I. I. Mazin , A. G. Petukhov , L. Chioncel , A. I. Lichtenstein

The magnetoresistivity tensor of an interacting two-dimensional electron system with a lateral and unidirectional electric or magnetic modulation, in a perpendicular quantizing magnetic field, is calculated within the Kubo formalism. The…

Mesoscale and Nanoscale Physics · Physics 2009-10-30 Andrei Manolescu , Rolf R. Gerhardts

The use of effective local Coulomb interactions that are dynamical, that is, frequency-dependent, is an efficient tool to describe the effect of long-range Coulomb interactions and screening thereof in solids. The dynamical character of the…

Strongly Correlated Electrons · Physics 2015-12-29 Silke Biermann , Ambroise van Roekeghem

We study the spectral density of electrons rho in an interacting quantum dot (QD) with a hybridization lambda to a non-interacting QD, which in turn is coupled to a non-interacting conduction band. The system corresponds to an impurity…

Strongly Correlated Electrons · Physics 2009-11-13 L. Vaugier , A. A. Aligia , A. M. Lobos