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We have derived several relations, which allow the evaluation of the system free energy changes in the leading order in $\hbar^{2}$ along classically generated trajectories. The results are formulated in terms of purely classical…

Statistical Mechanics · Physics 2009-11-02 M. F. Gelin , D. S. Kosov

When a system is driven out of equilibrium by a time-dependent protocol that modifies the Hamiltonian, it follows a nonequilibrium path. Samples of these paths can be used in nonequilibrium work theorems to estimate equilibrium quantities,…

Statistical Mechanics · Physics 2009-05-29 David D. L. Minh

The work fluctuations of a harmonic oscillator in contact with a thermostat and driven out of equilibrium by an external force are studied experimentally. For the work both the transient and stationary state fluctuation theorems hold. The…

Statistical Mechanics · Physics 2016-08-14 Sylvain Joubaud , Nicolas Garnier , Frédéric Douarche , Artem Petrosyan , Sergio Ciliberto

The connection between work and changes in the Hamiltonian for a system with a time-dependent Hamiltonian has recently been called into question, casting doubt on the usefulness of the Jarzynski equality for calculating free energy changes.…

Statistical Mechanics · Physics 2015-05-13 Eric N. Zimanyi , Robert J. Silbey

In this paper, we study Jarzynski's equality and fluctuation theorems for diffusion processes. While some of the results considered in the current work are known in the (mainly physics) literature, we review and generalize these…

Mathematical Physics · Physics 2019-04-09 Carsten Hartmann , Christof Schuette , Wei Zhang

Jarzynski's equality [1] allows us to investigate free energy landscapes (FELs) by constructing distributions of work performed on a system from an initial ensemble of states to final states. This work is experimentally measured by…

Biological Physics · Physics 2011-05-24 Van Ngo

The nonequilibrium free energy theorems show how distributions of work along nonequilibrium paths are related to free energy differences between the equilibrium states at the end points of these paths. In this paper we develop a natural way…

Statistical Mechanics · Physics 2011-11-09 Stephen R. Williams , Debra J. Searles , Denis J. Evans

The elastic mean free path of carriers in a recently introduced model of quantum chaotic billiards in two and three dimensions is calculated. The model incorporates surface roughness at a microscopic scale by randomly choosing the atomic…

Mesoscale and Nanoscale Physics · Physics 2009-10-30 E. Louis , E. Cuevas , J. A. Verges , M. Ortuno

The function exp(iwt) describes an oscillating motion. Energy of the oscillator is proportional to the square of w. exp(iwt) is the solution of a differential equation. We have replaced this differential equation by the corresponding…

Quantum Physics · Physics 2007-05-23 Mushfiq Ahmad , Muhammad O. G. Talukder

Quantitative evaluations of the free energy of materials must take into account thermal and zero-point energy fluctuations. While these effects can easily be estimated within a harmonic approximation, corrections arising from the anharmonic…

Materials Science · Physics 2019-06-18 Venkat Kapil , Edgar Engel , Mariana Rossi , Michele Ceriotti

A process of energy transfer is demonstrated in non-equilibrium charged particle beams with anisotropy and space charge. Equipartitioning of energy between available degrees of freedom occurs in just a few betatron wavelengths, without halo…

Accelerator Physics · Physics 2007-05-23 R. A. Kishek , P. G. O'Shea , M. Reiser

We consider a single Josephson junction in the presence of time varying gate charge, and examine the nonequilibrium work done by the charge control in the framework of fluctuation theorems. We obtain the probability distribution functions…

Statistical Mechanics · Physics 2013-02-07 Su Do Yi , Beom Jun Kim , Juyeon Yi

The Jarzynski equality (JE) provides a nonequilibrium method to measure and calculate the free energy difference (FED). Note that if two systems share the same Hamiltonian at two equilibrium states, respectively, they share the same FED…

Statistical Mechanics · Physics 2020-07-16 Liyun Zhu , Jiao Wang

In the global framework of finding an axiomatic derivation of nonequilibrium Statistical Mechanics from fundamental principles, such as the maximum path entropy -- also known as Maximum Caliber principle -- , this work proposes an…

Statistical Mechanics · Physics 2017-06-28 Diego González , Sergio Davis

We obtain an exact formula for the equilibrium free energy of a charged quantum particle moving in a harmonic potential in the presence of a uniform external magnetic field and linearly coupled to a heat bath of independent quantum harmonic…

Statistical Mechanics · Physics 2013-12-04 Shamik Gupta , Malay Bandyopadhyay

We study the high-dimensional limit of the free energy associated with the inference problem of a rank-one nonsymmetric matrix. The matrix is expressed as the outer product of two vectors, not necessarily independent. The distributions of…

Probability · Mathematics 2020-06-18 Hong-Bin Chen

We study the energy current and its fluctuations in quantum gapless 1d systems far from equilibrium modeled by conformal field theory, where two separated halves are prepared at distinct temperatures and glued together at a point contact.…

Strongly Correlated Electrons · Physics 2012-08-29 Denis Bernard , Benjamin Doyon

We present a method for determining the free energy of coexisting states from irreversible work measurements. Our approach is based on a fluctuation relation that is valid for dissipative transformations in partially equilibrated systems.…

Soft Condensed Matter · Physics 2009-02-21 Ivan Junier , Alessandro Mossa , Maria Manosas , Felix Ritort

The standard definition of quantum fluctuating work is based on the two-projective energy measurement, which however does not apply to systems with initial quantum coherence because the first projective energy measurement destroys the…

Quantum Physics · Physics 2019-04-12 Rui Pan , Zhaoyu Fei , Tian Qiu , Jing-Ning Zhang , H. T. Quan

We consider the nonequilibrium work distribution of a quantum oscillator with modulated angular frequency. We examine the discrete-to-continuous transition of the distribution as the temperature and the degree of nonadiabaticity of the…

Statistical Mechanics · Physics 2011-04-28 Sebastian Deffner , Obinna Abah , Eric Lutz