Related papers: Quantum free energy differences from non-equilibri…
Starting from the canonical formalism of relativistic (timeless) quantum mechanics, the formulation of timeless path integral is rigorously derived. The transition amplitude is reformulated as the sum, or functional integral, over all…
While techniques to compute thermal fluctuation induced, or pseudo-Casimir, forces in equilibrium systems are well established, the same is not true for non-equilibrium cases. We present a general formalism that allows us to unambiguously…
We consider classical, interacting particles coupled to a thermal reservoir and subject to a local, time-varying potential while undergoing hops on a lattice. We impose detailed balance on the hopping rates and map the dynamics to the Fock…
Stochastic dynamics in the energy representation is employed as a method to study non-equilibrium Brownian-like systems. It is shown that the equation of motion for the energy of such systems can be taken in the form of the Langevin…
The Maxwell equations in the presence of sources are first derived without making use of the potentials and the Hamilton-Jacobi equation for classical electrodynamics is written down. The manifestly gauge invariant theory is then quantized…
The shift in chemical equilibria due to isotope substitution is often exploited to gain insight into a wide variety of chemical and physical processes. It is a purely quantum mechanical effect, which can be computed exactly using…
Path integrals are a central tool when it comes to describing quantum or thermal fluctuations of particles or fields. Their success dates back to Feynman who showed how to use them within the framework of quantum mechanics. Since then, path…
We consider a quantum mechanical system represented in phase space (referred to hereafter as "Wigner space"), coupled to a harmonic oscillator bath. We derive quantum hierarchal Fokker-Planck (QHFP) equations not only in real time, but also…
We study the energy current and its fluctuations in quantum gapless 1d systems far from equilibrium modeled by conformal field theory, where two separated halves are prepared at distinct temperatures and glued together at a point contact.…
We consider classical and quantum mechanics related to an additional noncommutativity, symmetric in position and momentum coordinates. We show that such mechanical system can be transformed to the corresponding one which allows employment…
Extracting equilibrium information from nonequilibrium measurements is a challenge task of great importance in understanding the thermodynamic properties of physical, chemical, and biological systems. The discovery of the Jarzynski equality…
The Jarzynski equality (JE) provides a nonequilibrium method to measure and calculate the free energy difference (FED). Note that if two systems share the same Hamiltonian at two equilibrium states, respectively, they share the same FED…
We derive a semi-classical nonequilibrium work identity by applying the Wigner-Weyl quantization scheme to the Jarzynski identity for a classical Hamiltonian. This allows us, to the leading order in $\hbar$, to overcome the problem of…
Symplectic quantization is a functional approach to quantum field theory that allows sampling of quantum fluctuations directly in Minkowski space time by means of a generalized Hamiltonian dynamics in an extra time variable $\tau$ which, at…
In the thermodynamics of nanoscopic systems the relation between classical and quantum mechanical description is of particular importance. To scrutinize this correspondence we study an anharmonic oscillator driven by a periodic external…
The equilibrium properties of a single quantum particle (qp) interacting with a classical gas for a wide range of temperatures that explore the system's behavior in the classical as well as in the quantum regime is investigated. Both the…
We report the quantum computing of reacting flows by simulating the Hamiltonian dynamics. The scalar transport equation for reacting flows is transformed into a Hamiltonian system, mapping the dissipative and non-Hermitian problem in…
Non-equilibrium fluctuation theorems (NFTs) relate work performed on a system as its Hamiltonian varies with time, to equilibrium data of the initial and final states. In a classical context the system energy can be directly measured, while…
Building on parallels between geometric quantum mechanics and classical mechanics, we explore an alternative basis for quantum thermodynamics that exploits the differential geometry of the underlying state space. We develop both…
The Hamiltonian conservative system of two interacting particles has been considered both in classical and quantum description. The quantum model has been realized using a symmetrized two-particle basis reordered in the unperturbed energy.…