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An analytic approach to the electron transport phenomena in molecular devices is presented. Analyzed devices are composed of organic molecules attached to the two semi-infinite electrodes. Molecular system is described within the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Kamil Walczak

We present a general analytical formula and an ab initio study of quantum interference in multi-branch molecules. Ab initio calculations are used to investigate quantum interference in a benzene-1,2-dithiolate (BDT) molecule sandwiched…

Mesoscale and Nanoscale Physics · Physics 2016-08-14 R. E. Sparks , V. M. García-Suárez , D. Zs. Manrique , C. J. Lambert

Molecular transistors have the potential for switching with lower gate voltages than conventional field-effect transistors. We have calculated the performance of a single-molecule device in which there is interference between electron…

Mesoscale and Nanoscale Physics · Physics 2016-07-28 Ying Li , Jan Mol , Simon Benjamin , Andrew Briggs

Destructive quantum interference (QI) has been a source of interest as a new paradigm for molecular electronics as the electronic conductance is widely dependent on the occurrence or absence of destructive QI effects. In order to interpret…

Mesoscale and Nanoscale Physics · Physics 2022-09-23 O. Sengul , A. Valli , R. Stadler

If simple guidelines could be established for understanding how quantum interference (QI) can be exploited to control the flow of electricity through single molecules, then new functional molecules, which exploit room-temperature QI could…

Mesoscale and Nanoscale Physics · Physics 2019-03-11 Lara Ulčakar , Tomaž Rejec , Jure Kokalj , Sara Sangtarash , Hatef Sadeghi , Anton Ramšak , John H. Jefferson , Colin J. Lambert

Quantum transport for different models of isomer molecules attached to two semi-infinite leads is studied on the basis of Green's function technique. Electronic transport properties are significantly affected by (a) the relative position of…

Mesoscale and Nanoscale Physics · Physics 2009-09-15 Santanu K. Maiti

We present a general framework for quantum interference (QI) between multiple, fundamentally different processes. Our framework reveals the importance of shaped input wavefunctions in enabling QI, and predicts unprecedented interactions…

Quantum Physics · Physics 2023-10-10 J. Lim , Y. S. Ang , L. K. Ang , L. J. Wong

Quantum interference (QI) in molecular transport junctions can lead to dramatic reductions of the electron transmission at certain energies. In a recent work [Markussen et al., Nano Lett. 2010, 10, 4260] we showed how the presence of such…

Mesoscale and Nanoscale Physics · Physics 2017-09-13 Troels Markussen , Robert Stadler , Kristian S. Thygesen

We report experiments demonstrating Quantum Interference Control (QuIC) based on two nonlinear optical absorption processes in semiconductors. We use two optical beams of frequencies $\omega$ and $3\omega /2$ incident on AlGaAs and measure…

Mesoscale and Nanoscale Physics · Physics 2019-08-14 Kai Wang , Rodrigo A. Muniz , J. E. Sipe , S. T. Cundiff

We investigate the interplay of quantum interference effects and electronic-vibrational coupling in electron transport through single-molecule junctions, employing a nonequilibrium Green's function approach. Our findings show that inelastic…

Mesoscale and Nanoscale Physics · Physics 2013-02-18 R. Härtle , M. Butzin , M. Thoss

Quantum interference (QI) effects in molecular systems are a topic of emerging interest in electron transport studies of single molecule junctions. In a recent Letter, Xia et al. employed a graphical scheme introduced by my colleagues and…

Mesoscale and Nanoscale Physics · Physics 2016-11-08 Robert Stadler

An unresolved challenge facing electronics at a few-nm scale is that resistive channels start leaking due to quantum tunneling. This affects the performance of nanoscale transistors, with single-molecule devices displaying particularly low…

In this paper, we explore quantum interference in molecular conductance from the point of view of graph theory and walks on lattices. By virtue of the Cayley-Hamilton theorem for characteristic polynomials and the Coulson-Rushbrooke pairing…

Chemical Physics · Physics 2018-04-26 Yuta Tsuji , Ernesto Estrada , Ramis Movassagh , Roald Hoffmann

We study all-carbon-hydrogen molecular transistors where zigzag graphene nanoribbons play the role of three metallic electrodes connected to a ring-shaped 18-annulene molecule. Using the nonequilibrium Green function formalism combined with…

Mesoscale and Nanoscale Physics · Physics 2010-12-02 Kamal K. Saha , Branislav K. Nikolic , Vincent Meunier , Wenchang Lu , J. Bernholc

We show theoretically and experimentally the existence of a new quantum interference(QI) effect between the electron-hole interactions and the scattering by a single Mn impurity. Theoretical model, including electron-valence hole…

Mesoscale and Nanoscale Physics · Physics 2015-05-28 A. Trojnar , M. Korkusinski , E. Kadantsev , P. Hawrylak , M. Goryca , T. Kazimierczuk , P. Kossacki , P. Wojnar , M. Potemski

We study the transport through a molecular junction exhibiting interference effects. We show that these effects can still be observed in the presence of molecular vibrations if Coulomb repulsion is taken into account. In the Kondo regime,…

Strongly Correlated Electrons · Physics 2019-09-04 P. Roura-Bas , F. Güller , L. Tosi , A. A. Aligia

Molecular electronics offers unique scientific and technological possibilities, resulting from both the nanometre scale of the devices and their reproducible chemical complexity. Two fundamental yet different effects, with no classical…

Mesoscale and Nanoscale Physics · Physics 2017-05-12 Andrew K. Mitchell , Kim G. L. Pedersen , Per Hedegaard , Jens Paaske

We study non-classical pathways and quantum interference in enhanced ionisation of diatomic molecules in strong laser fields using machine learning techniques. Quantum interference provides a bridge, which facilitates intramolecular…

As the dimensions of a conductor approach the nano-scale, quantum effects will begin to dominate its behavior. This entails the exciting possibility of controlling the conductance of a device by direct manipulation of the electron wave…

We use a generalized master equation (GME) to describe the nonequilibrium magnetotransport of interacting electrons through a broad finite quantum wire with an embedded ring structure. The finite quantum wire is weakly coupled to two broad…

Mesoscale and Nanoscale Physics · Physics 2012-03-15 Vidar Gudmundsson , Chi-Shung Tang , Olafur Jonasson , Valeriu Moldoveanu , Andrei Manolescu