Related papers: Isotope shift calculations in Ti II
We present an ab initio method of calculation of isotope shift and relativistic shift in atoms with a few valence electrons. It is based on an energy calculation involving combination of the configuration interaction method and many-body…
We present an ab initio method of calculation of isotope shift in atoms with a few valence electrons, based on the configuration-interaction calculation of energy. The main motivation for developing the method comes from the need to analyze…
This work presents a method for the ab initio calculation of isotope shift in atoms and ions with one valence electron above closed shells. As a zero approximation we use relativistic Hartree-Fock and then calculate correlation corrections.…
We use the combination of configuration interaction and many-body perturbation theory method (CI+MBPT) to perform ab initio calculations the low-energy spectra of Cr II with high accuracy. It is found that second-order MBPT diagrams should…
We report new precision measurements of the $^{20}$Ne--$^{22}$Ne isotope shift for several transitions, as well as state-of-the-art, \textit{ab initio} field-shift calculations. Our results are combined with historical measurements in a…
Isotope shifts of the 2$p_{3/2}$-2$p_{1/2}$ transition in B-like ions are evaluated for a wide range of the nuclear charge number: Z=8-92. The calculations of the relativistic nuclear recoil and nuclear size effects are performed using a…
We study the $^1$S$_0 - ^3$D$_2$ and $^1$S$_0 - ^3$D$_3$ transitions in Cu II and the $^1$S$_0 - ^3$P$^{\rm o}_2$ transition in Yb III as possible candidates for the optical clock transitions. A recently developed version of the…
Relativistic Hartree-Fock method together with many-body perturbation theory and configuration interaction techniques are used to calculate relativistic energy shifts for frequencies of the strong electric dipole transitions of C III, C IV,…
Theories unifying gravity with other interactions suggest spatial and temporal variation of fundamental "constants" in the Universe. A change in the fine structure constant, alpha, could be detected via shifts in the frequencies of atomic…
Relativistic calculations of the isotope shifts of energy levels in highly charged Li-like ions are performed. The nuclear recoil (mass shift) contributions are calculated by merging the perturbative and large-scale…
Precise calculations of the isotope shifts in berylliumlike thorium and uranium ions are presented. The main contributions to the field and mass shifts are calculated within the framework of the Dirac-Coulomb-Breit Hamiltonian employing the…
We report a precise measurement of the isotope shifts in the $4^2$S$_{1/2} \rightarrow 3^2$D$_{5/2}$ electric quadrupole transition at 729~nm in the $^{40 - 42,44,48}$Ca$^+$. The measurement has been made via high-resolution laser…
X-Ray transition energies and isotope shifts in heavy atoms are evaluated. The energy levels with vacancies in the inner shells are calculated within the approximation of the average of nonrelativistic configuration employing the…
We calculate field isotope shifts for nobelium atoms using nuclear charge distributions which come from different nuclear models. We demonstrate that comparing calculated isotope shifts with experiment can serve as a testing ground for…
The present work reports results from systematic multiconfiguration Dirac-Hartree-Fock calculations of electronic isotope shift factors for a set of transitions between low-lying states in neutral aluminium. These electronic quantities…
By combining a recent precise measurement of the ionization energy of $^{87}$Rb with previous measurements of electronic and hyperfine structure, an accurate value for the $^{85}\textrm{Rb}-^{87}\textrm{Rb}$ isotope shift of the…
We apply a recently demonstrated method for precision spectroscopy on strong transitions in trapped ions to measure both fine structure components of the 3s-3p transition in 24-Mg+ and 26-Mg+. We deduce absolute frequency reference data for…
We calculate isotope mass shift for several light ions using Dirac wave functions and mass shift operator with relativistic corrections of the order of $(\alpha Z)^2$. Calculated relativistic corrections to the specific mass shift vary from…
Atomic isotope shifts (ISs) are the isotope-dependent energy differences in the atomic electron energy levels. These shifts serve an important role in atomic and nuclear physics, and particularly in the latter as signatures of nuclear…
The shift in chemical equilibria due to isotope substitution is often exploited to gain insight into a wide variety of chemical and physical processes. It is a purely quantum mechanical effect, which can be computed exactly using…