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We extend the method of Silvestrelli [P. L. Silvestrelli, J. Chem. Phys. 139, 054106 (2013)] to approximate long-range van der Waals interactions at the density functional theory level based on maximally localized Wannier functions combined…

Materials Science · Physics 2015-04-21 Pouya Partovi-Azar , T. D. Kühne

The large variety of 2D materials and their co-integration in van der Waals (vdW) heterostructures enable innovative device engineering. In addition, their atomically-thin nature promotes the design of artificial materials by proximity…

Mesoscale and Nanoscale Physics · Physics 2021-10-20 Juan F. Sierra , Jaroslav Fabian , Roland K. Kawakami , Stephan Roche , Sergio O. Valenzuela

Understanding how soft particles can fill the space is still an open question. Structures far from classical FCC or BCC phases are now commonly experimentally observed in many different systems. Models based on pair interaction between soft…

Soft Condensed Matter · Physics 2017-11-10 Brigitte Pansu , Jean-François Sadoc

Discovery of two-dimensional materials with unique electronic, superior optoelectronic or intrinsic magnetic order have triggered worldwide interests among the fields of material science, condensed matter physics and device physics.…

Applied Physics · Physics 2019-12-24 Shi-Jun Liang , Bin Cheng , Xinyi Cui , Feng Miao

Van der Waals heterostructures, which explore the synergetic properties of two-dimensional (2D) materials when assembled into three-dimensional stacks, have already brought to life a number of exciting new phenomena and novel electronic…

Mesoscale and Nanoscale Physics · Physics 2018-08-02 Tatiana Latychevskaia , Colin Robert Woods , Yi Bo Wang , Matthew Holwill , Eric Prestat , Sarah J. Haigh , Kostya S. Novoselov

Creating materials with structure that is independently controllable at a range of scales requires breaking naturally occurring hierarchies. Breaking these hierarchies can be achieved via the decoupling of building block attributes from…

Soft Condensed Matter · Physics 2022-07-04 Lucia Baldauf , Erin G. Teich , Peter Schall , Greg van Anders , Laura Rossi

We investigate liquid layers adsorbed at spherical and corrugated cylindrical substrates. The effective Hamiltonians for the liquid-gas interfaces fluctuating in the presence of such curved substrates are derived via the mean-field density…

Soft Condensed Matter · Physics 2015-05-13 F. Dutka , M. Napiorkowski

We investigate the behaviour of a system of particles with the different character of interaction. The approach makes it possible to describe systems of interacting particles by statistical methods taking into account a spatial…

Condensed Matter · Physics 2007-05-23 Volodymyr Krasnoholovets , Bohdan Lev

The ability to control the polarization of light at the extreme nanoscale has long been a major scientific and technological goal for photonics. Here we predict the phenomenon of polarization splitting through van der Waals heterostructures…

Optics · Physics 2018-07-20 Shahnawaz Shah , Xiao Lin , Lian Shen , Maturi Renuka , Baile Zhang , Hongsheng Chen

The first principles approaches, density functional theory (DFT) and quantum Monte Carlo, have been used to examine the balance between van der Waals (vdW) forces and hydrogen (H) bonding in ambient and high pressure phases of ice. At…

Electronic and optical properties of silver clusters were calculated using two different \textit{ab initio} approaches: 1) based on all-electron full-potential linearized-augmented plane-wave method and 2) local basis function…

Mesoscale and Nanoscale Physics · Physics 2016-11-28 John T. Titantah , Mikko Karttunen

We investigate the potential energy curves of rare-gas dimers with various ranges and strengths of interparticle interactions (nuclear-electron, electron-electron, and nuclear-nuclear interactions). Our investigation is based on the highly…

Chemical Physics · Physics 2016-02-05 Yu-Ting Chen , Kerwin Hui , Jeng-Da Chai

We present the idea and illustrate potential benefits of having a tool chain of closely related regular, unscreened and screened hybrid exchange-correlation (XC) functionals, all within the consistent formulation of the van der Waals…

The concept of swapping the two most important spin interactions -- exchange and spin-orbit coupling -- is proposed based on two-dimensional multilayer van der Waals heterostructures. Specifically, we show by performing realistic ab initio…

Mesoscale and Nanoscale Physics · Physics 2020-11-05 Klaus Zollner , Martin Gmitra , Jaroslav Fabian

The van der Waals dispersion interaction between two chiral molecules in the presence of arbirary magnetoelectric media is derived using perturbation theory. To be general, the molecular polarisabilities are assumed to be of electric,…

Quantum Physics · Physics 2020-06-24 Hassan Safari , Pablo Barcellona , Stefan Yoshi Buhmann , Akbar Salam

We propose a second version of the van der Waals density functional (vdW-DF2) of Dion et al. [Phys. Rev. Lett. 92, 246401 (2004)], employing a more accurate semilocal exchange functional and the use of a large-N asymptote gradient…

Materials Science · Physics 2010-08-17 Kyuho Lee , Éamonn D. Murray , Lingzhu Kong , Bengt I. Lundqvist , David C. Langreth

In this article we review recent work on van der Waals (vdW) systems in which at least one of the components has strong spin-orbit coupling. We focus on a selection of vdW heterostructures to exemplify the type of interesting electronic…

Mesoscale and Nanoscale Physics · Physics 2020-06-04 Enrico Rossi , Christopher Triola

One-dimensional (1D) van der Waals heterostructures based on carbon nanotube templates are raising a lot of excitement due to the possibility of creating new optical and electronic properties, by either confining molecules inside their…

Materials Science · Physics 2021-07-22 Sofie Cambré , Ming Liu , Dmitry Levshov , Keigo Otsuka , Shigeo Maruyama , Rong Xiang

In this paper we employ all-electron \textit{ab-initio} time-dependent density functional theory based method to calculate the long range dipole-dipole dispersion coefficient (van der Waals coefficient) $C_{6}$ of sodium atom clusters…

Atomic and Molecular Clusters · Physics 2009-11-13 Arup Banerjee , Aparna Chakrabarti , Tapan K. Ghanty

We calculate the properties of a graphene monolayer on the Ir(111) surface, using the model in which the periodicities of the two structures are assumed equal, instead of the observed slight mismatch which leads to a large superperiodic…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 R. Brako , D. Sokcevic , P. Lazic , N. Atodiresei