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To illustrate Boltzmann's construction of an entropy function that is defined for a microstate of a macroscopic system, we present here the simple example of the free expansion of a one dimensional gas of non-interacting point particles.…

Statistical Mechanics · Physics 2022-09-20 Subhadip Chakraborti , Abhishek Dhar , Sheldon Goldstein , Anupam Kundu , Joel L. Lebowitz

The postulates of thermodynamics were originally formulated for macroscopic systems. They lead to the definition of the entropy, which, for a homogeneous system, is a homogeneous function of order one in the extensive variables and is…

Statistical Mechanics · Physics 2018-11-14 Dragos-Victor Anghel , Alexandru S. Parvan

Based on the property of extensivity (mathematically, homogeneity of first degree), we derive in a mathematically consistent manner the explicit expressions of the chemical potential $\mu$ and the Clausius entropy $S$ for the case of…

Statistical Mechanics · Physics 2013-01-15 Thomas Oikonomou , G. Baris Bagci

In this contribution we prove that the entropy of an N-body isolated system can not decrease and the entropy production should be non-negative provided the system possesses an equilibrium state. We define the entropy as a functional of the…

Statistical Mechanics · Physics 2007-05-23 A. Perez-Madrid

The Eigenstate Thermalization Hypothesis (ETH) posits that the reduced density matrix for a subsystem corresponding to an excited eigenstate is "thermal." Here we expound on this hypothesis by asking: for which class of operators, local or…

Strongly Correlated Electrons · Physics 2018-05-02 James R. Garrison , Tarun Grover

In stochastic thermodynamics, the entropy production of a thermodynamic system is defined by the irreversibility measured by the logarithm of the ratio of the path probabilities in the forward and reverse processes. We derive the relation…

Statistical Mechanics · Physics 2018-03-14 Hyun-Myung Chun , Jae Dong Noh

We introduce an ergotropy-based formulation of quantum thermodynamics, which provides a strong connection between average heat and von Neumann entropy. By adopting this formulation, we can reinterpret the infinitesimal average heat in terms…

Quantum Physics · Physics 2025-11-26 J. M. Z. Choquehuanca , P. A. C. Obando , M. S. Sarandy , F. M. de Paula

It is believed that thermodynamic laws are associated with random processes occurring in the system and, therefore, deterministic mechanical systems cannot be described within the framework of the thermodynamic approach. In this paper, we…

Classical Physics · Physics 2020-09-28 Sergey Rashkovskiy

Entropy is a quantity which is of great importance in physics and chemistry. The concept comes out of thermodynamics, proposed by Rudolf Clausius in his analysis of Carnot cycle and linked by Ludwig Boltzmann to the number of specific ways…

Popular Physics · Physics 2015-11-25 Amelia Carolina Sparavigna

The classical Second Law of Thermodynamics demands that an isolated system evolves with a non-diminishing entropy. This holds as well in quantum mechanics if the evolution of the energy-isolated system can be described by a unital quantum…

Quantum Physics · Physics 2018-05-01 N. S. Kirsanov , A. V. Lebedev , M. V. Suslov , V. M. Vinokur , G. Blatter , G. B. Lesovik

The 2nd law of thermodynamics yields an irreversible increase in entropy until thermal equilibrium is achieved. This irreversible increase is often assumed to require large and complex systems to emerge from the reversible microscopic laws…

Statistical Mechanics · Physics 2023-11-21 Ralph V. Chamberlin

The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schr\"odinger equation, which preserves…

Quantum Physics · Physics 2025-01-16 Florian Meier , Tom Rivlin , Tiago Debarba , Jake Xuereb , Marcus Huber , Maximilian P. E. Lock

Many complex systems are characterized by non-Boltzmann distribution functions of their statistical variables. If one wants to -- justified or not -- hold on to the maximum entropy principle for complex statistical systems (non-Boltzmann)…

Statistical Mechanics · Physics 2009-11-13 Stefan Thurner , Rudolf Hanel

The definition of nonequilibrium entropy is provided for the general nonequilibrium processes by connecting thermodynamics with statistical physics, and the principle of entropy increment in the nonequilibrium processes is also proved in…

Data Analysis, Statistics and Probability · Physics 2007-05-23 Xiaochun Mei

A typical strategy of realizing an adiabatic change of a many-particle system is to vary parameters very slowly on a time scale $t_\text{r}$ much larger than intrinsic equilibration time scales. In the ideal case of adiabatic state…

Statistical Mechanics · Physics 2021-03-24 Philipp S. Weiß , Dennis Hardt , Achim Rosch

In this work we study the flow of holographic entanglement entropy in dimensions $d \geq 3$ in the gauge/gravity duality set up. We observe that a generalized entanglement temperature $T_g$ can be defined which gives the Hawking temperature…

High Energy Physics - Theory · Physics 2019-11-27 Ashis Saha , Sunandan Gangopadhyay , Jyoti Prasad Saha

We generalize the second law of thermodynamics in its maximum work formulation for a nonequilibrium initial distribution. It is found that in an isothermal process, the Boltzmann relative entropy (H-function) is not just a Lyapunov function…

Statistical Mechanics · Physics 2015-05-13 H. -H. Hasegawa , J. Ishikawa , K. Takara , D. J. Driebe

In this paper, we establish a sum rule that connects the pseudoentropy and entanglement entropy of a superposition state. Through analytical continuation of the superposition parameter, we demonstrate that the transition matrix and density…

High Energy Physics - Theory · Physics 2024-06-12 Wu-zhong Guo , Yao-zong Jiang , Jin Xu

Entropy is a fundamental concept from Thermodynamics and it can be used to study models on context of Creation Cold Dark Matter (CCDM). From conditions on the first ($\dot{S}\geq0$)\footnote{Throughout the present work we will use dots to…

General Relativity and Quantum Cosmology · Physics 2020-12-02 R. Valentim , J. F. Jesus

In the setup of isolated quantum systems, it is proved that the thermodynamic entropy and the diagonal entropy must increase extensively in any nontrivial quantum quench. The extensive increase of the thermodynamic entropy is shown for any…

Statistical Mechanics · Physics 2016-10-26 Takashi Mori