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The behavior of polyelectrolytes between charged surfaces immersed in semi-dilute solutions is investigated theoretically. A continuum mean field approach is used for calculating numerically concentration profiles between two electrodes…

Soft Condensed Matter · Physics 2007-05-23 I. Borukhov , D. Andelman , H. Orland

The adsorption of MgO molecules on a Fe(001) surface was studied using density functional theory (DFT) and projector augmented wave methods. The energetically most favored configurations for different adsorption sites considered were…

Materials Science · Physics 2015-12-10 D. Wiśnios , A. Kiejna , J. Korecki

First principles density functional calculations are used to study the early oxidation stages of the Mg(0001) surface for oxygen coverages 1/16 <= Theta <= 3 monolayers. It is found that at very low coverages O is incorporated below the…

Materials Science · Physics 2015-06-24 Elsebeth Schroder , Roman Fasel , Adam Kiejna

The existence of strong absorption bands of singly deuterated methane (CH3D) at wavelengths where normal methane (CH4) absorbs comparatively weakly could enable remote measurement of D/H ratios in methane ice on outer solar system bodies.…

Earth and Planetary Astrophysics · Physics 2015-05-27 W. M. Grundy , S. J. Morrison , M. J. Bovyn , S. C. Tegler , D. M. Cornelison

Using a diffusion Monte Carlo (DMC) technique, we calculated the phase diagram of 3He adsorbed on a first solid layer of a molecular hydrogen isotope (H2,HD and D2) on top of graphite. The results are qualitatively similar in all cases: a…

Other Condensed Matter · Physics 2024-07-18 M. C. Gordillo , J. Boronat

In this report we present a theoretical investigation of the potential-energy diagram for water formation from adsorbed O and H species on Rh(111) and Pt(111) surfaces. The study is based on accurate first-principles calculations applying…

Materials Science · Physics 2009-10-31 Steffen Wilke , Vincent Natoli , Morrel H. Cohen

Ab initio total energy calculations within the framework of density functional theory have been performed for atomic hydrogen and oxygen chemisorption on the (0001) surface of double hexagonal packed americium using a full-potential…

Strongly Correlated Electrons · Physics 2015-05-14 P. P. Dholabhai , R. Atta-Fynn , A. K. Ray

Hydrogen plays critical roles in materials science, particularly for advancing technologies in hydrogen storage and phase manipulation, while also posing challenges like hydrogen embrittlement. Understanding its behavior, vital for…

Materials Science · Physics 2025-07-28 Pengcheng Li , Chenglin Pua , Zehao Dong , Zhengxiong Su , Tao Liu , Chao Cai , Huahai Shen , Lin Gu , Zhen Chen

Patterning the wettability of solid surfaces is a successful strategy to control the dropwise condensation of vapor onto partially wetting solid surfaces. We followed the condensation of water vapor onto electrowetting-functionalized…

Fluid Dynamics · Physics 2020-07-28 Harmen Hoek , Ranabir Dey , Frieder Mugele

Chemical adsorption of atomic hydrogen on a negatively charged single layer graphene sheet has been analyzed with ab-initio Density Functional Theory calculations. We have simulated both finite clusters and infinite periodic systems to…

Materials Science · Physics 2015-05-18 J. A. Verges , P. L. de Andres

We report an investigation of the suitability of quantum embedding for modeling the effects of the environment on the X-ray photoelectron spectra of hydrogen chloride and the chloride ions adsorbed on ice surfaces, as well as of chloride…

Chemical Physics · Physics 2023-05-10 Richard Asamoah Opoku , Céline Toubin , André Severo Pereira Gomes

We have carried out a series of helium atom scattering measurements in order to characterise the adsorption properties of hydrogen on antimony(111). Molecular hydrogen does not adsorb at temperatures above 110 K in contrast to…

Materials Science · Physics 2017-05-25 Patrick Kraus , Christian Gösweiner , Anton Tamtögl , Florian Apolloner , Wolfgang E. Ernst

Density functional theory has been used to study the adsorption of molecular H2 on a graphene layer. Different adsorption sites on top of atoms, bonds and the center of carbon hexagons have been considered and compared. We conclude that the…

Chemical Physics · Physics 2009-11-06 J. S. Arellano , L. M. Molina , A. Rubio , J. A. Alonso

The dipole force components in nano-sized metal hydrides are quantitatively determined with curvature and x-ray diffraction measurements. Ab-initio density functional theory is used to calculate the dipole components and the symmetry of the…

Mesoscale and Nanoscale Physics · Physics 2016-05-30 Gunnar K. Pálsson , Moritz Wälde , Martin Amft , Yuanyuan Wu , Martina Ahlberg , Max Wolff , Astrid Pundt , Björgvin Hjörvarsson

We present an ab initio investigation of the interaction between methane, its dehydrogenated forms and the cerium oxide surface. In particular, the stoichiometric CeO2(111) surface and the one with oxygen vacancies are considered. We study…

Materials Science · Physics 2019-11-21 Marco Fronzi , Simone Piccinin , Bernard Delley , Enrico Traversa , Catherine Stampfl

Chemisorption of CO on the stepped Cu(211) surface is studied within ab-initio density functional theory (DFT) and scanning tunneling microscopy (STM) imaging as well as manipulation experiments. Theoretically we focus on the experimentally…

Materials Science · Physics 2009-11-10 Marek Gajdos , Andreas Eichler , Jurgen Hafner , Gerhard Meyer , Karl-Heinz Rieder

A new modeling way of describing the continuous absorption of electromagnetic (EM) radiation in dense partially ionized hydrogen plasma is tested in this work. It is shown that the obtained results give a possibility of calculating spectral…

Solar and Stellar Astrophysics · Physics 2012-08-14 A. A. Mihajlov , N M Sakan , V. A. Sreckovic , Y. Vitel

Adsorption in nanoporous materials is one strategy that can be used to store hydrogen at conditions of temperature and pressure that are economically viable. Adsorption capacity of nanoporous materials depends on surface area which can be…

Materials Science · Physics 2024-05-28 Siddharth Gautam , David R. Cole , Zoltán Imre Dudás , Indu Dhiman

We use density functional theory to investigate adsorption of liquid mixtures on solid surfaces modified with end-grafted chains. The chains are modelled as freely joined spheres. The fluid molecules are spherical. All spherical species…

Soft Condensed Matter · Physics 2016-03-08 M. Borówko , T. Staszewski

Diffusion rates are calculated on the basis of van Hove's formula for the dynamical structure factor (DSF) related to particle scattering at mobile adsorbates. The formula is evaluated quantum mechanically using eigenfunctions obtained from…

Chemical Physics · Physics 2020-02-25 Thiago Firmino , Roberto Marquardt , Fabien Gatti , Wei Dong