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Related papers: Origin of large thermopower in LiRh$_2$O$_4$

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High-performance thermoelectric oxides could offer a great energy solution for integrated and embedded applications in sensing and electronics industries. Oxides, however, often suffer from low Seebeck coefficient when compared with other…

Materials Science · Physics 2020-08-25 M. Hussein N. Assadi , J. Julio Gutiérrez Moreno , Marco Fronzi

Based on first-principles calculations, we study the origin of the large thermopower in Ni-doped LaRhO3 and Mg-doped CuRhO2. We calculate the band structure and construct the maximally localized Wannier functions from which a tight binding…

Materials Science · Physics 2009-11-13 Hidetomo Usui , Ryotaro Arita , Kazuhiko Kuroki

Thermoelectric properties of GdBaCo_{2}O_{5+x} and NdBaCo_{2}O_{5+x} single crystals have been studied upon continuous doping of CoO_2 planes with either electrons or holes. The thermoelectric response and the resistivity behavior reveal a…

Strongly Correlated Electrons · Physics 2009-11-11 A. A. Taskin , A. N. Lavrov , Yoichi Ando

For technical applications thermoelectric materials with a high figure of merit are desirable, and strongly correlated electron systems are very promising in this respect. Since effects of bandstructure_and_ electronic correlations play an…

Strongly Correlated Electrons · Physics 2015-05-13 K. Held , R. Arita , V. I. Anisimov , K. Kuroki

An explanation is provided for the heavy quasiparticle excitations in LiV_2O_4. It differs considerably from that of other known heavy-fermion systems. Main ingredients of our theory are the cubic spinel structure of the material and strong…

Condensed Matter · Physics 2009-11-07 P. Fulde , A. N. Yaresko , A. A. Zvyagin , Y. Grin

We study the origin of the large Seebeck coefficient despite the metallic conductivity in the La-doped SrTiO$_3$ and Ba-doped KTaO$_3$. We calculate the band structure of SrTiO$_3$ and KTaO$_3$, from which the Seebeck coefficient is…

Materials Science · Physics 2010-07-16 Hidetomo Usui , Shinsuke Shibata , Kazuhiko Kuroki

We calculate the in-plane Seebeck coefficient of Sr$_2$RuO$_4$ within a framework combining electronic structure and dynamical mean-field theory. We show that its temperature-dependence is consistent with entropic considerations embodied in…

Strongly Correlated Electrons · Physics 2016-07-20 Jernej Mravlje , Antoine Georges

The usually negligibly small thermoelectric effects in superconducting heterostructures can be boosted dramatically due to the simultaneous effect of spin splitting and spin filtering. Building on an idea of our earlier work [Phys. Rev.…

Mesoscale and Nanoscale Physics · Physics 2015-02-20 P. Machon , M. Eschrig , W. Belzig

Search of new thermoelectric (TE) materials with high \textit{figure-of-merit} (ZT) is always inspired the researcher in TE field. Here, we present a combined experimental and theoretical study of TE properties of Na$_{0.74}$CoO$_{2}$…

Materials Science · Physics 2020-08-26 Shamim Sk , Jayashree Pati , R. S. Dhaka , Sudhir K. Pandey

We report the measurements of thermopower, electrical resistivity and thermal conductivity in a complex cobalt oxide Li$_{0.48}$Na$_{0.35}$CoO$_{2}$, whose crystal structure can be viewed as an intergrowth of the O3 phase of…

Materials Science · Physics 2007-05-23 Zhi Ren , Jingqin Shen , Shuai Jiang , Xiaoyang Chen , Chunmu Feng , Zhu'an Xu , Guanghan Cao

We have systematically measured the transport properties in the layered rhodium oxide K$_{x}$RhO$_{2}$ single crystals ($0.5\lesssim x \lesssim 0.67$), which is isostructural to the thermoelectric oxide Na$_{x}$CoO$_{2}$. We find that below…

Strongly Correlated Electrons · Physics 2019-01-21 Naoko Ito , Mayu Ishii , Ryuji Okazaki

We present a study of the thermoelectric (Seebeck and Nernst) response in heavily overdoped, non-superconducting La$_{1.67}$Sr$_{0.33}$CuO$_4$. In spite of the electron-like curvature of the Fermi surface, the Seebeck coefficient is…

Superconductivity · Physics 2021-04-12 Hao Jin , Alessandro Narduzzo , Minoru Nohara , Hidenori Takagi , Nigel Hussey , Kamran Behnia

Cubic spinel Li$_{\rm 1+x}$Ti$_2$O$_4$ is a promising electrode material as it exhibits a high lithium diffusivity and undergoes minimal changes in lattice parameters during lithiation and delithiation, thereby ensuring favorable…

The Seebeck effect describes the generation of an electric potential in a conducting solid exposed to a temperature gradient. Besides fundamental relevance in solid state physics, it serves as a key quantity to determine the performance of…

Intuitive entropic interpretations of the thermoelectric effect in metals predict an isotropic Seebeck coefficient at high temperatures in the incoherent regime even in anisotropic metals since entropy is not directional.…

Upon chemical substitution of oxygen with fluor, LaMnAsO has been electron-doped in experiments, resulting in samples with remarkably high Seebeck coefficients of around -300$\mu VK^{-1}$ at room temperature and 3% doping. Within the…

Strongly Correlated Electrons · Physics 2019-07-31 Manuel Zingl , Gernot J. Kraberger , Markus Aichhorn

Thermoelectricity was discovered almost two centuries ago in bismuth. The large and negative Seebeck coefficient of this semimetal remains almost flat between 300 K and 100 K. This striking feature can be understood by considering the ratio…

Other Condensed Matter · Physics 2022-06-29 Felix Spathelf , Benoît Fauqué , Kamran Behnia

In an electric field, the flow of electrons in a solid produces an entropy current in addition to the familiar charge current. This Peltier effect underlies all thermoelectric refrigerators. The upsurge in thermoelectric cooling…

Strongly Correlated Electrons · Physics 2009-11-10 Yayu Wang , Nyrissa S. Rogado , R. J. Cava , N. P. Ong

Thermoelectric properties of the system La$_2$NiO$_{4+\delta}$ have been studied ab initio. Large Seebeck coefficient values are predicted for the parent compound, and to some extent remain in the hole-doped metallic phase, accompanied of…

Strongly Correlated Electrons · Physics 2016-04-25 Victor Pardo , Antia S. Botana , Daniel Baldomir

Using analytical arguments and the numerical renormalization group method we investigate the spin-thermopower of a quantum dot in a magnetic field. In the particle-hole symmetric situation the temperature difference applied across the dot…

Mesoscale and Nanoscale Physics · Physics 2012-02-24 Tomaz Rejec , Rok Zitko , Jernej Mravlje , Anton Ramsak
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