Related papers: Vibrational spectroscopy of H2+: hyperfine structu…
In this work we study the last two hydrogen molecular ion isotopologues: DT$^+$ and T$_2^+$, for which high-precision calculations have not yet been made. We obtain the nonrelativistic solutions of the Schr\"odinger equation for the wide…
The possible use of high-resolution rovibrational spectroscopy of the hydrogen molecular ions H + 2 and HD + for an independent determination of several fundamental constants is analyzed. While these molecules had been proposed for…
We calculate the microwave spectra of ultracold KRb alkali metal dimers, including hyperfine interactions and in the presence of electric and magnetic fields. We show that microwave transitions may be used to transfer molecules between…
Symmetry adaptation techniques are applied to the determination of intensities of intra-configurational two-photon transitions for transition-metal ions in cubical symmetry. This leads to a simple model giving the polarization dependence of…
We have studied the radiative decay of the 2s state of one-electron and one-muon ions, where the two-photon mechanism plays an important role. Due to the nuclear size corrections the radiative decay of the 2s state in the electron and muon…
In the present work, we analyze the influence of the polarization effects taking place during the course of a 2DIR spectroscopy experiment performed on a molecular system undergoing an intermolecular vibrational energy transfer process.…
Recently a high precision spectroscopic investigation of the EF^1\Sigma_g^+ - X^1\Sigma_g^+ system of molecular hydrogen was reported yielding information on QED and relativistic effects in a sequence of rotational quantum states in the…
We apply ultrafast spectroscopy to establish a time-domain hierarchy between structural and electronic effects in a strongly-correlated electron system. We discuss the case of the model system VO2, a prototypical non-magnetic compound that…
We report rovibronic spectra of the A $^3\Sigma^+$($v'=0-2$) - X $^3\Pi_\Omega(v=0)$ rovibronic transitions ($|\Omega|=0, 1$ and 2) of the CO$^{2+}$ doubly-charged molecular ion. Spectra were recorded at high resolution ($\sim 5$~cm$^{-1}$)…
Ionic clocks exhibit as the most promising candidates for the frequency standards. Recent investigations show the profound advantages of interrogating two laser beams with different frequencies in developing the frequency standards. Here we…
Two-photon absorption (TPA) spectra of push-pull chromophores are described in terms of a two-state model accounting for electron-vibration coupling. Vibrations have two main effects in TPA spectra. The most obvious one is the appearance of…
Growing astronomical interest in phosphorous (P) chemistry is stimulating the search for new interstellar P-bearing molecules; a task requiring detailed knowledge of the microwave and infrared molecular spectrum. In this work, we present…
We demonstrate a new spectroscopic method for studying electronic transitions in molecules with extremely broad range of angular momentum. We employ an optical centrifuge to create narrow rotational wave packets in the ground electronic…
In many calculations of the two--photon decay of hadronic molecules, the decay matrix element is estimated using the wave function at the origin prescription, in analogy to the two-photon decay of parapositronium. We question the…
We theoretically investigate reflection and transmission measurements of two-photon and four-photon Kerr parametric oscillators (KPOs), introducing interference effects between inter-level transitions. Due to the level degeneracy of a KPO,…
Total and partial cross sections for breakup of ground rovibronic state of H$_2^+$by photon impact are calculated using the exact nonadiabatic nonrelativistic Hamiltonian without approximation. The converged results span six orders of…
Spectral bands for the B(2)$^{2}\Sigma^{+}\rightarrow$ X(1)$^{2}\Sigma^{+}$ electronic transition in the doubly-polar open-shell KSr molecule are recorded at moderate resolution using the thermoluminescence technique. The spectra are…
In this work we discuss the rotational structure of Rydberg molecules. We calculate the complete wave function in a laboratory fixed frame and derive the transition matrix elements for the pho- toassociation of free ground state atoms. We…
In this paper, we present experimental techniques to resolve the closely spaced hyperfine levels of a weak transition by eliminating the residual/partial two-photon Doppler broadening and cross-over resonances in a wavelength mismatched…
The charge transfer reaction of Ar+ with H2 and D2 has been investigated in an experiment combining crossed beams with three-dimensional velocity map imaging. Angle-differential cross sections for two collision energies have been obtained…