Related papers: The Thermodynamic Limit of Quantum Coulomb Systems…
We present two recent works on the thermodynamic limit of quantum Coulomb systems, in which we provided a general method allowing to show the existence of the limit for many different models.
In a previous paper, we have developed a general theory of thermodynamic limits. We apply it here to three different Coulomb quantum systems, for which we prove the convergence of the free energy per unit volume. The first system is the…
Following a recent method introduced by C. Hainzl, J.P. Solovej and the second author of this article, we prove the existence of the thermodynamic limit for a system made of quantum electrons, and classical nuclei whose positions and…
The minimal set of thermodynamic control parameters consists of a statistical (thermal) and a mechanical one. These suffice to introduce all the pertinent thermodynamic variables; thermodynamic processes can then be defined as paths on this…
The proof of the existence of the thermodynamic limit for electrons and nuclei interacting via the Coulomb potential, in the framework of non-relativistic quantum mechanics, was accomplished decades ago. This result did not take account of…
The thermodynamic limit of the internal energy and the entropy of the system of quantum interacting particles in random medium is shown to exist under the crucial requirements of stability and temperedness of interactions. The energy turns…
We take the perspective of open quantum systems and examine from their nonequilibrium dynamics the conditions when the physical quantities, their relations and the laws of thermodynamics become well defined and viable for quantum many body…
We present a consistent thermodynamic theory for the resonant level model in the wide band limit, whose level energy is driven slowly by an external force. The problem of defining 'system' and 'bath' in the strong coupling regime is…
The first law of thermodynamics imposes not just a constraint on the energy-content of systems in extreme quantum regimes, but also symmetry-constraints related to the thermodynamic processing of quantum coherence. We show that this…
It is often incorrectly assumed that the number of microstates \Omega (E,V,N,...) available to an isolated system can have arbitrary dependence on the extensive variables E,V,N, .... However, this is not the case for natural systems which…
I consider the non-equilibrium DC transport of electrons through a quantum system with a thermoelectric response. This system may be any nanostructure or molecule modeled by the nonlinear scattering theory which includes Hartree-like…
The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…
Various quantum thermodynamic bounds are shown to stem from a single tighter and more general inequality, consequence of the operator concavity of the logarithmic function. Such an inequality, which we call the "thermodynamic reverse…
Universality of classical thermodynamics rests on the central limit theorem, due to which, measurements of thermal fluctuations are unable to reveal detailed information regarding the microscopic structure of a macroscopic body. When small…
Underlying the classical thermodynamic principles are analogous microscopic laws, arising from the fundamental axioms of quantum mechanics. These define quantum thermodynamic variables such as quantum work and heat and characterize the…
The present effort addresses the question about the existence of a well-defined thermodynamic limit for the astrophysical systems with the following power law form: to tend the number of particles, N, the total energy, E, and the…
Quantum speed limits are rigorous estimates on how fast a state of a quantum system can depart from the initial state in the course of quantum evolution. Most known quantum speed limits, including the celebrated Mandelstam-Tamm and…
The thermodynamics of quantum systems driven out of equilibrium has attracted increasing attention in last the decade, in connection with quantum information and statistical physics, and with a focus on non-classical signatures. While a…
We have analytically explored thermodynamics of free Bose and Fermi gases for the entire range of temperature, and have extended the same for harmonically trapped cases. We have obtained approximate chemical potentials of the quantum gases…
A new microcanonical equilibrium state is introduced for quantum systems with finite-dimensional state spaces. Equilibrium is characterised by a uniform distribution on a level surface of the expectation value of the Hamiltonian. The…