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Mean square displacements of hydrogen atoms in glass-forming materials and proteins, as reported by incoherent elastic neutron scattering, show kinks in their temperature dependence. This crossover, known as the dynamical transition,…

Soft Condensed Matter · Physics 2016-08-24 Salman Seyedi , Daniel R. Martin , Dmitry V. Matyushov

We use theory and simulations to investigate the existence of amorphous glassy states in ultrasoft colloids. We combine the hyper-netted chain approximation with mode-coupling theory to study the dynamic phase diagram of soft repulsive…

Soft Condensed Matter · Physics 2010-12-16 Ludovic Berthier , Angel J. Moreno , Grzegorz Szamel

We report the observation of a distinct correlation between the kinetic fragility index $m$ and the reduced Arrhenius crossover temperature $\theta_A = T_A/T_g$ in various glass-forming liquids, identifying three distinguishable groups. In…

Soft Condensed Matter · Physics 2016-12-14 Abhishek Jaiswal , Takeshi Egami , K. F. Kelton , Kenneth S. Schweizer , Yang Zhang

We identify the pattern of microscopic dynamical relaxation for a two dimensional glass forming liquid. On short timescales, bursts of irreversible particle motion, called cage jumps, aggregate into clusters. On larger time scales, clusters…

Soft Condensed Matter · Physics 2010-10-04 R. Candelier , A. Widmer-Cooper , J. K. Kummerfeld , O. Dauchot , G. Biroli , P. Harrowell , D. R. Reichman

Within the framework of the mode-coupling theory of super-cooled liquids, we investigate new phenomena in colloidal systems on approach to their glass transitions. When the inter-particle potential contains an attractive part, besides the…

Soft Condensed Matter · Physics 2009-11-07 K. A. Dawson , G. Foffi , F. Sciortino , P. Tartaglia , E. Zaccarelli

We study the growing time scales and length scales associated with dynamical slow down for a realistic glass former, using computer simulations. We perform finite size scaling to evaluate a length scale associated with dynamical…

Statistical Mechanics · Physics 2009-11-13 Smarajit Karmakar , Chandan Dasgupta , Srikanth Sastry

The origin of stretched exponential relaxation in supercooled glass-forming liquids is one of the central questions regarding the anomalous dynamics of these fluids. The dominant explanation for this phenomenon has long been the proposition…

Soft Condensed Matter · Physics 2021-02-03 Daniel Diaz Vela , David S. Simmons

In the context of the random first order transition theory we use an extended mode coupling theory of the glass transition that includes activated events to account for spatiotemporal structures in aging and rejuvenating glasses. We…

Disordered Systems and Neural Networks · Physics 2015-06-15 Apiwat Wisitsorasak , Peter G. Wolynes

We numerically study dynamics and correlation length scales of a colloidal liquid in both quiescent and sheared conditions to further understand the origin of slow dynamics and dynamic heterogeneity in glass-forming systems. The simulation…

Soft Condensed Matter · Physics 2015-06-05 Wen-Sheng Xu , Zhao-Yan Sun , Li-Jia An

A universal dynamical crossover temperature, Tcr, in glassy liquids, associated with the {\alpha}-\b{eta} bifurcation temperature, TB, has been observed in dielectric spectroscopy and other experiments. Tcr lies significantly above the…

Soft Condensed Matter · Physics 2024-03-29 Shubham Kumar , Sarmistha Sarkar , Biman Bagchi

We consider the effect of droplet excitations in the random first order transition theory of glasses on the configurational entropy. The contribution of these excitations is estimated both at and above the ideal glass transition…

Statistical Mechanics · Physics 2009-11-07 M. P. Eastwood , P. G. Wolynes

We divide glass and viscous liquid sciences into two major research areas, the first dealing with how to avoid crystals and so access the viscous liquid state, and the second dealing with how liquids behave when no crystals form. We review…

Disordered Systems and Neural Networks · Physics 2009-11-13 C. Austen Angell

Glassy systems are disordered systems characterized by extremely slow dynamics. Examples are supercooled liquids, whose dynamics slow down under cooling. The specific pattern of slowing-down depends on the material considered. This…

Disordered Systems and Neural Networks · Physics 2016-04-12 Le Yan

A microscopically motivated theory of glassy dynamics based on an underlying random first order transition is developed to explain the magnitude of free energy barriers for glassy relaxation. A variety of empirical correlations embodied in…

Disordered Systems and Neural Networks · Physics 2009-10-31 Xiaoyu Xia , Peter G. Wolynes

Volume and enthalpy relaxation of glasses after a sudden temperature change has been extensively studied since Kovacs seminal work. One observes an asymmetric approach to equilibrium upon cooling versus heating and, more…

Soft Condensed Matter · Physics 2020-03-11 Matteo Lulli , Chun-Shing Lee , Hai-Yao Deng , Cho-Tung Yip , Chi-Hang Lam

An alternative scenario for the glass transition based on the cooperative nature of nucleation processes and the role of entropic effects is presented. The new ingredient is to relate the dissipation during the relaxation process to the…

Statistical Mechanics · Physics 2007-05-23 Andrea Crisanti , Felix Ritort

The relationship between spatially heterogeneous dynamics (SHD) and jamming is studied in a glass-forming binary Lennard-Jones system via molecular dynamics simulations. It has been suggested that the probability distribution of…

Disordered Systems and Neural Networks · Physics 2007-05-23 Naida Lacevic , Sharon C. Glotzer

In this work, the short-time dynamics of simple liquid is explored both analytically and numerically with the focus on the interplay between the density fluctuations in a volume surrounding a chosen particle and its random walk motion. The…

Statistical Mechanics · Physics 2019-06-26 Eugene B. Postnikov

We compare the slow dynamics of irreversible gels, colloidal gels, glasses and spin glasses by analyzing the behavior of the so called non-linear dynamical susceptibility, a quantity usually introduced to quantitatively characterize the…

Soft Condensed Matter · Physics 2015-06-25 A. Coniglio , T. Abete , A. de Candia , E. Del Gado , A. Fierro

Analysis of temperature dependence of structural relaxation time in supercooled liquids revealed a qualitatively distinct feature - a sharp, cusp-like maxumum in the second derivative of its logarithm. It suggests that the super-Arrhenius…

Soft Condensed Matter · Physics 2016-01-20 V. N. Novikov , A. P. Sokolov