Related papers: Ionic Kratzer bond theory and vibrational levels f…
The Kratzer's potential $V(r)=g_{1}/r^{2}-g_{2}/r$ is studied in quantum mechanics with a generalized uncertainty principle, which includes a minimal length $\left( \Delta X\right) _{\min}=\hbar\sqrt{5\beta}$. In momentum representation,…
The study of diatomic molecules plays a central role in the understanding of the chemical bond. For their simplicity, they serve as a model for the study of more complex molecular systems. In this article, we solve the rovibrational…
Symmetry breaking in Hsub2, quantified with Kratzer bond theory, leads to vibrational levels with errors of only 0,00008 %. For quanta, 0,0011 % errors are smaller than with any ab initio QM method. Chiral behavior of covalent bond Hsub2…
The energy levels of quantum systems are determined by quantization conditions. For one-dimensional anharmonic oscillators, one can transform the Schrodinger equation into a Riccati form, i.e., in terms of the logarithmic derivative of the…
Quantum harmonic oscillators linearly coupled through coordinates and momenta, represented by the Hamiltonian $ {\hat H}=\sum^2_{i=1}\left( \frac{ {\hat p}^{2}_i}{2 m_i } + \frac{m_i \omega^2_i}{2} x^2_i\right) +{\hat H}_{int} $, where the…
An effective Hamiltonian is considered for hydrogen bonding between two molecules due to the quantum mechanical interaction between the orbitals of the H-atom and the donor and acceptor atoms in the molecules. The Hamiltonian acts on two…
We argue that the textbook method for solving eigenvalue equations is simpler, more elegant and efficient than the Asymptotic Iteration Method (AIM) applied in J. Phys. A {\bf 44} 155205. We show that the Kratzer potential is not a…
We argue that several potentials proposed recently for the analysis of the vibrational-rotational spectra of diatomic molecules and their thermodynamic properties exhibit a flaw. One can easily show that the parameters $D_e $ and $r_e$ in…
We review harmonic oscillator theory for closed, stable quantum systems. The H2 potential energy curve (PEC) of Mexican hat-type, calculated with a confined Kratzer oscillator, is better than the Rydberg-Klein-Rees (RKR) H2 PEC. Compared…
We propose an alternative to the usual time--independent Born--Oppenheimer approximation that is specifically designed to describe molecules with symmetrical Hydrogen bonds. In our approach, the masses of the Hydrogen nuclei are scaled…
We determine the energy eigenvalues and eigenfunctions of the harmonic oscillator where the coordinates and momenta are assumed to obey the modified commutation relations [x_i,p_j]=i hbar[(1+ beta p^2) delta_{ij} + beta' p_i p_j]. These…
A system of two coupled quantum harmonic oscillators with the Hamiltonian ${\hat H}=\frac{1}{2}\left(\frac{1}{m_1}{\hat p}^{2}_1 + \frac{1}{m_2}{\hat p}^{2}_2+A x^2_1+B x^2_2+ C x_1 x_2\right)$ can be found in many applications of quantum…
The properties of a nonlinear oscillator with an additional term $k_g/x^2$, characterizing the isotonic oscillator, are studied. The nonlinearity affects to both the kinetic term and the potential and combines two nonlinearities associated…
We study the structural effects produced by the quantization of vibrational degrees of freedom in periodic crystals at zero temperature. To this end we introduce a methodology based on mapping a suitable subspace of the vibrational manifold…
The recent generalized Debye-Hueckel (GDH) theory is applied to the calculation of the charge-charge correlation function G_{ZZ}(r). The resulting expression satisfies both (i) the charge neutrality condition and (ii) the Stillinger-Lovett…
A microscopic quantum ideal rotor-model Hamiltonian (distinct from that of Bohr's rotational model) is derived for a rotation about a single axis by applying a dynamic rotation operator to the deformed nuclear ground-state wavefunction. It…
We review the essentials of the formalism of quantum mechanics based on a deformed Heisenbeg algebra, leading to the existence of a minimal length scale. We compute in this context, the energy spectra of the pseudoharmonic oscillator and…
We formulate the second quantization of a charged scalar field in homogeneous, time-dependent electromagnetic fields, in which the Hamiltonian is an infinite system of decoupled, time-dependent oscillators for electric fields, but it is…
The fundamental ground tone vibration of H2, HD, and D2 is determined to an accuracy of 2 x 10^-4 cm^-1 from Doppler-free laser spectroscopy in the collisionless environment of a molecular beam. This rotationless vibrational splitting is…
Using the effective rotational Hamiltonian method, we have conducted an analysis of the D218O ground and the first excited vibration state rotational energy levels. The analysis was based on the effective Hamiltonians represented in several…