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The electronic properties of hybrid organic-inorganic semiconductor interfaces depend strongly on the alignment of the electronic carrier levels in the organic/inorganic components. In the present work, we address this energy level…

The alignment of the frontier orbital energies of an adsorbed molecule with the substrate Fermi level at metal-organic interfaces is a fundamental observable of significant practical importance in nanoscience and beyond. Typical density…

Mesoscale and Nanoscale Physics · Physics 2017-03-07 Zhenfei Liu , David A. Egger , Sivan Refaely-Abramson , Leeor Kronik , Jeffrey B. Neaton

We have performed a density functional theory study of the possible layered geometries occurring after dehydrogenation of a self-assembled monolayer (SAM) of biphenyl-thiol molecules (BPTs) adsorbed on a Au(111), as it has been…

Mesoscale and Nanoscale Physics · Physics 2011-11-10 Pepa Cabrera-Sanfelix , Andrés Arnau , Daniel Sánchez-Portal

Room-temperature and low-temperature (77 K) scanning tunneling spectroscopy (STS) and voltage-dependent scanning tunneling microscopy (STM) data are used to study the local electronic properties of the quasi-one-dimensional Si(557)-Au…

Mesoscale and Nanoscale Physics · Physics 2014-02-19 M. Sauter , R. Hoffmann , C. Surgers , H. v. Lohneysen

Using a metal-oxide-semiconductor field effect transistor (MOSFET) structure with a high-quality CoFe/n^+Si contact, we systematically study spin injection and spin accumulation in a nondegenerated Si channel with a doping density of ~…

Materials Science · Physics 2013-05-16 K. Hamaya , Y. Ando , K. Masaki , Y. Maeda , Y. Fujita , S. Yamada , K. Sawano , M. Miyao

The design of low-dimensional organic-inorganic interfaces for the next generation of opto-electronic applications requires an in-depth understanding of the microscopic mechanisms ruling electronic interactions in these systems. In this…

Two-dimensional (2D) metal halides have received more attention because of their electronic and optoelectronic properties. Recently, researchers are interested to investigate the thermoelectric properties of metal halide monolayers because…

Materials Science · Physics 2020-04-30 Atanu Betal , Jayanta Bera , Satyajit Sahu

Relaxed atomic geometries and chemisorption energies have been calculated for the dissociative adsorption of molecular hydrogen on vicinal Si(001) surfaces. We employ density-functional theory, together with a pseudopotential for Si, and…

Condensed Matter · Physics 2009-10-31 E. Pehlke , P. Kratzer

Organic semiconductors are a promising class of materials for numerous electronic and optoelectronic applications, including solar cells. However, these materials tend to be extremely sensitive to the local environment and surrounding…

Mesoscale and Nanoscale Physics · Physics 2023-03-29 Katherine A. Cochrane , Tanya S. Roussy , Bingkai Yuan , Gary Tom , Erik Mårsell , Sarah A. Burke

This study explores atomic and molecular adsorption on a number of early transition-metal carbides (TMC's) by means of density-functional theory calculations. Trend studies are conducted with respect to both period and group in the periodic…

Materials Science · Physics 2012-05-14 Aleksandra Vojvodic , Carlo Ruberto , Bengt I. Lundqvist

The local atomic structure and lattice dynamics of two isostructural layered transition metal dichalcogenides (TMDs), 1T-TiSe$_2$ and 1T-VSe$_2$, were studied using temperature-dependent X-ray absorption spectroscopy at the Ti, V, and Se…

Materials Science · Physics 2024-01-30 Inga Pudza , Boris Polyakov , Kaspars Pudzs , Edmund Welter , Alexei Kuzmin

Understanding the ultra-fast transport properties of hot charge carriers is of significant importance both fundamentally and technically in applications like solar cells and transistors. However, direct measurement of charge transport at…

Chemical Physics · Physics 2022-08-10 Peter A. Sloan , Kristina R. Rusimova

Two-dimensional transition metal dichalcogenides (TMDs) represent an ideal testbench for the search of materials by design, because their optoelectronic properties can be manipulated through surface engineering and molecular…

We have investigated Rb adsorption on the Si(100) surface for 0.5 and 1 monolayer coverages using the total energy method with norm-conserving pseudopotentials. For 2$\times$1 reconstruction at 1 ML coverage symmetrized dimers are found to…

Strongly Correlated Electrons · Physics 2007-05-23 E. Mete , R. Shaltaf , Ş. Ellialtıoğlu

Based on a Fermi liquid picture, the temperature effect on the impurity-induced spatial modulation of local density of states (LDOS) is investigated for the d-wave superconductor Bi$_2$Sr$_2$CaCu$_2$O$_8$, in the context of scanning…

Superconductivity · Physics 2009-11-10 K. -K. Voo , W. C. Wu , H. -Y. Chen , C. -Y. Mou

Adsorption of acetylene on Si(100) is studied from first principles. We find that, among a number of possible adsorption configurations, the lowest-energy structure is a ``bridge'' configuration, where the C$_2$H$_2$ molecule is bonded to…

Condensed Matter · Physics 2009-10-31 Pier Luigi Silvestrelli , Flavio Toigo , Francesco Ancilotto

The realization of self-assembled molecular-electronic films, whose room-temperature transport properties are controlled by quantum interference (QI), is an essential step in the scale-up QI effects from single molecules to parallel arrays…

We present an ab initio study of the structural and electronic properties of styrene molecules adsorbed on the dimerized Si(100) surface at different coverages, ranging from the single-molecule to the full monolayer. The adsorption…

Soft Condensed Matter · Physics 2009-11-11 A. Calzolari , A. Ruini , M. J. Caldas , E. Molinari

In this work, we have investigated the electronic structure and thermoelectric properties of quaternary heusler alloy, FeRuTiSi, using first principle DFT tools implemented in WIEN2k and BoltzTraP code. Electronic structure calculations…

Strongly Correlated Electrons · Physics 2020-12-02 Saurabh Singh , Shubham Singh , Nitinkumar Bijewar , Ashish Kumar

Alkali-metal (potassium) adsorption on FeSe thin films with thickness from two unit cells (UC) to 4-UC on SrTiO3 grown by molecular beam epitaxy is investigated with a low-temperature scanning tunneling microscope. At appropriate potassium…