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Within the coexistence region between liquid and vapor the equilibrium pressure of a simulated fluid exhibits characteristic jumps and plateaus when plotted as a function of density at constant temperature. These features exclusively…

Statistical Mechanics · Physics 2015-09-09 S. Prestipino , C. Caccamo , D. Costa , G. Malescio , G. Munaò

A mode-coupling theory for the slow single-particle dynamics in fluids adsorbed in disordered porous media is derived, which complements previous work on the collective dynamics [V. Krakoviack, Phys. Rev. E 75, 031503 (2007)]. Its…

Disordered Systems and Neural Networks · Physics 2009-06-10 V. Krakoviack

Molecular dynamics simulations are performed to investigate heterogeneous dynamics in amorphous glassy materials under oscillatory shear strain. We consider three-dimensional binary Lennard-Jones mixture well below the glass transition…

Soft Condensed Matter · Physics 2013-05-10 Nikolai V. Priezjev

We investigate the calorimetric liquid-glass transition by performing simulations of a binary Lennard-Jones mixture in one through four dimensions. Starting at a high temperature, the systems are cooled to T=0 and heated back to the ergodic…

Disordered Systems and Neural Networks · Physics 2009-01-01 Ralf Brüning , Denis A. St-Onge , Steve Patterson , Walter Kob

Using molecular dynamics simulations we study the temperature-density phase diagram of a simple model system of particles in two dimensions. In addition to translational degrees of freedom, each particle has two internal states and…

Soft Condensed Matter · Physics 2013-05-29 Chandana Mondal , Surajit Sengupta

The phase diagram of the prototypical two-dimensional Lennard-Jones system, while extensively investigated, is still debated. In particular, there are controversial results in the literature as concern the existence of the hexatic phase and…

Statistical Mechanics · Physics 2020-12-08 Yan-Wei Li , Massimo Pica Ciamarra

Dynamical properties of a Lennard-Jones binary mixture embedded in an off lattice matrix of soft spheres are studied in the direct space upon supercooling by molecular dynamics simulations. On lowering temperature the smaller particles tend…

Soft Condensed Matter · Physics 2009-11-10 P. Gallo , R. Pellarin , M. Rovere

A thermodynamic approach to derive the liquid-glass transition line in the reduced temperature vs reduced density plane for a monatomic Lennard-Jones fluid is presented. The approach makes use of a recent reformulation of the classical…

Statistical Mechanics · Physics 2009-11-07 M. Robles , M. López de Haro

We report the first observation of homogeneous crystallization in simulated high-dimensional ($d > 3$) liquids that follow physically realistic dynamics and have system sizes that are large enough to eliminate the possibility that…

Soft Condensed Matter · Physics 2023-11-08 Robert S. Hoy

The fluid flow across an unbounded horizontal plate embedded with uniform mass diffusion is studied in this article together with the impacts of the chemical reaction and parabolic motion, while the temperature and concentration of the…

Dynamical Systems · Mathematics 2024-10-08 P. Sivakumar , R. M. Madhusudhan , R. Muthucumaraswamy , A. Ramamoorthy

We provide a consistent statistical-mechanical treatment for describing the thermodynamics and the structure of fluids embedded in the hyperbolic plane. In particular, we derive a generalization of the virial equation relating the bulk…

Statistical Mechanics · Physics 2009-05-18 François Sausset , Gilles Tarjus , Pascal Viot

Mixtures of glass-forming fluids sometimes exhibit glass-glass phase separation at low temperatures. Here, we use a molecular dynamics simulation to study one of the simplest examples of the glass-glass phase separation. We consider a…

Statistical Mechanics · Physics 2020-04-07 Yuri Oku , Kyohei Takae , Atsushi Ikeda

The dynamical correlations of a model consisting of particles constrained on the line and interacting with a nearest--neighbour Lennard--Jones potential are computed by molecular--dynamics simulations. A drastic qualitative change of the…

Statistical Mechanics · Physics 2009-11-11 Stefano Lepri , Paolo Sandri , Antonio Politi

We propose a model of a heterogeneous glass forming liquid and compute the low-temperature behavior of a tagged molecule moving within it. This model exhibits stretched-exponential decay of the wavenumber-dependent, self intermediate…

Materials Science · Physics 2009-11-13 J. S. Langer , S. Mukhopadhyay

A relaxation process, with the associated phenomenology of sound attenuation and sound velocity dispersion, is found in a simulated harmonic Lennard-Jones glass. We propose to identify this process with the so called microscopic (or…

Disordered Systems and Neural Networks · Physics 2009-10-31 G. Ruocco , F. Sette , R. Di Leonardo , G. Monaco , M. Sampoli , T. Scopigno , G. Viliani

We investigate the influence of space curvature, and of the associated "frustration", on the dynamics of a model glassformer: a monatomic liquid on the hyperbolic plane. We find that the system's fragility, i.e. the sensitivity of the…

Statistical Mechanics · Physics 2008-10-15 François Sausset , Gilles Tarjus , Pascal Viot

We investigate the thermohydrodynamic lubrication of the Lennard-Jones (LJ) fluid in the parallel-plate channel composed of the LJ particles by using molecular dynamics (MD) simulation. We discover a counterintuitive solidification of the…

Soft Condensed Matter · Physics 2019-09-25 Kouki Nakamura , Ryo Ookawa , Shugo Yasuda

A kinetic Monte Carlo (KMC) method is used to study the structural properties and dynamics of a supercooled binary Lennard-Jones liquid around the glass transition temperature. This technique permits us to explore the potential energy…

Soft Condensed Matter · Physics 2015-06-24 Javier Hernandez-Rojas , David J. Wales

Using molecular dynamic simulations we study a waterlike model confined between two fixed hydrophobic plates. The system is tested for density, diffusion and structural anomalous behavior and compared with the bulk results. Within the range…

Chemical Physics · Physics 2013-03-06 Leandro Batirolla Krott , Marcia Cristina Bernardes Barbosa

Self-diffusion and radial distribution functions are studied in a strongly confined Lennard-Jones fluid. Surprisingly, in the solid-liquid phase transition region, where the system exhibits dynamic coexistence, the self-diffusion constants…

Statistical Mechanics · Physics 2016-02-11 N. de Sousa , J. J. Sáenz , Frank Scheffold , A. García Martín , L. S. Froufe-Pérez