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Single-molecule transistors provide a unique experimental tool to investigate the coupling between charge transport and the molecular degrees of freedom in individual molecules. One interesting class of molecules for such experiments are…

We measure electron tunneling via discrete energy levels in ferromagnetic cobalt particles less than 4 nm in diameter, using non-magnetic electrodes. Due to magnetic anisotropy, the energy of each tunneling resonance shifts as an applied…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 S. Gueron , Mandar M. Deshmukh , E. B. Myers , D. C. Ralph

We have measured quantum transport through an individual Fe$_4$ single-molecule magnet embedded in a three-terminal device geometry. The characteristic zero-field splittings of adjacent charge states and their magnetic field evolution are…

The ability to make electrical contact to single molecules creates opportunities to examine fundamental processes governing electron flow on the smallest possible length scales. We report experiments in which we controllably stretch…

A key to building functional devices on the basis of single molecule magnets in the framework of molecular electronics is the ability to deposit and study these molecules on a surface, because the structural, electronic and magnetic…

Mesoscale and Nanoscale Physics · Physics 2016-01-26 Judith Donner , Jan-Philipp Broschinski , Bastian Feldscher , Anja Stammler , Hartmut Bögge , Thorsten Glaser , Daniel Wegner

Well-protected magnetization, tunable quantum states and long coherence time are desired for the use of magnetic molecules in spintronics and quantum information technologies. In this work, endohedral fullerene molecules M@C28 with…

Materials Science · Physics 2022-01-12 Jie Li , Lei Gu , Ruqian Wu

In single-molecule transistors, we observe inelastic cotunneling features that correspond energetically to vibrational excitations of the molecule, as determined by Raman and infrared spectroscopy. This is a form of inelastic electron…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 L. H. Yu , Z. K. Keane , J. W. Ciszek , L. Cheng , M. P. Stewart , J. M. Tour , D. Natelson

This article takes a broad view of the understanding of magnetic bistability and magnetic quantum tunneling in single-molecule magnets (SMMs), focusing on three families of relatively simple, low-nuclearity transition metal clusters: spin S…

We present detailed measurements of the discrete electron-tunneling level spectrum within nanometer-scale cobalt particles as a function of magnetic field and gate voltage, in this way probing individual quantum many-body eigenstates inside…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 M. M. Deshmukh , S. Gueron , E. Bonet , A. N. Pasupathy , S. Kleff , J. von Delft , D. C. Ralph

Spin tunneling in molecular magnets has attracted much attention, however theoretical considerations of this phenomenon up to now have not taken into account the many-spin nature of molecular magnets. We present, to our knowledge, the first…

Materials Science · Physics 2009-10-31 M. Al-Saqer , V. V. Dobrovitski , B. N. Harmon , M. I. Katsnelson

Access to magnetic excitation spectra of single atoms deposited on surfaces is nowadays possible by means of low-temperature inelastic scanning tunneling spectroscopy. We present a first-principles method for the calculation of inelastic…

Strongly Correlated Electrons · Physics 2015-06-22 Benedikt Schweflinghaus , Manuel dos Santos Dias , Antonio T. Costa , Samir Lounis

We consider transport through a single N@C60 molecule, weakly coupled to metallic leads. Employing a density-matrix formalism we derive rate equations for the occupation probabilities of many-particle states of the molecule. We calculate…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Florian Elste , Carsten Timm

We present an experimental and theoretical study of a magnetic single-molecule transistor based on N@C60 connected to gold electrodes. Particular attention is paid to the regime of intermediate molecule-lead coupling, where cotunneling…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 Nicolas Roch , Romain Vincent , Florian Elste , Wolfgang Harneit , Wolfgang Wernsdorfer , Carsten Timm , Franck Balestro

The ability to electrically-drive spin excitations in molecules with magnetic anisotropy is key for high-density storage and quantum-information technology. Electrons, however, also tunnel via the vibrational excitations unique to a…

Molecular nanomagnets show clear signatures of coherent behavior and have a wide variety of effective low-energy spin Hamiltonians suitable for encoding qubits and implementing spin-based quantum information processing. At the nanoscale,…

Mesoscale and Nanoscale Physics · Physics 2013-05-29 Mircea Trif , Filippo Troiani , Dimitrije Stepanenko , Daniel Loss

Electrical control of spins at the nanoscale offers significant architectural advantages in spintronics, because electric fields can be confined over shorter length scales than magnetic fields. Thus, recent demonstrations of electric-field…

Mesoscale and Nanoscale Physics · Physics 2021-10-15 Junjie Liu , Jakub Mrozek , Aman Ullah , Yan Duan , José J. Baldoví , Eugenio Coronado , Alejandro Gaita-Ariño , Arzhang Ardavan

It is proposed that nuclear (or electron) spins in a trapped molecule would be well isolated from the environment and the state of each spin can be measured by means of mechanical detection of magnetic resonance. Therefore molecular traps…

Quantum Physics · Physics 2007-05-23 Haiqing Wei , Xin Xue

Molecular spintronics is made possible by the coupling between electronic configuration and magnetic po- larization of the molecules. For control and application of the individual molecular states it is necessary to both read and write…

Mesoscale and Nanoscale Physics · Physics 2016-04-27 T. Saygun , J. Bylin , H. Hammar , J. Fransson

We investigate the spin- and energy dependent tunneling through a single organic molecule (CoPc) adsorbed on a ferromagnetic Fe thin film, spatially resolved by low-temperature spin-polarized scanning tunneling microscopy. Interestingly,…

Inelastic tunneling through magnetically anisotropic molecules is studied theoretically in the presence of a strong magnetic field. Since the molecular orientation is not well controlled in tunneling experiments, we consider arbitrary…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Carsten Timm
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