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Using density-functional-theory calculations, we have identified new stable configurations for tri-, tetra-, and penta-vacancies in silicon. These new configurations consist of combinations of a ring-hexavacancy with three, two, or one…

Materials Science · Physics 2009-11-10 D. V. Makhov , Laurent J. Lewis

Using first principles simulations we perform a detailed study of the structural, electronic and transport properties of monoatomic platinum chains, sandwiched between platinum electrodes. First we demonstrate that the most stable atomic…

Materials Science · Physics 2007-05-23 V. M. Garcia-Suarez , A. R. Rocha , S. W. Bailey , C. J. Lambert , S. Sanvito , J. Ferrer

The deposition of one silicon monolayer on Ag(111) gives rise to a set of superstructures depending on growth conditions. These superstructures are correlated to the epitaxy between the honeycomb structure of silicon (so called silicene)…

Materials Science · Physics 2015-09-30 H. Jamgotchian , B. Ealet , Y. Colignon , H. Maradj , J-Y. Hoarau , J-P. Biberian , B. Aufray

We present an atomic-resolution observation and analysis of graphene constrictions and ribbons with sub-nanometer width. Graphene membranes are studied by imaging side spherical aberration-corrected transmission electron microscopy at 80…

Mesoscale and Nanoscale Physics · Physics 2009-08-20 A. Chuvilin , J. C. Meyer , G. Algara-Siller , U. Kaiser

Adsorption of benzene on the Si(100) surface is studied from first principles. We find that the most stable configuration is a tetra-$\sigma$-bonded structure characterized by one C-C double bond and four C-Si bonds. A similar structure,…

Condensed Matter · Physics 2009-10-31 Pier Luigi Silvestrelli , Francesco Ancilotto , Flavio Toigo

Although (103) is a stable nominal orientation for both silicon and germanium, experimental observations revealed that in the case of silicon this surface remains disordered on an atomic scale even after careful annealing. We report here a…

Materials Science · Physics 2009-11-13 C. V. Ciobanu , F. C. Chuang , D. E. Lytle

We describe a recently discovered stable planar surface of silicon, Si(114). This high-index surface, oriented 19.5 degrees away from (001) toward (111), undergoes a 2x1 reconstruction. We propose a complete model for the reconstructed…

mtrl-th · Physics 2009-10-30 Steven C. Erwin , Alison A. Baski , Lloyd J. Whitman

We report on total-energy electronic-structure calculations in the density-functional theory performed for both monolayer and bilayer silicene on Ag(111) surfaces. The rt3 x rt3 structure observed experimentally and argued to be the…

Mesoscale and Nanoscale Physics · Physics 2014-04-15 Zhi-Xin Guo , Atsushi Oshiyama

First-principles calculations show that monatomic strings of carbon have high cohesive energy and axial strength, and exhibit stability even at high temperatures. Due to their flexibility and reactivity, carbon chains are suitable for…

Materials Science · Physics 2007-05-23 S. Tongay , R. T. Senger , S. Dag , S. Ciraci

The stability of atomic intercalated carbon $K_{4}$ crystals, XC$_{2}$ (X=H, Li, Be, B, C, N, O, F, Na, Mg, Al, Si, P, S, Cl, K, Ca, Ga, Ge, As, Se, Br, Rb or Sr) is evaluated by geometry optimization and frozen phonon analysis based on…

Materials Science · Physics 2011-03-23 Masahiro Itoh , Seiichi Takami , Yoshiyuki Kawazoe , Tadafumi Adschiri

In the search for evidence of silicene, a two-dimensional honeycomb lattice of silicon, it is important to obtain a complete picture for the evolution of Si structures on Ag(111), which is believed to be the most suitable substrate for…

Materials Science · Physics 2015-06-04 Baojie Feng , Zijing Ding , Sheng Meng , Yugui Yao , Xiaoyue He , Peng Cheng , Lan Chen , Kehui Wu

Single-atom catalysts have attracted significant attention due to their exceptional atomic utilization and high efficiency in a range of catalytic reactions. However, these systems often face thermodynamic instability, leading to…

Materials Science · Physics 2025-01-24 Lina Wang , Zhenhai Wen , Guangfu Luo

We have carried out an ab-initio study of $\alpha$-Sn (111), with the aim of predicting and understanding its structure, reconstructions, and electronic states. We consider a variety of structural possibilities, and optimize them by moving…

Condensed Matter · Physics 2009-10-28 Zhong-Yi Lu , Guido L. Chiarotti , S. Scandolo , E. Tosatti

The stability of interfaces and the mechanisms of thin film growth on semiconductors are issues of central importance in electronic devices. These issues can only be understood through detailed study of the relevant microscopic processes.…

mtrl-th · Physics 2016-09-07 Efthimios Kaxiras

Twelve two-dimensional group-IV monochalcogenide monolayers (SiS, SiSe, SiTe, GeS, GeSe, GeTe, SnS, SnSe, SnTe, PbS, PbSe, and PbTe) with a buckled honeycomb atomistic structure--belonging to symmetry group P3m1--and an out-of-plane…

Materials Science · Physics 2021-02-24 Shiva P. Poudel , Salvador Barraza-Lopez

Prediction of high-$T_{\rm{c}}$ superconductivity in hole-doped Li$_x$BC two decades ago has brought about an extensive effort to synthesize new materials with honeycomb B-C layers, but the thermodynamic stability of Li-B-C compounds…

We present a first-principles study of bare and hydrogen passivated armchair nanoribbons of the puckered single layer honeycomb structures of silicon and germanium. Our study includes optimization of atomic structure, stability analysis…

Mesoscale and Nanoscale Physics · Physics 2010-12-21 S. Cahangirov , M. Topsakal , S. Ciraci

Thin nanowires of silicon oxide were studied by pseudopotential density functional electronic structure calculations using the generalized gradient approximation. Infinite linear and zigzag Si-O chains were investigated. A wire composed of…

Materials Science · Physics 2009-11-11 G. Bilalbegovic

Mono- and bi-alkali antimonides, X$_2$YSb (X and Y from Group I), are promising for next-generation electron emitters due to their capability of producing high-quality electron beams. However, these materials are not yet well understood, in…

Materials Science · Physics 2022-05-31 J. K. Nangoi , M. Gaowei , A. Galdi , J. M. Maxson , S. Karkare , J. Smedley , T. A. Arias

Si-Ge monolayers (SiGeM) with different elementary proportion x (0<x<1) were systematically studied for the first-time using ab initio calculations in this work. The structural stabilities of the Si1-xGexM with different symmetries were…

Materials Science · Physics 2020-04-07 Jiating Lu , Xi Zhang , Limeng Shen , Ya Nie , Gang Xiang