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Density-functional theory calculations are performed to investigate hydrogen transport in the proton conductor BaSnO$_3$. Structural optimizations in the stable and saddle point configurations for transfer and reorientation allow…

Materials Science · Physics 2014-11-13 Grégory Geneste , Alistar Ottochian , Jessica Hermet , Guilhem Dezanneau

Frequency dependence of the dielectric constant of complex perovskite oxide Ba(1-x)La(x)Ti(1-x)Cr(x)O3 (BLTC) ceramics with the composition ratio 0.4<= x <= 0.7 is precisely measured in the temperature range from 20 K to 300 K, and the…

Materials Science · Physics 2007-05-23 Mamoru Fukunaga , Yoshiaki Uesu

We investigate the relaxation and conduction mechanism of Ba0.90Sr0.10TiO3 (BST) ceramic, synthesized by the solid state reaction method. The dielectric and relaxation properties are analyzed in the temperature range of 380-450{\deg}C with…

Materials Science · Physics 2019-03-27 H. Zaitouni , L. Hajji , E. Choukri , D. Mezzane , Z. Abkhar , L. Essaleh , A. Alimoussa , M. El Marssi , I. A. Luk'yanchuk

A percolation transition in the vortex state of a superconducting 2H-NbSe2 crystal is observed in the regime where vortices form a heterogeneous phase consisting of ordered and disordered domains. The transition is signaled by a sharp…

Superconductivity · Physics 2009-11-11 O. Dogru , E. Y. Andrei , M. J. Higgins , S. Bhattacharya

Chalcogenide perovskites provide a promising avenue for non-toxic, stable thermoelectric materials. Here, thermal transport and thermoelectric properties of BaZrS$_3$ as a typical orthorhombic perovskite are investigated. An extremely low…

Materials Science · Physics 2023-12-14 Yu Wu , Ying Chen , Qiaoqiao Li , Kui Xue , Hezhu Shao , Hao Zhang , Liujiang Zhou

We have studied the low-temperature electrical transport properties of Pb$_x$(SiO$_2$)$_{1-x}$ ($x$ being the Pb volume fraction) nanogranular films with thicknesses of $\sim$1000 nm and $x$ spanning the dielectric, transitional, and…

Mesoscale and Nanoscale Physics · Physics 2019-03-27 Xiu-Zhi Duan , Zhi-Hao He , Yang Yang , Zhi-Qing Li

We develop a theory of far from the equilibrium transport in arrays of tunnel junctions. We find that if the rate of the electron-electron interactions exceeds the rate of the electron-phonon energy exchange, the energy relaxation ensuring…

Mesoscale and Nanoscale Physics · Physics 2009-12-10 N. M. Chtchelkatchev , V. M. Vinokur , T. I. Baturina

The energy landscape and diffusion barriers of protonic defects in Gd-doped BaCeO3, a compound candidate as electrolyte for protonic ceramic fuel cells, have been investigated by density functional theory calculations, starting from a…

Materials Science · Physics 2013-01-03 Jessica Hermet , Marc Torrent , François Bottin , Guilhem Dezanneau , Gregory Geneste

Dynamics of tunneling centers (TC) in metallic systems is studied, using the technique of bosonization. The interaction of the TC with the conduction electrons of the metal involves two processes, namely, the screening of the TC by…

Condensed Matter · Physics 2009-10-22 Tabish Qureshi

The molecular dynamics of solid benzene are extremely complex; especially below 77 K, its inner mechanics remain mostly unexplored. Benzene is also a prototypical molecular crystal that becomes energetically frustrated at low temperatures…

Chemical Physics · Physics 2017-03-07 F. Yen , S. Z. Huang , S. X. Hu , L. Y. Zhang , L. Chen

We report that the lowest energy transverse-optic phonon in metallic SnTe softens to near zero energy at the structural transition at $T_C=75 \text{~K}$ and importantly show that the energy of this mode below $T_C$ increases as the…

The tunneling reaction H$_2$ + D$^-$ $\rightarrow$ HD + H$^-$ was studied in a recent experimental work at low temperatures (10, 19, and 23~K) by Endres {\it et al.}, Phys. Rev. A {\bf 95}, 022706 (2017). An upper limit of the rate…

A new relaxation mechanism is shown to arise from overdamped two-level systems above a critical temperature $T^*\approx 5$ K, thus yielding an explanation for experimental observations in dielectric glasses in the temperature range between…

Condensed Matter · Physics 2009-10-22 Peter Neu , Alois Würger

We present a thorough dielectric investigation of the hexagonal perovskites La1.2Sr2.7IrO7.33 and La1.2Sr2.7RuO7.33 in a broad frequency and temperature range, supplemented by additional infrared measurements. The occurrence of giant…

Strongly Correlated Electrons · Physics 2016-08-16 P. Lunkenheimer , T. Götzfried , R. Fichtl , S. Weber , T. Rudolf , A. Loidl , A. Reller , S. G. Ebbinghaus

Perovskite structure materials based on the Ba1-xGdxTiO3 system, where x = 0.001, 0.002, 0.003, 0.004 and 0.005, were prepared via the Pechini chemical synthesis route. The dielectric properties have been analyzed over a wide temperature…

Materials Science · Physics 2024-09-25 T. H. T. Rosa , M. A. Oliveira , Y. Mendez-Gonzalez , F. Guerrero , R. Guo , A. S. Bhalla , J. D. S. Guerra

We report the nonlinear dielectric properties of three triple-perovskite ruthenates: Ba$_3$CoRu$_2$O$_9$, Ba$_3$BiRu$_2$O$_9$, and Sr$_3$CaRu$_2$O$_9$. These compounds exhibit notable correlations among their spin, charge, lattice, and…

Strongly Correlated Electrons · Physics 2023-07-26 Shruti Chakravarty , Sunil Nair

The composition-driven structural transition from the R3c to Pbnm symmetry was observed. Highest dielectric constant was observed for Bi0.95Nd0.05Fe0.95Mn0.05O3. Conductivity can be explained by the small polaron hopping model. The…

Materials Science · Physics 2015-12-10 Chandrakanta Panda , Pawan Kumar , A. K. Sinha , Archna Sagdeo , Manoranjan Kar

Several experiments conducted over decades have revealed that the perovskite-structured BaCeO3 goes through a series of temperature-induced structural phase transitions. However, it has been frequently observed that the number of phases and…

State-of-the-art hybrid perovskites have demonstrated excellent functionality in photovoltaics and light-emitting applications, and have emerged as a promising candidate for exciton-polariton (polariton) optoelectronics. In the strong…

The anelastic spectrum of calix[4]arene was measured at two different vibrational frequencies. Three thermally activated peaks were detected. The lowest temperature peak can be described considering a continous distribution function of…

Soft Condensed Matter · Physics 2009-11-07 A. Paolone , R. Cantelli , R. Caciuffo , A. Arduini
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