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Evidence implies that basic laws of thermodynamics must be tested by experiments. In this paper, an experiment is designed to measure the entropy of a system with at least one known (measurable) equation of state, especially the gas…

General Physics · Physics 2007-05-23 Bin Zhou

The fluctuation-dissipation relation tells that dissipation always accompanies with thermal fluctuations. Relativistic fluctuating hydrodynamics is used to study the effects of the thermal fluctuations in the hydrodynamic expansion of the…

Nuclear Theory · Physics 2019-02-20 Tetsufumi Hirano , Ryuichi Kurita , Koichi Murase

For a small driven system coupled strongly to a heat bath, internal energy and exchanged heat are identified such that they obey the usual additive form of the first law. By identifying this exchanged heat with the entropy change of the…

Statistical Mechanics · Physics 2016-02-03 Udo Seifert

Physical devices operating out of equilibrium are inherently affected by thermal fluctuations, limiting their operational precision. This issue is pronounced at microscopic and especially quantum scales and can only be mitigated by…

It exists a large class of systems for which the traditional notion of extensivity breaks down. From experimental examples we induce two general hypothesis concerning such systems. In the first the existence of an internal coordinate system…

Statistical Mechanics · Physics 2015-03-09 J-P. Badiali , A. El Kaabouchi

We consider the basic, thermodynamic properties of an elementary micro-machine operating at colloidal length scales. In particular, we track and analyse the driven stochastic motion of a carefully designed micro-propeller rotating unevenly…

Soft Condensed Matter · Physics 2020-08-04 Stuart J. Box , Michael P. Allen , David B. Phillips , Stephen H. Simpson

The Modified Fluctuation Dissipation Theorem (MFDT) proposed by G. Verley et al. {\it (EPL 93, 10002, (2011))} for non equilibrium transient states is experimentally studied. We apply MFDT to the transient relaxation dynamics of the…

Statistical Mechanics · Physics 2015-09-30 Isaac Theurkauff , Aude Caussarieu , Artyom Petrosyan , Sergio Ciliberto

The experimental verification of the Fluctuation Theorem by Wang et al. is not a violation but even a confirmation of the second law, resulting from their observations in a proper interpretation.

Condensed Matter · Physics 2007-05-23 Theo M. Nieuwenhuizen , Armen E. Allahverdyan

Thermodynamics is usually developed starting from entropy and the maximum entropy principle. We investigate here to what extent one can replace entropy with relative entropy which has several advantages, for example in the context of local…

Statistical Mechanics · Physics 2020-11-17 Stefan Floerchinger , Tobias Haas

Heat, work and entropy production: the statistical distribution of such quantities are constrained by the fluctuation theorems (FT), which reveal crucial properties about the nature of non-equilibrium dynamics. In this paper we report…

Quantum Physics · Physics 2021-10-15 K. Khan , J. Sales Araújo , W. F. Magalhães , G. H. Aguilar , B. de Lima Bernardo

Fluctuation theorems are fundamental extensions of the second law of thermodynamics for small nonequilibrium systems. While work and heat are equally important forms of energy exchange, fluctuation relations have not been experimentally…

Statistical Mechanics · Physics 2022-02-24 Markus Rademacher , Michael Konopik , Maxime Debiossac , David Grass , Eric Lutz , Nikolai Kiesel

We analyse diffusion at low temperature by bringing the fluctuation-dissipation theorem (FDT) to bear on a physically natural, viscous response-function R(t). The resulting diffusion-law exhibits several distinct regimes of time and…

Statistical Mechanics · Physics 2018-05-03 Urbashi Satpathi , Supurna Sinha , Rafael D. Sorkin

A major part of the many thermally driven processes in our natural environment as well as in engineering solutions of Carnot-type machinery is based on the second law of thermodynamics (or principle of entropy increase). An interesting link…

General Physics · Physics 2010-09-29 Hans R. Moser

Fluctuation theorems impose constraints on the probability of observing negative entropy production in small systems driven out of equilibrium. The range of validity of fluctuation theorems has been extensively tested for transitions…

Statistical Mechanics · Physics 2015-04-21 Léo Granger , Jumna Mehlis , Édgar Roldán , Sergio Ciliberto , Holger Kantz

We present a general framework for systems which are prepared in a non-stationary non-equilibrium state in the absence of any perturbation, and which are then further driven through the application of a time-dependent perturbation. We…

Statistical Mechanics · Physics 2012-12-06 Gatien Verley , David Lacoste

The Heat theorem reveals the second law of equilibrium Thermodynamics (i.e.existence of Entropy) as a manifestation of a general property of Hamiltonian Mechanics and of the Ergodic Hypothesis, valid for 1 as well as $10^{23}$ degrees of…

Statistical Mechanics · Physics 2008-02-01 Giovanni Gallavotti

The fluctuation theorem is the fundamental equality in nonequilibrium thermodynamics that is used to derive many important thermodynamic relations, such as the second law of thermodynamics and the Jarzynski equality. Recently, the…

Statistical Mechanics · Physics 2019-09-16 Yoshihiko Hasegawa , Tan Van Vu

Based on trajectory dependent path probability formalism in state space, we derive generalized entropy production fluctuation relations for a quantum system in the presence of measurement and feedback. We have obtained these results for…

Statistical Mechanics · Physics 2015-06-04 Shubhashis Rana , Sourabh Lahiri , A. M. Jayannavar

We prove the second law of thermodynamics and the nonequilibirum fluctuation theorem for pure quantum states.The entire system obeys reversible unitary dynamics, where the initial state of the heat bath is not the canonical distribution but…

Statistical Mechanics · Physics 2017-09-13 Eiki Iyoda , Kazuya Kaneko , Takahiro Sagawa

A manifestly covariant, coordinate independent reformulation of the Thermodynamic Field Theory (TFT) is presented. The TFT is a covariant field theory that describes the evolution of a thermodynamic system, extending the near-equilibrium…

Statistical Mechanics · Physics 2015-06-25 Giorgio Sonnino , Jarah Evslin