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A first step toward a universal nuclear energy density functional based on low-momentum interactions is taken using the density matrix expansion (DME) of Negele and Vautherin. The DME is adapted for non-local momentum-space potentials and…

Nuclear Theory · Physics 2009-11-13 S. K. Bogner , R. J. Furnstahl , L. Platter

Quantum embedding methods enable the study of large, strongly correlated quantum systems by (usually self-consistent) decomposition into computationally manageable subproblems, in the spirit of divide-and-conquer methods. Among these,…

Strongly Correlated Electrons · Physics 2025-03-14 Alicia Negre , Fabian Faulstich , Raehyun Kim , Thomas Ayral , Lin Lin , Eric Cancès

Density matrix embedding theory (DMET) provides a theoretical framework to treat finite fragments in the presence of a surrounding molecular or bulk environment, even when there is significant correlation or entanglement between the two. In…

Chemical Physics · Physics 2016-11-29 Sebastian Wouters , Carlos A. Jiménez-Hoyos , Qiming Sun , Garnet Kin-Lic Chan

We extend our density matrix embedding theory (DMET) [Phys. Rev. Lett. 109 186404 (2012)] from lattice models to the full chemical Hamiltonian. DMET allows the many-body embedding of arbitrary fragments of a quantum system, even when such…

Strongly Correlated Electrons · Physics 2013-11-15 Gerald Knizia , Garnet Kin-Lic Chan

Density matrix embedding theory (DMET) describes finite fragments in the presence of a surrounding environment. In contrast to most embedding methods, DMET explicitly allows for quantum entanglement between both. In this chapter, we discuss…

Strongly Correlated Electrons · Physics 2018-02-19 Sebastian Wouters , Carlos A. Jiménez-Hoyos , Garnet K. -L. Chan

We introduce DMET, a new quantum embedding theory for predicting ground-state properties of infinite systems. Like dynamical mean-field theory (DMFT), DMET maps the the bulk interacting system to a simpler impurity model and is exact in the…

Strongly Correlated Electrons · Physics 2015-03-20 Gerald Knizia , Garnet Kin-Lic Chan

We study the structure of the time evolution of the density matrix in contact with a thermal bath in a standard projection operator sheme. The reduced density matrix of the system in the steady state is obtained by tracing out the degree of…

Statistical Mechanics · Physics 2009-05-04 Takashi Mori , Seiji Miyashita

We describe a method to obtain the reduced density matrix (RDM) correct up to second order in system-bath coupling in \emph{nonequilibrium} steady state situations. The RDM is obtained via a scheme based on analytic continuation, using the…

Statistical Mechanics · Physics 2013-11-22 Juzar Thingna , Jian-Sheng Wang , Peter Hänggi

Spins in molecular magnets can experience both anisotropic exchange interactions and on-site magnetic anisotropy. In this paper we study the effect of exchange anisotropy on the molecular magnetic anisotropy both with and without on-site…

Materials Science · Physics 2018-12-12 Sumit Haldar , Rajamani Raghunathan , Jean-Pascal Sutter , S. Ramasesha

We present a quantum Monte Carlo method capable of sampling the full density matrix of a many-particle system at finite temperature. This allows arbitrary reduced density matrix elements and expectation values of complicated non-local…

Computational Physics · Physics 2015-06-15 N. S. Blunt , T. W. Rogers , J. S. Spencer , W. M. C. Foulkes

This thesis describes the development of the density matrix embedding theory (DMET) and its applications to lattice strongly correlated electron problems, including a review of DMET theory and algorithms (Ch 2), investigation of finite size…

Strongly Correlated Electrons · Physics 2018-03-29 Bo-Xiao Zheng

This chapter takes a microscopic view of quantum tunneling of magnetization (QTM) in single-molecule magnets (SMMs), focusing on the interplay between exchange and anisotropy. Careful consideration is given to the relationship between…

Mesoscale and Nanoscale Physics · Physics 2013-03-04 Junjie Liu , Enrique del Barco , Stephen Hill

Linear magnetization dynamics in the presense of a thermal bath is analyzed for two general classes of microscopic damping mechanisms. The resulting stochastic differential equations are always in the form of a damped harmonic oscillator…

Statistical Mechanics · Physics 2007-05-23 Vladimir L. Safonov , H. Neal Bertram

This article provides the first mathematical analysis of the Density Matrix Embedding Theory (DMET) method. We prove that, under certain assumptions, (i) the exact ground-state density matrix is a fixed-point of the DMET map for…

Mathematical Physics · Physics 2023-10-03 Eric Cancès , Fabian M. Faulstich , Alfred Kirsch , Eloïse Letournel , Antoine Levitt

A new variational method for studying the equilibrium states of an interacting particles system has been proposed. The statistical description of the system is realized by means of a density matrix. This method is used for description of…

General Physics · Physics 2014-12-19 Boris Bondarev

Microscopic input to a universal nuclear energy density functional can be provided through the density matrix expansion (DME), which has recently been revived and improved. Several DME implementation strategies are tested for neutron drop…

Nuclear Theory · Physics 2013-05-29 S. K. Bogner , R. J. Furnstahl , H. Hergert , M. Kortelainen , P. Maris , M. Stoitsov , J. P. Vary

We clarify different definitions of the density matrix by proposing the use of different names, the full density matrix for a single-closed quantum system, the compressed density matrix for the averaged single molecule state from an…

Quantum Physics · Physics 2007-05-23 Gui Lu Long , Yi-Fan Zhou , Jia-Qi Jin , Yang Sun , Hai-Woong Lee

Investigations of molecular magnets are driven both by prospective applications in future storage technology or quantum computing as well as by fundamental questions. Nowadays numerical simulation techniques and computer capabilities make…

Strongly Correlated Electrons · Physics 2009-10-08 J. Schnack

We describe a numerical algorithm for approximating the equilibrium-reduced density matrix and the effective (mean force) Hamiltonian for a set of system spins coupled strongly to a set of bath spins when the total system (system+bath) is…

Quantum Physics · Physics 2023-01-25 Tyler Chen , Yu-Chen Cheng

Density matrix embedding theory (DMET) provides a framework to describe ground-state expectation values in strongly correlated systems, but its extension to dynamical quantities is still an open problem. We show one route to obtaining…

Strongly Correlated Electrons · Physics 2025-11-13 Shuoxue Li , Chenghan Li , Huanchen Zhai , Garnet Kin-Lic Chan
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