Related papers: Size Dependent Phase Transitions
In one of the most celebrated examples of the theory of universal critical phenomena, the phase transition to the superfluid state of $^{4}$He belongs to the same three dimensional $\mathrm{O}(2)$ universality class as the onset of…
We study the critical droplet for a close-to-equilibrium Widom-Rowlinson model of interacting particles, represented by disks of radius $1$, in the two-dimensional plane at low temperature. The critical droplet is the set of macroscopic…
Kinetics of the first order phase transition has been investigated. The case when the droplets sizes have a limit value is considered. An analytical theory for such process has been constructed and all main characteristics of the process…
The Clausius-Clapeyron relation and its analogs in other first-order phase transitions, such as type-I superconductors, are derived using very elementary methods, without appealing to the more advanced concepts of entropy or Gibbs free…
In the Leidenfrost effect a small drop of fluid is levitated above a sufficiently hot surface, on a persistent vapor layer generated by evaporation from the drop. The vapor layer thermally insulates the drop from the surface leading to…
The deformation of a viscous liquid droplet suspended in another liquid and subject to an applied electric field is a classic multiphase flow problem best described by the Melcher-Taylor leaky dielectric model. The main assumption of the…
Direct numerical simulations are used to investigate the individual dynamics of large spherical particles suspended in a developed homogeneous turbulent flow. A definition of the direction of the particle motion relative to the surrounding…
Manipulating surface topography is one of the most promising strategies for increasing the efficiency of numerous industrial processes involving droplet contact with superheated surfaces. In such scenarios, the droplets may immediately boil…
In this work, we studied the effect of the diameter of horizontal hydrophobic cylinders on droplet growth. We postulate that the concentration gradient created by natural convection around a horizontal circular cylinder is related to the…
The formation of small droplets and bubbles in turbulent flows is a crucial process in geophysics and engineering, whose underlying physical mechanism remains a puzzle. In this letter, we address this problem by means of high-resolution…
Three-dimensional, time-dependent direct simulations of step emulsification micro-devices highlight two essential mechanisms for droplet formation: first, the onset of an adverse pressure gradient driving a back-flow of the continuous phase…
Crystal growth of semiconductor nanowires from a liquid droplet depends on the stability of this droplet at the liquid-solid interface. By combining in-situ transmission electron microscopy with theoretical analysis of the surface energies…
Surface tension plays a ubiquitous role in phase transitions including condensation or evaporation of atmospheric liquid droplets. Especially, understanding of interfacial thermodynamics of the critical nucleus of 1 nm scale is important…
A theoretical model of vapor-liquid phase transition in a system of charged hard cores of different diameters is suggested (with the parameters of the transition obtained in a number of studies using the Monte Carlo method). The model is…
The thermodynamic non-equilibrium (TNE) effects and the relationships between various TNE effects and entropy production rate, morphology, kinematics, and dynamics during two initially static droplet coalescence are studied in detail via…
We consider a spherical particle levitating above a liquid bath owing to the Leidenfrost effect, where the vapour of either the bath or sphere forms an insulating film whose pressure supports the sphere's weight. Starting from a reduced…
We numerically study the coalescence dynamics of two sessile droplets with radii $R_0$. The droplets are placed on top of a rigid substrate with a contact angle of $\theta_{eq.} = \pi/9$. Having a highly wettable substrate ($\theta_{eq} \ll…
Classical continuum-based liquid vapour phase-change models typically assume continuity of temperature at phase interfaces along with a relation which describes the rate of evaporation at the interface (Hertz-Knudsen-Schrage, for example).…
Depletion of the liquid density near a solid surface with a weak long-range fluid-surface interaction was studied by computer simulations of the liquid-vapor coexistence of a LJ fluid confined in slitlike pores. In a wide temperature range…
The size and composition distribution of an ensemble of aqueous organic droplets, evolving via nucleation and concomitant chemical aging, may be affected by the latent heat of condensation and enthalpy of heterogeneous chemical reactions,…