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We present the formulation and implementation of triples correction scheme to the relativistic equation-of-motion coupled-cluster method for ionization potential. Both full and partial triples correction schemes are implemented using the…

Chemical Physics · Physics 2026-03-31 Mrinal Thapa , Achinyta Kumar Dutta

In the cluster expansion framework of Bose liquids we calculate analytical expressions of the two-body, three-body and four-body diagrams contributing to the g.s. energy of an infinite system of neutral alpha-particles at zero-temperature,…

Nuclear Theory · Physics 2015-03-17 F. Carstoiu , S Misicu , V. Balanica , M. Lassaut

In this chapter we focus first on the theoretical methods and relevant computational approaches to calculate the electronic structure of atoms, molecules, and clusters containing heavy elements for which relativistic effects become…

Chemical Physics · Physics 2021-10-05 Simone Taioli , Stefano Simonucci

We develop an approach of calculating the many-body path integral based on the linked cluster expansion method. First, we derive a linked cluster expansion and we give the diagrammatic rules for calculating the free-energy and the pair…

Statistical Mechanics · Physics 2019-12-04 Anish Bhardwaj , Efstratios Manousakis

The standard and renormalized coupled cluster methods with singles, doubles, and noniterative triples and their generalizations to excited states, based on the equation of motion coupled cluster approach, are applied to the He-4 and O-16…

Nuclear Theory · Physics 2009-11-10 K. Kowalski , D. J. Dean , M. Hjorth-Jensen , T. Papenbrock , P. Piecuch

With increasing demand for accurate calculation of isotope shifts of atomic systems for fundamental and nuclear structure research, an analytic energy derivative approach is presented in the relativistic coupled-cluster theory framework to…

We investigate the convergence of coupled-cluster correlation energies and related quantities with respect to the employed basis set size for the uniform electron gas to gain a better understanding of the basis set incompleteness error. To…

Materials Science · Physics 2024-02-27 Nikolaos Masios , Felix Hummel , Andreas Grüneis , Andreas Irmler

The triplet contribution is computed to the 1 and 2 $^1S^\text{e}_0$ states of the He atom, to the $1\ ^1S^\text{e}_0$ state of the Li$^+$ and Be${^{2+}}$ ions, and to the $X\ ^1\Sigma_\text{g}^+$ ground state of the H$_2$ molecule by…

Atomic Physics · Physics 2023-01-25 Péter Jeszenszki , Edit Mátyus

We present a generalization of the recently proposed variational cluster perturbation theory to extended Hubbard models at half filling with repulsive nearest neighbor interaction. The method takes into account short-range correlations…

Strongly Correlated Electrons · Physics 2009-11-10 M. Aichhorn , H. G. Evertz , W. von der Linden , M. Potthoff

We investigate the order-by-order convergence behavior of many-body perturbation theory (MBPT) as a simple and efficient tool to approximate the ground-state energy of closed-shell nuclei. To address the convergence properties directly, we…

Nuclear Theory · Physics 2016-04-20 Alexander Tichai , Joachim Langhammer , Sven Binder , Robert Roth

We demonstrate an iterative scheme for coupled-cluster properties calculations without truncating the dressed properties operator. For validation, magnetic dipole hyperfine constants of alkaline Earth ions are calculated with relativistic…

Atomic Physics · Physics 2010-04-22 B. K. Mani , D. Angom

A wide class of coupled-cluster methods is introduced, based on Arponen's extended coupled-cluster theory. This class of methods is formulated in terms of a coordinate transformation of the cluster operators. The mathematical framework for…

Chemical Physics · Physics 2020-12-02 Simen Kvaal , Andre Laestadius , Tilmann Bodenstein

In this paper, we rigorously study an order 2 scheme that was previously proposed by some of the authors. A slight modification is proposed that enables us to prove the convergence of the scheme while simplifying in the same time the inner…

Numerical Analysis · Mathematics 2015-06-05 François Alouges , Evaggelos Kritsikis , Jutta Steiner , Jean-Christophe Toussaint

Systematic QED calculations of ionization energies of the $2s$, $2p_{1/2}$, and $2p_{3/2}$ states, as well as the $2p_{1/2}$--$2s$ and $2p_{3/2}$--$2p_{1/2}$ transition energies are performed for Li-like ions with the nuclear charge numbers…

Atomic Physics · Physics 2025-10-09 V. A. Yerokhin , Z. Harman , C. H. Keitel

We present a study of the two dimensional circular quantum dot model Hamiltonian using a range of quantum chemical ab initio methods. Ground and excited state energies are computed on different levels of perturbation theories including the…

Chemical Physics · Physics 2022-03-23 Faruk Salihbegović , Alejandro Gallo , Andreas Grüneis

We revisit a unified methodology for the iterative solution of nonlinear equations in Hilbert spaces. Our key observation is that the general approach from [Heid & Wihler, Math. Comp. 89 (2020), Calcolo 57 (2020)] satisfies an energy…

Numerical Analysis · Mathematics 2021-02-18 Pascal Heid , Dirk Praetorius , Thomas P. Wihler

We present first-principle numerical calculations for few particle solutions of the attractive Bose-Hubbard model with periodic boundary conditions. We show that the low-energy many-body states found by numerical diagonalization can be…

Quantum Gases · Physics 2012-04-23 Ole Søe Sørensen , Søren Gammelmark , Klaus Mølmer

We focus here on a class of fourth-order parabolic equations that can be written as a system of second-order equations by introducing an auxiliary variable. We design a novel second-order fully discrete mixed finite element method to…

Numerical Analysis · Mathematics 2020-08-28 Sana Keita , Abdelaziz Beljadid , Yves Bourgault

In this contribution we present calculations performed for interacting electron systems within a non-perturbative formulation of the cluster theory. Extrapolation of the model to describe the time dependence of the interacting systems is…

Atomic Physics · Physics 2009-11-13 M. Tomaselli , T. Kuehl , D. Ursescu , S. Fritzsche

High-energy nuclear collisions have opened a new experimental method to reveal collective behavior in nuclear ground states through the lens of many-body correlations of nucleons. Using ab initio lattice and variational calculations of…

Nuclear Theory · Physics 2025-12-23 Jean-Paul Blaizot , Giuliano Giacalone , Alessandro Lovato