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Ab initio calculations have been carried out to study the magnetic dipole and electric quadrupole hyperfine structure constants of $^{205}$Pb$^+$. Many-body effects have been considered to all orders using the relativistic coupled-cluster…

Atomic Physics · Physics 2015-06-26 Sonjoy Majumder , B. K. Sahoo , R. K. Chaudhuri , B. P. Das , D. Mukherjee

A practical high-accuracy relativistic method of atomic structure calculations for univalent atoms is presented. The method is rooted in the coupled-cluster formalism and includes non-perturbative treatment of single and double excitations…

Atomic Physics · Physics 2009-11-11 Sergey G. Porsev , Andrei Derevianko

This work presents a first time accurate calculation of the magnetic dipole hyperfine structure constants for the ground state and some low-lying excited states of Pb$^+$. By comparing different levels of approximation with experimental…

Atomic Physics · Physics 2009-11-10 Bijaya K. Sahoo , Rajat K. Chaudhuri , B. P. Das , Holger Merlitz , Debashis Mukherjee

We consider evaluation of matrix elements with the coupled-cluster method. Such calculations formally involve infinite number of terms and we devise a method of partial summation (dressing) of the resulting series. Our formalism is built…

Atomic Physics · Physics 2009-11-10 Andrei Derevianko , Sergey Porsev

The coupled-cluster method is applied to the spin-1/2 antiferromagnetic XXZ model on a square lattice by employing an approximation which contains two-body long-range correlations and high-order four-body local correlations. Improvement is…

Strongly Correlated Electrons · Physics 2015-05-28 Mohammad Merdan , Y. Xian

Energy levels of 30 low-lying states of Lu2+ and allowed electric-dipole matrix elements between these states are evaluated using a relativistic all-order method in which all single, double and partial triple excitations of Dirac-Fock wave…

Atomic Physics · Physics 2016-09-14 U. I. Safronova , M. S. Safronova , W. R. Johnson

Electric-dipole matrix elements for ns-n'p, nd-n'p, and 6d-4f transitions in Rb are calculated using a relativistic all-order method. A third-order calculation is also carried out for these matrix elements to evaluate the importance of the…

Atomic Physics · Physics 2009-11-10 M. S. Safronova , Carl J. Williams , Charles W. Clark

We derive coupled-cluster equations for three-body Hamiltonians. The equations for the one- and two-body cluster amplitudes are presented in a factorized form that leads to an efficient numerical implementation. We employ low-momentum two-…

Nuclear Theory · Physics 2008-11-26 G. Hagen , T. Papenbrock , D. J. Dean , A. Schwenk , A. Nogga , M. Wloch , P. Piecuch

We present relativistic coupled-cluster (CC) calculations of energies, magnetic-dipole hyperfine constants, and electric-dipole transition amplitudes for low-lying states of atomic boron. The trivalent boron atom is computationally treated…

Atomic Physics · Physics 2015-06-05 H. Gharibnejad , A. Derevianko

Extensive calculations of the electric-dipole matrix elements in alkali-metal atoms are conducted using the relativistic all-order method. This approach is a linearized version of the coupled-cluster method, which sums infinite sets of…

Atomic Physics · Physics 2009-11-13 Bindiya Arora , M. S. Safronova , Charles W. Clark

An electrodynamical coupled cluster (CC) methodology starting from a covariant formalism and an equal time approximation, and finally based on the Dirac-Fock picture of the electron and positron fields and Coulomb gauge, is given here. The…

Atomic Physics · Physics 2019-04-30 Sambhu N. Datta

We apply high-order many-body perturbation theory for the calculation of ground-state energies of closed-shell nuclei using realistic nuclear interactions. Using a simple recursive formulation, we compute the perturbative energy…

Nuclear Theory · Physics 2010-02-03 Robert Roth , Joachim Langhammer

We have developed an all particle Fock-space relativistic coupled-cluster method for two-valence atomic systems. We then describe a scheme to employ the coupled-cluster wave function to calculate atomic properties. Based on these…

Atomic Physics · Physics 2011-01-11 B. K. Mani , D. Angom

A variational solution procedure is reported for the many-particle no-pair Dirac-Coulomb-Breit Hamiltonian aiming at a parts-per-billion (ppb) convergence of the atomic and molecular energies, described within the fixed nuclei…

Quantum Physics · Physics 2024-06-19 Péter Jeszenszki , Dávid Ferenc , Edit Mátyus

We have carried out a detailed and systematic study of the correlation energies of inert gas atoms Ne, Ar, Kr and Xe using relativistic many-body perturbation theory and relativistic coupled-cluster theory. In the relativistic…

Atomic Physics · Physics 2009-12-29 B. K. Mani , D. Angom

Energies of (2s2 2p5 3l3l') and (2s 2p6 3l3l') states for sodiumlike ions with Z =14--100 are evaluated to second order in relativistic many-body perturbation theory starting from a neonlike Dirac-Fock potential. Second-order Coulomb and…

Atomic Physics · Physics 2009-11-07 U. I. Safronova , W. R. Johnson , M. S. Safronova , J. R. Albritton

We tabulate angularly reduced fourth-order many-body corrections to matrix elements for univalent atoms, derived in [A. Derevianko and E.D. Emmons, Phys. Rev. A 65, 052115 (2002)]. In particular we focused on practically important diagrams…

Atomic Physics · Physics 2007-05-23 Andrei Derevianko

An algorithm, based on numerical description of the terms of many-body perturbation theory (Goldstone diagrams), is presented. The algorithm allows the use of the same piece of computer code to evaluate any particular diagram in any…

Atomic Physics · Physics 2015-05-13 V. A. Dzuba

We numerically examine divergences of the total energy in metallic systems of approximate many-body theories using Hartree--Fock as a reference, including perturbative (M\oller-Plesset, MP), coupled cluster (CC) and configuration…

Chemical Physics · Physics 2012-08-31 James J. Shepherd , Andreas Grüneis

Energy levels, wavelengths, magnetic-dipole and electric-quadrupole transition rates between the low-lying states are evaluated for W$^{51+}$ to W$^{54+}$ ions with $3d^n$ (n = 2 to 5) electronic configurations using an approach combining…

Atomic Physics · Physics 2018-01-10 M. S. Safronova , U. I. Safronova , S. G. Porsev , M. G. Kozlov , Yu. Ralchenko
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