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NMR spin echo measurements of C-13 in C60, Y-89 in Y2O3, and Si-29 in silicon are shown to defy conventional expectations when more that one pi pulse is used. Multiple pi-pulse echo trains may either freeze our or accelerate the decay of…

Quantum Physics · Physics 2007-05-23 Dale Li , A. E. Dementyev , Yanqun Dong , R. G. Ramos , S. E. Barrett

In spectroscopy, it is conventional to treat pulses much stronger than the linewidth as delta-functions. In NMR, this assumption leads to the prediction that pi pulses do not refocus the dipolar coupling. However, NMR spin echo measurements…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Dale Li , Yanqun Dong , R. G. Ramos , J. D. Murray , K. MacLean , A. E. Dementyev , S. E. Barrett

Coherent control is an optical technique to manipulate quantum states of matter. The coherent control of 40-THz optical phonons in diamond was demonstrated by using a pair of sub-10-fs optical pulses. The optical phonons were detected via…

I describe composite pulses during which the average dipolar interactions within a spin ensemble are controlled while realizing a global rotation. The construction method used is based on the average Hamiltonian theory and rely on the…

Other Condensed Matter · Physics 2016-10-18 Emmanuel Baudin

Pulsed magnetic resonance is a wide-reaching technology allowing the quantum state of electronic and nuclear spins to be controlled on the timescale of nanoseconds and microseconds respectively. The time required to flip either dilute…

We investigate the theoretically achievable fidelities when coherently controlling an effective three qubit system consisting of a negatively charged nitrogen vacancy (NV$^-$) center in diamond with an additional nearby carbon $^{13}$C spin…

Quantum Physics · Physics 2014-09-29 Burkhard Scharfenberger , William J. Munro , Kae Nemoto

Detecting and controlling nuclear spin nano-ensembles is crucial for the further development of nuclear magnetic resonance (NMR) spectroscopy and for the emerging solid state quantum technology. Here we present the fabrication of a…

The efficiency of dipole-dipole coupling driven coherence transfer experiments in solid-state NMR spectroscopy of powder samples is limited by dispersion of the orientation of the internuclear vectors relative to the external magnetic…

Quantum Physics · Physics 2009-11-13 N. Khaneja , C. Kehlet , S. J. Glaser , N. C. Nielsen

The past decade has demonstrated increasing interests in using optimal control based methods within coherent quantum controllable systems. The versatility of such methods has been demonstrated with particular elegance within nuclear…

Quantum Physics · Physics 2015-05-18 Ivan I. Maximov , Niels Chr. Nielsen , Julien Salomon , Gabriel Turinici

Incoherence in the controlled Hamiltonian is an important limitation on the precision of coherent control in quantum information processing. Incoherence can typically be modelled as a distribution of unitary processes arising from slowly…

Quantum Physics · Physics 2009-11-10 N. Boulant , S. Furuta , J. Emerson , T. F. Havel , D. G. Cory

Errors in the control of quantum systems may be classified as unitary, decoherent and incoherent. Unitary errors are systematic, and result in a density matrix that differs from the desired one by a unitary operation. Decoherent errors…

We describe a method for improving coherent control through the use of detailed knowledge of the system's Hamiltonian. Precise unitary transformations were obtained by strongly modulating the system's dynamics to average out unwanted…

We show how it is possible to suppress decoherence using tailored external forcing acting as pulses. In the limit of infinitely frequent pulses decoherence and dissipation are completely frozen; however, a significant decoherence…

Quantum Physics · Physics 2009-10-31 David Vitali , Paolo Tombesi

Relaxation effects impose fundamental limitations on our ability to coherently control quantum mechanical phenomena. In this letter, we establish physical limits on how closely can a quantum mechanical system be steered to a desired target…

Quantum Physics · Physics 2009-11-10 N. Khaneja , B. Luy , S. J. Glaser

Conical intersections (CI) between molecular potential energy surfaces with non-vanishing non-adiabatic couplings generally occur in any molecule consisting of at least three atoms. They play a fundamental role in describing the molecular…

The prospect of developing magnetic qubits is discussed. The first part of the article makes suggestions on how to achieve the coherent quantum superposition of spin states in small ferromagnetic clusters, weakly uncompensated…

Statistical Mechanics · Physics 2007-05-23 Eugene M. Chudnovsky

We explore the physical limits of pulsed dynamical decoupling methods for decoherence control as determined by finite timing resources. By focusing on a decohering qubit controlled by arbitrary sequences of $\pi$-pulses, we establish a…

Quantum Physics · Physics 2011-04-11 Kaveh Khodjasteh , Tamás Erdélyi , Lorenza Viola

Composite Pulses (CPs) are widely used in Nuclear Magnetic Resonance (NMR), optical spectroscopy, optimal control experiments and quantum computing to manipulate systems that are well-described by a two-level Hamiltonian. A careful design…

Quantum Physics · Physics 2025-07-03 Jonathan Berkheim , David J. Tannor

Over recent decades, the value of conducting experiments at lower frequencies and in inhomogeneous and/or time-variable fields has grown. For example, an interest in the nanoscale heterogeneities of hydration dynamics demands increasingly…

Chemical Physics · Physics 2022-11-23 Alec A. Beaton , Alexandria Guinness , John M. Franck

Being the key resource in quantum physics, the proper quantification of coherence is of utmost importance. Amid complex-looking functionals in quantifying coherence, we set forth a simple and easy-to-evaluate approach: Principal diagonal…

Quantum Physics · Physics 2023-02-08 Manis Hazra , Debabrata Goswami
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