Related papers: Potassium ground state scattering parameters and B…
Asymptotic levels of the A $^1\Sigma_u^+$ state of the two isotopomers $^{39}{\rm K}_2$ and $^{39}{\rm K}^{41}{\rm K}$ up to the dissociation limit are investigated with a Doppler-free high resolution laser-spectroscopic experiment in a…
We demonstrate high accuracy calculations for the HeH$^+$ molecule using newly developed analytic formulas for two-center two-electron integrals with exponential functions. The Born-Oppenheimer potential for the ground electronic…
We report on high resolution Fourier-transform spectroscopy of fluorescence to the a^3\Sigma_u^+ state excited by two-photon or two-step excitation from the X^1\Sigma_g^+ state to the 2^3\Pi_g state in the molecule K_2. These spectroscopic…
An experimental study of the long range behavior of the ground state X^1\Sigma^+_g of Sr_2 is performed by high resolution spectroscopy of asymptotic vibrational levels and the use of available photoassociation data. Ground state levels as…
Accurate $EF{}^1\Sigma^+_g-X{}^1\Sigma^+_g$ transition energies in molecular hydrogen were determined for transitions originating from levels with highly-excited vibrational quantum number, $v=11$, in the ground electronic state.…
The Born-Oppenheimer potential for the $^1\Sigma_g^+$ state of H$_2$ is obtained in the range of 0.1 -- 20 au, using analytic formulas and recursion relations for two-center two-electron integrals with exponential functions. For small…
We report here oscillator strengths, transition rates, branching ratios and lifetimes due to allowed transitions in potassium (K) atom. We evaluate electric dipole (E1) amplitudes using an all order relativistic many-body perturbation…
A comprehensive study of the electronic states at the 4s+5s asymptote in KRb is presented. Abundant spectroscopic data on the \astate state were collected by Fourier-transform spectroscopy which allow to determine an accurate experimental…
Using the polarisation labelling spectroscopy, we performed the detailed analysis of the level structure of excited electronic states of the $^{39}$KCs molecule in the excitation energy interval between 17500~cm$^{-1}$ and 18600~cm$^{-1}$…
High-resolution spectroscopy on the $A^2\Pi$ - $X^2\Sigma^+$ electronic system of $^{138}$Ba$^{19}$F is performed using a cold molecular beam produced by a buffer gas source. The hyperfine structure in both $X^2\Sigma^+$ ground and $A^2\Pi$…
We report on spectroscopic studies of hot and ultracold RbSr molecules, and combine the results in an analysis that allows us to fit a potential energy curve (PEC) for the X(1)$^2\Sigma^+$ ground state bridging the short-to-long-range…
We report on a high-resolution spectroscopic survey of ${}^{6}\textrm{Li}{}^{40}\textrm{K}$ molecules near the $2\textrm{S}+4\textrm{P}$ dissociation threshold and produce a fully empirical representation for the $\textrm{B}^{1}\Pi$…
We report on highly accurate calculations of Born-Oppenheimer potentials for excited $n\,\Sigma^{+}$ states of the hydrogen molecule for all possible combinations of singlet/triplet and gerade/ungerade symmetries up to $n=7$. A relative…
We investigated transition strengths from ultracold weakly bound 41K87Rb molecules produced via the photoassociation of laser-cooled atoms. An accurate potential energy curve of the excited state (3)1Sigma+ was constructed by carrying out…
Basics of the Born-Oppenheimer (B-O) approximation are reviewed. Assuming the domain of applicability of B-O approximation is limited to 4 significant digits (s.d.) in energy spectrum, where mass, relativistic and QED corrections do NOT…
By two-color photoassociation of $^{40}$Ca four weakly bound vibrational levels in the Ca$_2$ \Xpot ground state potential were measured, using highly spin-forbidden transitions to intermediate states of the coupled system $^3\Pi_{u}$ and…
We optically probe the spectrum of ground and excited state transitions of an individual, electrically tunable self-assembled quantum dot molecule. Photocurrent absorption measurements show that the spatially direct neutral exciton…
Vibrational branching ratios in the B$^2\Sigma^+$ -- X$^2\Sigma^+$ and A$^2\Pi$ -- X$^2\Sigma^+$ optical-cycling transitions of BaH molecules are investigated using measurements and {\it ab initio} calculations. The experimental values are…
The filtered laser excitation technique was applied for measuring transition frequencies of the Ca$_2$ B-X system from asymptotic levels of the X$^1\Sigma_{\mathrm g}^{+}$ ground state reaching $v''=38$. That level has an outer classical…
We present a comprehensive study of electron collisions with calcium atoms by using the convergent \emph{B}-spline \emph{R}-matrix method. Elastic, excitation, and ionization cross sections were obtained for all transitions between the…