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Related papers: Daubechies wavelets as a basis set for density fun…

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Density fitting (DF), also known as the resolution of the identity (RI), is a widely used technique in quantum chemical calculations with various types of atomic basis sets - Gaussian-type orbitals, Slater-type orbitals, as well as…

Chemical Physics · Physics 2021-12-22 Susi Lehtola

Multiscale and multiphysics problems need novel numerical methods in order for them to be solved correctly and predictively. To that end, we develop a wavelet based technique to solve a coupled system of nonlinear partial differential…

Numerical Analysis · Mathematics 2023-03-22 Cale Harnish , Luke Dalessandro , Karel Matous , Daniel Livescu

Electronic structure methods for accurate calculation of molecular properties have a high cost that grows steeply with the problem size, therefore, it is helpful to have the underlying atomic basis functions that are less in number but of…

Chemical Physics · Physics 2019-03-15 Dimitri N. Laikov

We introduce an energy functional for ground-state electronic structure calculations. Its variables are the natural spin-orbitals of singlet many-body wave functions and their joint occupation probabilities deriving from controlled…

Chemical Physics · Physics 2016-12-04 Ralph Gebauer , Morrel H. Cohen , Roberto Car

The perovskite oxides are known to be susceptible to structural distortions over a long wavelength when compared to their parent cubic structures. From an ab initio simulation perspective, this requires accurate calculations including many…

Computational Physics · Physics 2022-02-16 Jack S. Baker , Tsuyoshi Miyazki , David R. Bowler

Discrete mixture models are one of the most successful approaches for density estimation. Under a Bayesian nonparametric framework, Dirichlet process location-scale mixture of Gaussian kernels is the golden standard, both having nice…

Methodology · Statistics 2013-12-02 Antonio Canale , Bruno Scarpa

A versatile method for combining density functional theory (DFT) in the local density approximation (LDA) with dynamical mean-field theory (DMFT) is presented. Starting from a general basis-independent formulation, we use Wannier functions…

Strongly Correlated Electrons · Physics 2009-11-11 F. Lechermann , A. Georges , A. Poteryaev , S. Biermann , M. Posternak , A. Yamasaki , O. K. Andersen

We present model-assisted density fitting (MADF) basis set generator, an algorithm for generating primitive atomic Gaussian density fitting (DF) basis sets (DFBSs) from a contracted Gaussian orbital basis set (OBS). The MADF algorithm…

Chemical Physics · Physics 2025-10-14 Kshitijkumar A. Surjuse , Edward F. Valeev

We introduce an acceleration algorithm for coulomb gauge fixing, using the compactly supported wavelets introduced by Daubechies. The algorithm is similar to Fourier acceleration. Our provisional numerical results for $SU(3)$ on $8^{4}$…

High Energy Physics - Lattice · Physics 2009-10-22 Terrence Draper , Craig McNeile

Moving beyond traditional 2D materials is now desirable to have switching capabilities (e.g., transistors). Here we propose using borophene because, as we will show in this letter, obtaining regions of the electronic bandstructure which act…

Materials Science · Physics 2020-12-15 Clifford M. Krowne , Xianwei Sha

This paper presents a new family of localized orthonormal bases - sinlets - which are well suited for both signal and image processing and analysis. One-dimensional sinlets are related to specific solutions of the time-dependent harmonic…

Multimedia · Computer Science 2012-09-19 Alexander Y. Davydov

The LDA+DMFT method is a very powerful tool for gaining insight into the physics of strongly correlated materials. It combines traditional ab-initio density-functional techniques with the dynamical mean-field theory. The core aspects of the…

Strongly Correlated Electrons · Physics 2017-11-22 Eva Pavarini

Faithful representations of atomic environments and general models for regression can be harnessed to learn electron densities that are close to the ground state. One of the applications of data-derived electron densities is to orbital-free…

Materials Science · Physics 2019-03-01 Andrew T. Fowler , Chris J. Pickard , James A. Elliott

The decomposition of an image into a linear combination of digitised basis functions is an everyday task in astronomy. A general method is presented for performing such a decomposition optimally into an arbitrary set of digitised basis…

Astrophysics · Physics 2009-11-10 R. H. Berry , M. P. Hobson , S. Withington

The description of weakly bound electronic states is especially difficult with atomic orbital basis sets. The diffuse atomic basis functions that are necessary to describe the extended electronic state generate significant linear…

Chemical Physics · Physics 2019-12-30 Susi Lehtola

Density-functional perturbation theory (DFPT) is nowadays the method of choice for the accurate computation of linear and non-linear response properties of materials from first principles. A notable advantage of DFPT over alternative…

Materials Science · Physics 2019-06-19 Miquel Royo , Massimiliano Stengel

The increasing use of high-throughput density-functional theory (DFT) calculations in the computational design and optimization of materials requires the availability of a comprehensive set of soft and transferable pseudopotentials. Here we…

Materials Science · Physics 2013-12-10 Kevin F. Garrity , Joseph W. Bennett , Karin M. Rabe , David Vanderbilt

In the framework of a recently reported linear-scaling method for density-functional-pseudopotential calculations, we investigate the use of localized basis functions for such work. We propose a basis set in which each local orbital is…

mtrl-th · Physics 2009-10-30 E. Hernandez , M. J. Gillan , C. M. Goringe

Kinetic energy functionals of the electronic density are used to model large systems in the context of density functional theory, without the need to obtain electronic wavefunctions. We discuss the problems associated with the application…

Condensed Matter · Physics 2009-11-07 Nicholas Choly , Efthimios Kaxiras

We introduce a new family of multivariate wavelets which are obtained by "polyharmonic subdivision". They generalize directly the original compactly supported Daubechies wavelets.

Numerical Analysis · Mathematics 2010-06-08 Ognyan Kounchev , Damyan Kalaglarsky