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We have applied the Finite Element Method to the self-consistent electronic structure calculations of molecules and solids for the first time. In this approach all the calculations are performed in "real space" and the use of non-uniform…

mtrl-th · Physics 2009-10-28 Eiji Tsuchida , Masaru Tsukada

We present the implementation of a variational finite element solver in the HelFEM program for benchmark calculations on diatomic systems. A basis set of the form $\chi_{nlm}(\mu,\nu,\phi)=B_{n}(\mu)Y_{l}^{m}(\nu,\phi)$ is used, where…

Chemical Physics · Physics 2019-08-19 Susi Lehtola

We develop a computational workflow for high-throughput Wannierization of density functional theory (DFT) based electronic band structure calculations. We apply this workflow to 1771 materials, and we create a database with the resulting…

Materials Science · Physics 2020-07-03 Kevin F. Garrity , Kamal Choudhary

Localized basis sets in the projector augmented wave formalism allow for computationally efficient calculations within density functional theory (DFT). However, achieving high numerical accuracy requires an extensive basis set, which also…

Materials Science · Physics 2020-11-18 G. Gandus , A. Valli , D. Passerone , R. Stadler

Multiresolution analysis of electronic structure affords the opportunity to capture the full physics of atomic cores in a systematically improvable manner. Applying new techniques, we demonstrate for the first time that multiresolution…

Condensed Matter · Physics 2009-11-07 Torkel D. Engeness , T. A. Arias

Structure factors obtained from diffraction experiments are one of the most important quantities for characterizing the electronic and structural properties of materials. Methods for calculating this quantity from plane-wave density…

Materials Science · Physics 2022-09-27 Benjamin X. Shi , Rebecca J. Nicholls , Jonathan R. Yates

In this work, we present a computationally efficient methodology that utilizes a local real-space formulation of the projector augmented wave (PAW) method discretized with a finite-element (FE) basis to enable accurate and large-scale…

Computational Physics · Physics 2025-01-03 Kartick Ramakrishnan , Sambit Das , Phani Motamarri

A degenerate perturbation $k\cdot p$ approach for effective mass calculations is implemented in the all-electron density functional theory (DFT) package WIEN2k. The accuracy is tested on major group IVA, IIIA-VA, and IIB-VIA semiconductor…

Materials Science · Physics 2022-01-06 Oleg Rubel , Fabien Tran , Xavier Rocquefelte , Peter Blaha

We introduce one- and two-dimensional `exponential shapelets': orthonormal basis functions that efficiently model isolated features in data. They are built from eigenfunctions of the quantum mechanical hydrogen atom, and inherit mathematics…

Instrumentation and Methods for Astrophysics · Physics 2019-03-27 Joel Bergé , Richard Massey , Quentin Baghi , Pierre Touboul

We propose a class of spherical wavelet bases for the analysis of geophysical models and forthe tomographic inversion of global seismic data. Its multiresolution character allows for modeling with an effective spatial resolution that varies…

A set of orthogonal polynomials on the unit disk $B(0,1)$ known as Zernike polynomials are commonly used in the analysis and evaluation of optical systems. Here Zernike polynomials are used to construct wavelets for polynomial subspaces of…

Functional Analysis · Mathematics 2025-07-24 Somantika Datta , Kanti B. Datta

We present a new adaptive method for electronic structure calculations based on novel fast algorithms for reduction of multivariate mixtures. In our calculations, spatial orbitals are maintained as Gaussian mixtures whose terms are selected…

Numerical Analysis · Mathematics 2019-06-19 Gregory Beylkin , Lucas Monzon , Xinshuo Yang

In recent years, "composite" density-functional-theory-based methods comprising specially optimized combinations of functionals, basis sets, and empirical corrections have become widely used owing to their robustness and computational…

Chemical Physics · Physics 2024-11-21 Corin C. Wagen , Jonathon E. Vandezande

We derive an analytic connection between the screened self-consistent effective potential from density functional theory (DFT) and atomic effective pseudopotentials (AEPs). The motivation to derive AEPs is to address structures with…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 J. R. Cárdenas , G. Bester

We discuss efficient algorithms for the accurate forward and reverse evaluation of the discrete Fourier-Bessel transform (dFBT) as numerical tools to assist in the 2D polar convolution of two radially symmetric functions, relevant, e.g., to…

Computational Physics · Physics 2016-11-08 O. Melchert , M. Wollweber , B. Roth

Combination of deep learning and ab initio calculation has shown great promise in revolutionizing future scientific research, but how to design neural network models incorporating a priori knowledge and symmetry requirements is a key…

Computational Physics · Physics 2023-06-12 Xiaoxun Gong , He Li , Nianlong Zou , Runzhang Xu , Wenhui Duan , Yong Xu

The performance of basis sets made of numerical atomic orbitals is explored in density-functional calculations of solids and molecules. With the aim of optimizing basis quality while maintaining strict localization of the orbitals, as…

Materials Science · Physics 2009-11-07 Javier Junquera , Oscar Paz , Daniel Sanchez-Portal , Emilio Artacho

Electronic structure calculations are mostly carried out with Coulomb potential singularity adapted basis sets like STO or contracted GTO. With other basis or for heavy elements the pseudopotentials may appear as a practical alternative.…

Chemical Physics · Physics 2022-11-14 Tommi Höynälänmaa , Tapio Rantala

We introduce $\Psi \mathrm{ec}$, a discretization of Cartan's exterior calculus of differential forms using wavelets. Our construction consists of differential $r$-form wavelets with flexible directional localization that provide tight…

Numerical Analysis · Computer Science 2020-10-27 Christian Lessig

In wavelet based electron structure calculations introducing a new, finer resolution level is usually an expensive task, this is why often a two-level approximation is used with very fine starting resolution level. This process results in…

Quantum Physics · Physics 2016-01-20 Szilvia Nagy , János Pipek
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