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The Interest in polycyclic aromatic hydrocarbons (PAHs) spans numerous fields and infrared spectroscopy is usually the method of choice to disentangle their molecular structure. In order to compute vibrational frequencies, numerous…

Chemical Physics · Physics 2021-05-18 Gaétan Laurens , Malalatiana Rabary , Julien Lam , Daniel Peláez , Abdul-Rahman Allouche

The JWST will deliver large data sets of high-quality spectral data over the 0.6-28 $\mu$m range. It will combine sensitivity, spectral and spatial resolution. Specific tools are required to provide efficient scientific analysis of such…

Astrophysics of Galaxies · Physics 2019-12-11 Sacha Foschino , Olivier Berné , Christine Joblin

We present a charge distribution-based emission model that calculates the infrared spectrum of fullerenes (C$_{60}$). Analysis of the modelled spectrum of C$_{60}$ in various charge states shows that the relative intensity of the features…

Astrophysics of Galaxies · Physics 2023-04-25 Ameek Sidhu , A. G. G. M. Tielens , Els Peeters , Jan Cami

We present 5--14~$\mu$m spectra at two different positions across the Orion Bar photodissociation region (PDR) obtained with the Infrared Spectrograph onboard the Spitzer Space Telescope and 3.3~$\mu$m PAH observations obtained with the…

Astrophysics of Galaxies · Physics 2021-11-03 C. Knight , E. Peeters , A. G. G. M. Tielens , W. D. Vacca

Long-slit 8-13 um spectroscopy of the nebula around NGC 1333 SVS reveals spatial variations in the strength and shape of emission features which are probably produced by polycyclic aromatic hydrocarbons (PAHs). Close to SVS 3, the 11.2 um…

Astrophysics · Physics 2009-10-31 G. C. Sloan , T. L. Hayward , L. J. Allamandola , J. D. Bregman , B. DeVito , D. M. Hudgins

The aromatic features in M101 were studied spectroscopically and photometrically using observations from all three instruments on the Spitzer Space Telescope. The global SED of M101 shows strong aromatic feature (commonly called PAH…

Potential vibrational modes associated with diffuse interstellar bands (DIBs) could be discerned by examining energy differences between correlated DIBs. Consequently, $\approx 10^3$ higher correlated DIB pairs ($r-\sigma_r \ge 0.8$, $\ge…

The generation of infrared (IR) radiation and the observed IR intensity distribution at wavelengths of 8, 24, and 100 micron in the ionized hydrogen region around a young, massive star is investigated. The evolution of the HII region is…

Astrophysics of Galaxies · Physics 2015-06-16 Yaroslav Pavlyuchenkov , Maria Kirsanova , Dmitry Wiebe

Previous as well as recent observations by ISO, Spitzer, AKARI, SOFIA, JWST etc. have revealed various characteristics of mid-infrared emission bands between 3-20 micron. Subsequently, several forms of organics including Polycylic Aromatic…

Astrophysics of Galaxies · Physics 2025-03-12 Mridusmita Buragohain , Takashi Onaka , Amit Pathak , Akant Vats , Itsuki Sakon

The coexistence of a large variety of molecular species (i.e., aromatic, cycloaliphatic and aliphatic) in several astrophysical environments suggests that unidentified IR emission (UIE) occurs from small solid particles containing a mix of…

Solar and Stellar Astrophysics · Physics 2015-06-12 F. Cataldo , D. A. Garcia-Hernandez , A. Manchado

We design and train a neural network (NN) model to efficiently predict the infrared spectra of interstellar polycyclic aromatic hydrocarbons (PAHs) with a computational cost many orders of magnitude lower than what a first-principles…

Astrophysics of Galaxies · Physics 2020-10-20 Peter Kovacs , Xiaosi Zhu , Jesus Carrete , Georg K. H. Madsen , Zhao Wang

A novel theoretical method is developed to study the polycyclic aromatic hydrocarbon - diffuse interstellar band (PAH-DIB) hypothesis. In this method, a computer program is used to enumerate all PAH molecules with up to a specific number of…

Astrophysics · Physics 2007-05-23 Xiaofeng Tan

A gas-phase optical spectrum of a large polycyclic aromatic hydrocarbon (PAH) cation - C78H26 +- in the 410-610 nm range is presented. This large all-benzenoid PAH should be large enough to be stable with respect to photodissociation in the…

Instrumentation and Methods for Astrophysics · Physics 2015-12-04 Junfeng Zhen , Giacomo Mulas , Anthony Bonnamy , Christine Joblin

We present spectra of a sample of Herbig Ae and Be (HAeBe) stars obtained with the Infrared Spectrograph on the Spitzer Space Telescope. All but one of the Herbig stars show emission from polycyclic aromatic hydrocarbons (PAHs) and seven of…

The detection of a new 16.4 micron emission feature in the ISO-SWS spectra of NGC 7023, M17, and the Orion Bar is reported. Previous laboratory experiments measured a mode near this wavelength in spectra of PAHs (Polycyclic Aromatic…

Astrophysics · Physics 2007-05-23 C. Moutou , L. Verstraete , A. Leger , K. Sellgren , W. Schmidt

We present 14--21 um emission spectra of star forming regions and compare them with the PAH spectra from the Ames PAH database. We show that while the emission in this region can be quite variable, the bulk of these variations can be…

Astrophysics · Physics 2007-05-23 E. Peeters , A. L. Mattioda , F. Kemper , D. M. Hudgins , L. J. Allamandola

Using data obtained by the DIRBE and FIRAS instruments on the COBE spacecraft we present the mean 3.5-1000 um dust spectrum from the high latitude cirrus clouds. These data represent the most comprehensive wavelength coverage of dust…

Astrophysics · Physics 2009-10-28 E. Dwek

Two ultracompact H II regions (IRAS 19181+1349 and 20178+4046) and one compact molecular clump (20286+4105) have been observed at far infrared wavelengths using the TIFR 1 m balloon-borne telescope and at mid infrared wavelengths using ISO.…

Astrophysics · Physics 2009-11-07 R. P. Verma , S. K. Ghosh , B. Mookerjea , T. N. Rengarajan

We present the results of mid-infrared N-band spectroscopy of the Herbig Ae/Be system MWC1080 using the Cooled Mid-Infrared Camera and Spectrometer (COMICS) on board the 8m Subaru Telescope. The MWC1080 has a geometry such that the diffuse…

Photodissociation regions (PDRs) exhibit emission between 3-20 um known as the Aromatic Infrared Bands (AIBs), originating from small carbonaceous species such as polycyclic aromatic hydrocarbons (PAHs). The AIB spectra observed in Galactic…