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We investigate the emission properties of polycyclic aromatic hydrocarbons (PAHs) in various metallicity environments with the Infrared Spectrograph on board Spitzer. Local giant HII regions are used as references as they enable access to…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-20 V. Lebouteiller , J. Bernard-Salas , D. G. Whelan , B. Brandl , F. Galliano , V. Charmandaris , S. Madden , D. Kunth

Up to now, no laboratory-based study has investigated polycyclic aromatic hydrocarbon (PAH) species as potential carriers of both the diffuse interstellar bands (DIBs) and the 2175 A UV bump. We examined the proposed correlation between…

Astrophysics of Galaxies · Physics 2011-11-01 Mathias Steglich , Jordy Bouwman , Friedrich Huisken , Thomas Henning

Quantifying the effect of anharmonicity on the infrared spectrum of large molecules such as polycyclic aromatic hydrocarbons (PAHs) at high temperature is the focus of a number of theoretical and experimental studies, many of them motivated…

Chemical Physics · Physics 2019-06-19 Shubhadip Chakraborty , Giacomo Mulas , Karine Demyk , Christine Joblin

We present mid-infrared to optical properties of 22 representative irregular galaxies: 18 Im, 3 BCDs, and one Sm. The mid-IR is based on images from the Spitzer Space Telescope archives. The 3.6 and 4.5 micron bands and the UBVJHK images…

Astrophysics · Physics 2008-11-26 Deidre A. Hunter , Bruce G. Elmegreen , Emily Martin

Polycyclic Aromatic Hydrocarbon (PAH) molecules have been long adjudged to contribute to the frequently detected distinct emission features at 3.3, 6.2, 7.7, 8.6, 11.2 and 12.7 {\mu}m with weaker and blended features distributed in the 3-20…

Astrophysics of Galaxies · Physics 2020-03-25 Mridusmita Buragohain , Amit Pathak , Itsuki Sakon , Takashi Onaka

Ratios of polycyclic aromatic hydrocarbon (PAH) vibrational bands are a promising tool for measuring the properties of the PAH population and their effect on star formation. The photometric bands of the MIRI and NIRCam instruments on JWST…

Studying the anharmonicity in the infrared (IR) spectra of polycyclic aromatic hydrocarbons (PAHs) at elevated temperatures is important to understand vibrational features and chemical properties of interstellar dust, especially in the…

Polycyclic aromatic hydrocarbon (PAH) emission has been found in both starbursts and modestly starforming galaxies, but the relation between starforming activity and PAH luminosity is still a matter of debate. The different correlation…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-14 Martin Haas , Christian Leipski , Ralf Siebenmorgen , Helmut Meusinger , Holger Drass , Rolf Chini

Emission from a class of benzene-based molecules known as Polycyclic Aromatic Hydrocarbons (PAHs) dominates the infrared spectrum of star-forming regions. The observed emission appears to arise from the combined emission of numerous PAH…

Instrumentation and Methods for Astrophysics · Physics 2014-03-20 Kevin H. Knuth , Man Kit Tse , Joshua Choinsky , Haley A. Maunu , Duane F. Carbon

We combined mapping-mode mid-infrared Spitzer spectra with complementary infrared imaging to perform a spatially resolved study of polycyclic aromatic hydrocarbons (PAHs) emission from the central regions of 66 nearby galaxies, roughly…

Astrophysics of Galaxies · Physics 2022-12-13 Lulu Zhang , Luis C. Ho , Aigen Li

We present gas-phase InfraRed Multiple Photon Dissociation (IRMPD) spectroscopy of cationic phenanthrene, pyrene, and perylene over the 100$-$1700 cm$^{-1}$ (6-95 $\mu$m) spectral range. This range covers both local vibrational modes…

Chemical Physics · Physics 2022-09-28 Sandra D. Wiersma , Alessandra Candian , Joost M. Bakker , Annemieke Petrignani

We investigate the presence and properties of PAHs on the surface of circumstellar disks around Herbig Ae/Be stars by comparing the predictions of disk models with observations. We present results of a radiation transfer code for disks…

Astrophysics · Physics 2009-11-10 Emilie Habart , Antonella Natta , Endrik Krügel

Context. As revealed by high-resolution spectral investigations in the wavelength range between 300 and 400 nm, the interstellar extinction curve does not display any of the sharp electronic absorption bands that are characteristic for…

This work proposes deuteronated PAH (DPAH+ ) molecules as a potential carrier of the 4.4 and 4.65 {\mu}m mid infrared emission bands that have been observationally detected towards the Orion and M17 regions. Density Functional Theory…

Astrophysics of Galaxies · Physics 2017-11-28 Mridusmita Buragohain , Amit Pathak , Peter Sarre , Takashi Onaka , Itsuki Sakon

Aims. In this work we determine the effects of anharmonicity on the mid-infrared spectra of the linear polycyclic aromatic hydrocarbons (PAHs) naphthalene, anthracene, tetracene and pentacene recorded using the free electron laser FELIX.…

Astrophysics of Galaxies · Physics 2019-08-15 A. K. Lemmens , D. B. Rap , J. M. M. Thunnissen , C. J. Mackie , A. Candian , A. G. G. M. Tielens , A. M. Rijs , W. J. Buma

We introduce a novel model to spectroscopically constrain the mid-infrared (MIR) extinction/attenuation curve from 3--17 um, using Polycyclic Aromatic Hydrocarbon (PAH) emission drawn from an AKARI-Spitzer extragalactic cross-archival…

We present mid-infrared (MIR) spectra of HII regions within star-forming galaxies M83 and M33. Their emission features are compared with Galactic and extragalactic HII regions, HII-type galaxies, starburst galaxies, and Seyfert/LINER type…

Astrophysics of Galaxies · Physics 2018-10-17 A. Maragkoudakis , N. Ivkovich , E. Peeters , D. J. Stock , D. Hemachandra , A. G. G. M. Tielens

We extend the prediction of vibrational spectra to large sized polycyclic aromatic hydrocarbon (PAH) molecules comprising up to \sim 1500 carbon atoms by evaluating the efficiency of several computational chemistry methodologies. We employ…

We measure IRAC colors of extended emission in several fields covering a range of Galactic latitudes and longitudes outside of star forming regions. We determine the nature of the Galactic diffuse emission in Spitzer/IRAC images by…

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