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Polycyclic aromatic hydrocarbons (PAHs) are believed to be ubiquitous in the interstellar medium. Yet, to date no specific PAH molecule has been identified. In this paper, a new observational avenue is suggested to detect individual PAHs,…

Astrophysics of Galaxies · Physics 2015-08-21 Yacine Ali-Haïmoud

We investigate the mid-infrared (IR) emission in the Orion Bar photodissociation region, using archival photometric and spectroscopic observations from UKIRT, Spitzer, ISO, and SOFIA telescopes. Specifically, we consider flux densities of…

Astrophysics of Galaxies · Physics 2021-11-11 Maria S. Murga , Maria S. Kirsanova , Dmitry S. Wiebe , Paul A. Boley

Aromatic infrared bands (AIBs) are a set of broad emission bands at 3.3, 6.2, 7.7, 8.6, 11.2, and 12.7 $\mu$m, seen in the infrared spectra of most galaxies. With JWST, the 3.3 $\mu$m AIB can in principle be detected up to a redshift of…

Using the Mid-Infrared Spectrometer on board the Infrared Telescope in Space and the low-resolution grating spectrometer (PHT-S) on board the Infrared Space Observatory, we obtained 820 mid-infrared (5 to 12 $\mu$m) spectra of the diffuse…

Spitzer 'hidden' observations of the background are used to construct a catalog of 4,090 spectra and examine the signature of polycyclic aromatic hydrocarbon (PAH) molecules and their connection to extinction by dust. A strong positive…

Astrophysics of Galaxies · Physics 2024-11-04 Christiaan Boersma , Jesse D. Bregman , Louis J. Allamandola , Pasquale Temi , Alexandros Maragkoudakis

We present a quantitative model for the infrared emission from dust in the diffuse interstellar medium. The model consists of a mixture of amorphous silicate grains and carbonaceous grains, each with a wide size distribution ranging from…

Astrophysics · Physics 2008-11-26 Aigen Li , B. T. Draine

Utilizing the data and tools provided through the NASA Ames PAH IR Spectroscopic Database (PAHdb), we study the PAH component of over 900 Spitzer-IRS galaxy spectra. Employing a database-fitting approach, the average PAH size, the PAH size…

Astrophysics of Galaxies · Physics 2022-06-01 A. Maragkoudakis , C. Boersma , P. Temi , J. D. Bregman , L. J. Allamandola

The PAH model predicts many weak emission features in the 1-5 $\mu$m region that can resolve significant questions that it has faced since its inception in the mid-80s. These features contain fundamental information about the PAH population…

Astrophysics of Galaxies · Physics 2024-03-05 L. J. Allamandola , C. Boersma , T. J. Lee , J. D. Bregman , P. Temi

The study of the Aromatic Infrared Bands (AIBs) in astronomical environments has opened interesting spectroscopic questions on the effect of anharmonicity on the infrared (IR) spectrum of hot polycyclic aromatic hydrocarbons (PAHs) and…

Astrophysics of Galaxies · Physics 2021-05-19 Shubhadip Chakraborty , Giacomo Mulas , Mathias Rapacioli , Christine Joblin

The coexistence of PAHs and the C$_{60}$ fullerene in different astrophysical environments can give rise to the formation of new complex species denoted as PAH-C$_{60}$ adducts, which may contribute to the infrared (IR) emission observed.…

Infrared emission from polycyclic aromatic hydrocarbons (PAHs) play a major role in determining the charge balance of their host environments that include photo-dissociation regions (PDRs) in galaxies, planetary nebulae, and rims of…

Superhydrogenated polycyclic aromatic hydrocarbons (PAHs) may be present in H-rich and ultraviolet-poor benign regions. The addition of excess H atoms to PAHs converts the aromatic bonds into aliphatic bonds, the strongest of which falls…

Astrophysics of Galaxies · Physics 2020-03-04 X. J. Yang , Aigen Li , R. Glaser

We have obtained new STIS/HST spectra to search for structure in the ultraviolet interstellar extinction curve, with particular emphasis on a search for absorption features produced by polycyclic aromatic hydrocarbons (PAHs). The presence…

We present a new method to accurately describe the ionization fraction and the size distribution of polycyclic aromatic hydrocarbons (PAHs) within astrophysical sources. To this purpose, we have computed the mid-infrared emission spectra of…

Astrophysics of Galaxies · Physics 2020-03-18 A. Maragkoudakis , E. Peeters , A. Ricca

Polycyclic Aromatic Hydrocarbons (PAHs) are believed to be the small-size tail of the interstellar carbonaceous dust grain population. Their vibrational emission is the most widely accepted source of the aromatic near-infrared features, and…

Astrophysics of Galaxies · Physics 2015-08-21 Yacine Ali-Haïmoud , Laura Pérez , Ronald Maddalena , Anish Roshi

Using physical models, we study the sensitivity of polycyclic aromatic hydrocarbon (PAH) emission spectra to the character of the illuminating starlight, to the PAH size distribution, and to the PAH charge distribution. Starlight models…

Astrophysics of Galaxies · Physics 2025-04-07 B. T. Draine , Aigen Li , Brandon S. Hensley , L. K. Hunt , K. Sandstrom , J. -D. T. Smith

The search for large polycyclic aromatic hydrocarbons (PAHs) with over 100 carbon atoms is crucial to resolving the origin of unidentified infrared emission (UIE) bands. These bands are commonly observed in nebulae and the interstellar…

Astrophysics of Galaxies · Physics 2025-08-22 Yi Shao , Yong Zhang , Xu-Jia Ouyang , Chuan-Peng Zhang

We present the results of a computational study to investigate the infrared spectroscopic properties of a large number of polycyclic aromatic hydrocarbon (PAH) molecules and their fully dehydrogenated counterparts. We constructed a database…

Astrophysics of Galaxies · Physics 2015-06-23 C. J. Mackie , E. Peeters , C. W. Bauschlicher , J. Cami

The infrared (IR) emission from interstellar dust in the Small Magellanic Cloud (SMC) is modelled using a mixture of amorphous silicate and carbonaceous grains, including a population of polycyclic aromatic hydrocarbon (PAH) molecules. (1)…

Astrophysics · Physics 2014-10-13 Aigen Li , B. T. Draine

Interstellar polycyclic aromatic hydrocarbon (PAHs) are an important component of the interstellar medium of galaxies, containing some 10 percent of the elemental carbon. Their vibrational emission dominates the mid-infrared spectra of…

Astrophysics of Galaxies · Physics 2026-03-06 A. G. G. M. Tielens