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The prevalent scheme of a diffusion-mediated bimolecular reaction $A+B\rightarrow P$ is an adaptation of that proposed by Briggs and Haldane for enzyme action [{\em Biochem J.\/}, 19:338--339, 1925]. The purpose of this Note is to explain,…

Chemical Physics · Physics 2014-11-11 K. Razi Naqvi

On example of diffusion-limited reversible $A+A \rightleftharpoons B$ reactions we re-examine two fundamental concepts of classical chemical kinetics - the notion of "Chemical Equilibrium" and the "Law of Mass Action". We consider a general…

Statistical Mechanics · Physics 2009-11-11 R. Voituriez , M. Moreau , G. Oshanin

This paper is concerned with the existence and further properties of propagation speeds of transition fronts for bistable reaction-diffusion equations in exterior domains and in some domains with multiple cylindrical branches. In exterior…

Analysis of PDEs · Mathematics 2018-08-13 Hongjun Guo , Francois Hamel , Wei-Jie Sheng

Experiments on the diffusion-limited corrosion of porous copper clusters in thin gap cells containing cupric chloride are reported. By carefully comparing corrosion front velocities and concentration profiles obtained by phase-shift…

Chemical Physics · Physics 2007-05-23 C. Leger , F. Argoul , M. Z. Bazant

We introduce a phase-field model to describe the dynamics of a self-sustaining propagating combustion front within a medium of randomly distributed reactants. Numerical simulations of this model show that a flame front exists for reactant…

Condensed Matter · Physics 2009-10-22 N. Provatas , T. Ala-Nissila , Martin Grant , K. R. Elder , Luc Pich

Variation in genotypes may be responsible for differences in dispersal rates, directional biases, and growth rates of individuals. These traits may favor certain genotypes and enhance their spatio-temporal spreading into areas occupied by…

Analysis of PDEs · Mathematics 2016-07-05 Kollár Richard , Novak Sebastian

We investigate the probabilities of large deviations for the position of the front in a stochastic model of the reaction $X+Y \to 2X$ on the integer lattice in which $Y$ particles do not move while $X$ particles move as independent simple…

Probability · Mathematics 2008-07-16 Jean Bérard , Alejandro Ramírez

Reaction-diffusion equations are one of the most common mathematical models in the natural sciences and are used to model systems that combine reactions with diffusive motion. However, rather than normal diffusion, anomalous subdiffusion is…

Statistical Mechanics · Physics 2021-04-23 Amanda M Alexander , Sean D Lawley

Spatio-temporal dynamics of the evolution of population involving growth and diffusion processes can be modeled by class of partial diffusion equations (PDEs) known as reaction-diffusion systems. In this work, we developed a nonlinear…

Populations and Evolution · Quantitative Biology 2024-12-16 Preet Mishra , Sapna Ratan Shah , R. K. Brojen Singh

We describe a universal transition mechanism characterizing the passage to an annealed behavior and to a regime where the fluctuations about this behavior are Gaussian, for the long time asymptotics of the empirical average of the expected…

Probability · Mathematics 2007-07-04 Gerard Ben Arous , Stanislav Molchanov , Alejandro F. Ramirez

The solution h to the Fisher-KPP equation with a steep enough initial condition develops into a front moving at velocity 2, with logarithmic corrections to its position. In this paper we investigate the value h(c t, t) of the solution ahead…

Analysis of PDEs · Mathematics 2023-02-21 Éric Brunet

We study distributions $F$ on $[0,\infty)$ such that for some $T\le\infty$, $F^{*2}(x,x+T]\sim 2 F(x,x+T]$. The case $T=\infty$ corresponds to $F$ being subexponential, and our analysis shows that the properties for $T<\infty$ are, in fact,…

Probability · Mathematics 2013-03-20 S. Asmussen , S. Foss , D. Korshunov

The problem of velocity selection for reaction fronts has been intensively investigated, leading to the successful marginal stability approach for propagation into an unstable state. Because the front velocity is controlled by the leading…

Soft Condensed Matter · Physics 2009-10-31 Leonid Pechenik , Herbert Levine

In this work, we propose an asymptotic preserving scheme for a non-linear kinetic reaction-transport equation, in the regime of sharp interface. With a non-linear reaction term of KPP-type, a phenomenon of front propagation has been proved…

Numerical Analysis · Mathematics 2018-05-23 Hélène Hivert

One-dimensional reaction-diffusion models A+A -> 0, A+A -> A, and $A+B -> 0, where in the latter case like particles coagulate on encounters and move as clusters, are solved exactly with anisotropic hopping rates and assuming synchronous…

Condensed Matter · Physics 2011-10-26 Vladimir Privman , Antonio M. R. Cadilhe , M. Lawrence Glasser

We study travelling fronts of equations of the form $u_{tt} + \phi(u) u_x = u_{xx} + f(u)$. A criterion for the transition from linear to nonlinear marginal stability is established for positive functions $\phi(u)$ and for any reaction term…

Pattern Formation and Solitons · Physics 2009-11-07 R. D. Benguria , M. C. Depassier

We introduce a novel numerical method for direct simulation of front propagation in the Fisher-KPP equation with a time-dependent parameter on an infinite domain. The method computes a time-dependent boundary condition that accurately…

Fluid Dynamics · Physics 2026-02-12 Troy Tsubota , Smridhi Mahajan , Adrian van Kan , Edgar Knobloch

We consider a single-species diffusion-limited annihilation reaction with reactants confined to a two-dimensional surface with one arbitrarily large dimension and the other comparable in size to interparticle distances. This situation could…

Biomolecules · Quantitative Biology 2015-03-20 Aleksandr Kivenson , Michael F. Hagan

We develop a theory of reversible diffusion-controlled reactions with generalized binding/unbinding kinetics. In this framework, a diffusing particle can bind to the reactive substrate after a random number of arrivals onto it, with a given…

Chemical Physics · Physics 2023-10-03 Denis S. Grebenkov

We establish rigorous lower bounds on the speed of traveling fronts and on the bulk burning rate in reaction-diffusion equation with passive advection. The non-linearity is assumed to be of either KPP or ignition type. We consider two main…

Analysis of PDEs · Mathematics 2015-06-26 Alexander Kiselev , Leonid Ryzhik
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