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In this article we present a novel semi-analytical approach to calculate first-order electron-vibration coupling constants within the framework of density functional theory. It combines analytical expressions for the first-order derivative…

Mesoscale and Nanoscale Physics · Physics 2013-11-12 Marius Bürkle , Janne K. Viljas , Thomas J. Hellmuth , Elke Scheer , Florian Weigend , Gerd Schön , Fabian Pauly

Vibronic effects in resonant electron transport through single-molecule junctions are analyzed. The study is based on generic models for molecular junctions, which include electronic states on the molecular bridge that are vibrationally…

Mesoscale and Nanoscale Physics · Physics 2011-03-15 R. Härtle , M. Thoss

This paper reviews some selected approaches to the description of transport properties, mainly electroconductivity, in crystalline and disordered metallic systems. A detailed qualitative theoretical formulation of the electron transport…

Statistical Mechanics · Physics 2011-09-27 A. L. Kuzemsky

The influence of vibrational motion on electron conduction through single molecules bound to metal electrodes is investigated employing first-principles electronic-structure calculations and projection-operator Green's function methods.…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 C. Benesch , M. Thoss , W. Domcke , M. Cizek

Understanding electron transport processes in molecular wires connected between contacts is a central focus in the field of molecular electronics. Especially, the dephasing effect causing tunneling-to-hopping transition has great importance…

Mesoscale and Nanoscale Physics · Physics 2012-06-26 Daijiro Nozaki , Claudia Gomes da Rocha , Horacio M. Pastawski , Gianaurelio Cuniberti

A theoretical analysis of inelastic electron tunneling spectroscopy (IETS) experiments conducted on molecular junctions are presented, where the second derivative of the current with respect to voltage is usually plotted as a function of…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Kamil Walczak

We analyze various limits of vibrationally coupled resonant electron transport in single-molecule junctions. Based on a master equation approach, we discuss analytic and numerical results for junctions under a high bias voltage or weak…

Mesoscale and Nanoscale Physics · Physics 2015-03-18 R. Härtle , M. Thoss

We present a method to analyze the results of first-principles based calculations of electronic currents including inelastic electron-phonon effects. This method allows us to determine the electronic and vibrational symmeties in play, and…

Mesoscale and Nanoscale Physics · Physics 2008-06-11 Magnus Paulsson , Thomas Frederiksen , Hiromu Ueba , Nicolas Lorente , Mads Brandbyge

Electron coupling to intra- and inter-molecular vibrational modes is investigated in models appropriate to single crystal organic semiconductors, such as oligoacenes. Focus is on spectral and transport properties of these systems beyond…

Strongly Correlated Electrons · Physics 2015-05-28 C. A. Perroni , V. Marigliano Ramaglia , V. Cataudella

Solid state physics deals with systems composed of atoms with strongly bound electrons. The tunneling probability of each electron is determined by interactions that typically extend to neighboring sites, as their corresponding wave…

Materials Science · Physics 2019-11-27 F. Ramírez-Ramírez , E. Flores-Olmedo , G. Báez , E. Sadurní , R. ~A. Méndez-Sánchez

In the past decade, a new research frontier emerges at the interface between physics and renewable energy, termed as the inelastic thermoelectric effects where inelastic transport processes play a key role. The study of inelastic…

Mesoscale and Nanoscale Physics · Physics 2022-07-13 Rongqian Wang , Chen Wang , Jincheng Lu , Jian-Hua Jiang

In this paper we calculate and visualize the dynamics of an ensemble of electrons trapping in an electrostatic wave of slowly increasing amplitude, illustrating that, despite disordering of particles in angle during the trapping transition…

Plasma Physics · Physics 2009-01-29 R. L. Dewar , J. C. -C. Yap

Temperature dependent transport of disordered electronic systems is examined in the presence of strong correlations. In contrast to what is assumed in Fermi liquid approaches, finite temperature behavior in this regime proves largely…

Strongly Correlated Electrons · Physics 2007-05-23 M. C. O. Aguiar , E. Miranda , V. Dobrosavljevic , E. Abrahams , G. Kotliar

The effect of vibrational motion on resonant charge transport through single molecule junctions is investigated. The study is based on a combination of first-principles electronic structure calculations to characterize the system and…

Other Condensed Matter · Physics 2007-12-24 Claudia Benesch , Martin Cizek , Jiri Klimes , Michael Thoss , Wolfgang Domcke

We expand iterative numerically-exact influence functional path-integral tools and present a method capable of following the nonequilibrium time evolution of subsystems coupled to multiple bosonic and fermionic reservoirs simultaneously.…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 Lena Simine , Dvira Segal

The most fundamental approach to an understanding of electronic, optical, and transport phenomena which the condensed matter physics (of conventional as well as nonconventional systems) offers is generally founded on two experiments: the…

Mesoscale and Nanoscale Physics · Physics 2013-06-18 Manvir S. Kushwaha

The interaction between electronic and vibrational degrees of freedom is an important mechanism in nonequilibrium charge transport through molecular nanojunctions. While adiabatic polaron-type coupling has been studied in great detail, new…

Mesoscale and Nanoscale Physics · Physics 2022-06-10 Christoph Kaspar , André Erpenbeck , Jakob Bätge , Christian Schinabeck , Michael Thoss

We calculate non-perturbatively the inelastic effects on the conductance through a conjugated molecular wire-metal heterojunction, including realistic electron-phonon coupling. We show that at sub-band-gap energies the current is dominated…

Materials Science · Physics 2009-10-31 H. Ness , A. J. Fisher

In single-molecule transistors, we observe inelastic cotunneling features that correspond energetically to vibrational excitations of the molecule, as determined by Raman and infrared spectroscopy. This is a form of inelastic electron…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 L. H. Yu , Z. K. Keane , J. W. Ciszek , L. Cheng , M. P. Stewart , J. M. Tour , D. Natelson

Inelastic transport of electrons through a two-impurity chain is studied theoretically with account of intersite Coulomb interaction, U. Both limits of ohmic transport (at low bias) and strongly non-ohmic transport (at high bias) are…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 A. D. Ballard , M. E. Raikh