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The realization of $p$-type doping in wide-band-gap oxide semiconductors remains a major challenge, particularly in $\beta-Ga_2O_3$ where nitrogen has long been considered a potential acceptor dopant but has consistently failed to produce…

The work presents the electronic structure, spin state and optical properties of TM-dinuclear molecules (TM = Cr, Mn, Fe, Co, and Ni) which was modelled according to the recently reported Pt$^{II}$-dinuclear complex…

Materials Science · Physics 2019-12-19 Indukuru Ramesh Reddy , Kartick Tarafder

As the dimensions of electronic devices approach those of molecules, the size, geometry and chemical composition of the contact electrodes play increasingly dominant roles in device functions. It is shown here that single-walled carbon…

Materials Science · Physics 2007-05-23 Pengfei Qi , Ali Javey , Marco Rolandi , Qian Wang , Erhan Yenilmez , Hongjie Dai

Carrying out first-principles calculations, we study N-doped capped carbon nanotube (CNT) electrodes applied to DNA sequencing. While we obtain for the face-on nucleobase junction configurations a conventional conductance ordering where the…

Mesoscale and Nanoscale Physics · Physics 2014-07-10 Han Seul Kim , Seung Jin Lee , Yong-Hoon Kim

Impressive advances in the field of molecular spintronics allow one to study electron transport through individual magnetic molecules embedded between metallic leads in the purely quantum regime of single electron tunneling. Besides…

Strongly Correlated Electrons · Physics 2019-09-05 Alessandro Chiesa , Emilio Macaluso , Paolo Santini , Stefano Carretta , Eva Pavarini

Finding an effective and controllable way to create a sizable energy gap in graphene-based systems has been a challenging topic of intensive research. We propose that the hybrid of boron nitride and graphene (h-BNC) at low BN doping serves…

Mesoscale and Nanoscale Physics · Physics 2023-12-01 Chih-Piao Chuu , Wei-En Tseng , Kuan-Hung Liu , Ching-Ming Wei , Mei-Yin Chou

Nickel oxide is a versatile p-type semiconducting oxide with many applications in opto-electronic devices, but high doping concentrations are often required to achieve necessary electrical conductivity. In contrast to many other transparent…

{\it Ab initio} investigations of the full static dielectric response and Born effective charge of BN nanotubes (BN-NTs) have been performed for the first time using finite electric field method. It is found that the ionic contribution to…

Materials Science · Physics 2009-11-13 G. Y. Guo , S. Ishibashi , T. Tamura , K. Terakura

We investigate the molecular sensing properties of carbon nanotube-boron nitride-carbon nanotube (CNT-BN-CNT) junctions. We demonstrate that the electrical conductance of such a junction changes in response to the binding of an analyte…

Mesoscale and Nanoscale Physics · Physics 2016-01-05 Laith Algharagholy , Thomas Pope , Qusiy Al-Galiby , Hatef Sadeghi , Steve W. D. Bailey , Colin J. Lambert

We present ab initio calculations on the band structure and density of states of single wall semiconducting carbon nanotubes with high degrees (up to 25%) of B, Si and N substitution. The doping process consists of two phases: different…

Mesoscale and Nanoscale Physics · Physics 2015-01-13 E. Tetik

Rhombohedral B$_{12}$ unit is viewed as a host matrix embedding linear tri-atomic arrangements of elements (E) resulting in a relatively large family of boron-rich compounds with B$_{12}${E-E-E} generic formulation. The present work focuses…

Materials Science · Physics 2021-01-13 Samir F. Matar , Vladimir L. Solozhenko

Advanced theoretical investigations are crucial for understanding the structural growth mechanisms, optoelectronic properties, and photocatalytic activity of photoelectrodes for efficient photoelectrochemical water splitting. In this work,…

Materials Science · Physics 2025-03-24 Abdul Ahad Mamun , Muhammad Anisuzzaman Talukder

We present a computational microscopy analysis (targeted molecular dynamics simulations) of the structure and performance of conductive metal organic framework (MOF) electrodes in supercapacitors with room temperature ionic liquids. The…

Materials Science · Physics 2020-02-24 Sheng Bi , Ming Chen , Runxi Wang , Jiamao Feng , Mircea Dinca , Alexei A. Kornyshev , Guang Feng

Single-molecule biosensing, with a promise of being applied in protein and DNA sequencing, could be achieved using tunneling current approach. Electrode-molecule-electrode tunneling current critically depends on whether molecular levels…

Using density functional theory (DFT) based electronic structure calculations, the effects of morphology of semiconducting nano structures on the magnetic interaction between two magnetic dopant atoms as well as a possibility of tuning band…

Mesoscale and Nanoscale Physics · Physics 2015-12-29 Soumendu Datta , Gopi Chandra Kaphle , Sayan Baral , Abhijit Mookerjee

The electronic properties of pure and As-doped Si nanowires with radii up to 9.53 nm are studied using large scale density functional theory (DFT) calculations. We show that, for the undoped nanowires, the DFT bandgap reduces with…

Materials Science · Physics 2019-10-24 Chathurangi Kumarasinghe , David R. Bowler

We have synthesized a large amount of boron-doped multiwalled carbon nanotubes (MWNTs) by hot-filament chemical vapor deposition. The synthesis was carried out in a flask using a methanol solution of boric acid as a source material. The…

Materials Science · Physics 2015-05-13 S. Ishii , M. Nagao , T. Watanabe , S. Tsuda , T. Yamaguchi , Y. Takano

Phosphorene is a promising single elemental two-dimensional layered semiconductor with huge potential for future nanoelectronics and spintronics applications. In this work, we investigated the effect of an organic molecule (benzene) in the…

Mesoscale and Nanoscale Physics · Physics 2019-07-09 A. Chaudhury , S. Majumder , S. J. Ray

Interaction of single-walled carbon nanotubes with electron donor and acceptor molecules causes significant changes in the electronic and Raman spectra, the relative proportion of the metallic species increasing on electron donation through…

Materials Science · Physics 2008-05-29 Rakesh Voggu , Chandra Sekhar Rout , Aaron D. Franklin , Timothy S. Fisher , C. N. R. Rao

To be practical, semiconductors need to be doped. Sometimes, to nearly degenerate levels, e.g. in applications such as thermoelectric, transparent electronics or power electronics. However, many materials with finite band gaps are not…