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Although nonequilibrium work and fluctuation relations have been studied in detail within classical statistical physics, extending these results to open quantum systems has proven to be conceptually difficult. For systems that undergo…

Thermodynamics allows the application of Statistical Mechanics to finite and even small systems. As surface effects cannot be scaled away, one has to be careful with the standard arguments of splitting a system into two or bringing two…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

We consider in this paper, a few important issues in non-equilibrium work fluctuations and their relations to equilibrium free energies. First we show that Jarzynski identity can be viewed as a cumulant expansion of work. For a switching…

Statistical Mechanics · Physics 2015-05-20 M Suman Kalyan , G Anjan Prasad , V S S Sastry , K P N Murthy

Thermodynamic uncertainty principles make up one of the few rare anchors in the largely uncharted waters of nonequilibrium systems, the fluctuation theorems being the more familiar. In this work we aim to trace the uncertainties of…

Statistical Mechanics · Physics 2022-08-02 Hang Dong , Daniel Reiche , Jen-Tsung Hsiang , Bei-Lok Hu

Thermalization of isolated quantum systems has been studied intensively in recent years and significant progresses have been achieved. Here, we study thermalization of small quantum systems that interact with large chaotic environments…

Statistical Mechanics · Physics 2019-06-05 Jiaozi Wang , Wen-ge Wang , Jiao Wang

Quantum dynamics controlled by a time-dependent coupling constant are studied. It is proven that an energy eigenstate expectation value of work done by the system in a quench process cannot exceed the work in the corresponding quasi-static…

Statistical Mechanics · Physics 2020-09-04 C. Itoi , M. Amano

Constructing optimal thermodynamic processes in quantum systems relies on managing the balance between the average excess work and its stochastic fluctuations. Recently it has been shown that two different quantum generalisations of…

Quantum Physics · Physics 2021-12-06 Mohammad Mehboudi , Harry J. D. Miller

We prove the second law of thermodynamics and the nonequilibirum fluctuation theorem for pure quantum states.The entire system obeys reversible unitary dynamics, where the initial state of the heat bath is not the canonical distribution but…

Statistical Mechanics · Physics 2017-09-13 Eiki Iyoda , Kazuya Kaneko , Takahiro Sagawa

It is usually expected and observed that non-integrable isolated quantum systems thermalize. However, for some non-integrable spin chain models, in a numerical study, initial states with oscillations that persisted for some time were found…

Quantum Physics · Physics 2024-09-10 Luis Fernando dos Prazeres , Thiago R. de Oliveira

In the classical limit no work is needed to couple a system to a bath with sufficiently weak coupling strength (or with arbitrarily finite coupling strength for a linear system) at the same temperature. In the quantum domain this may be…

Quantum Physics · Physics 2009-11-13 Ilki Kim , Guenter Mahler

We review a series of experimental studies of the thermodynamics of nonequilibrium processes at the microscale. In particular, in these experiments we studied the fluctuations of the thermodynamic properties of a single optically-trapped…

Statistical Mechanics · Physics 2016-06-22 L. Dinis , I. A. Martínez , É. Roldán , J. M. R. Parrondo , R. A. Rica

In this work, we numerically verify the Jarzynski equality and Crook fluctuation theorem for a Brownian particle diffusing in a heterogeneous thermal bath and hence having a non-Gaussian position distribution. We use the…

Statistical Mechanics · Physics 2026-03-05 A. Saravanan , I. Iyyappan

The second law of thermodynamics states that entropy production in macroscopic systems is non-negative, reaching zero only at thermodynamic equilibrium. As a corollary, this implies that the state trajectory of macroscopic systems is…

Statistical Mechanics · Physics 2025-01-30 O. Politano , Alejandro L. Garcia , F. Baras , M. Malek Mansour

Fluctuation theorems are a generalization of thermodynamics on small scales and provide the tools to characterize the fluctuations of thermodynamic quantities in non-equilibrium nanoscale systems. They are particularly important for…

Statistical Mechanics · Physics 2014-04-03 Jan Gieseler , Romain Quidant , Christoph Dellago , Lukas Novotny

New exact results about the nonequilibrium thermodynamics of open quantum systems at arbitrary timescales are obtained by considering all possible variations of initial conditions of a system, its environment, and correlations between them.…

Statistical Mechanics · Physics 2021-05-05 Paul M. Riechers , Mile Gu

We present the stochastic thermodynamics analysis of an open quantum system weakly coupled to multiple reservoirs and driven by a rapidly oscillating external field. The analysis is built on a modified stochastic master equation in the…

Statistical Mechanics · Physics 2015-05-12 Gregory Bulnes Cuetara , Andreas Engel , Massimiliano Esposito

Fluctuations are significant in mesoscopic systems and of particular importance in understanding quantum transport. Here, we show that fluctuations can be considered as a resource for the operations of open quantum systems as functional…

Mesoscale and Nanoscale Physics · Physics 2020-09-16 Jincheng Lu , Rongqian Wang , Chen Wang , Jian-Hua Jiang

We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open…

Quantum Physics · Physics 2022-05-31 Alessandra Colla , Heinz-Peter Breuer

Quantum thermodynamics allows for the interconversion of quantum coherence and mechanical work. Quantum coherence is thus a potential physical resource for quantum machines. However, formulating a general nonequilibrium thermodynamics of…

Quantum Physics · Physics 2025-11-05 Franklin L. S. Rodrigues , Eric Lutz

We investigate how to minimize the work dissipated during nonequilibrium processes. To this end, we employ methods from linear response theory to describe slowly varying processes, i.e., processes operating within the linear regime around…

Statistical Mechanics · Physics 2014-07-03 Marcus V. S. Bonança , Sebastian Deffner