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Thermodynamics constrains changes to the energy of a system, both deliberate and random, via its first and second laws. When the system is not in equilibrium, fluctuation theorems such as the Jarzynski equality further restrict the…

We study the notion of work fluctuations in quantum field theory, highlighting that the most common definitions used in finite-dimensional quantum systems cannot be applied to quantum field theory (QFT). Then we propose work distributions…

Quantum Physics · Physics 2020-11-20 Adam Teixidó-Bonfill , Alvaro Ortega , Eduardo Martín-Martínez

We consider an isothermal machine composed of two Brownian particles (say particle A and B) connected by a harmonic spring. A constant load is attached to particle A, and the particle B is trapped in a harmonic confinement whose minimum is…

Statistical Mechanics · Physics 2018-08-01 Deepak Gupta

Diffusive motion in an externally driven potential is considered. It is shown that the distribution of work required to drive the system from an initial equilibrium state to another is Gaussian for slow but finite driving. Our result is…

Statistical Mechanics · Physics 2007-05-23 Thomas Speck , Udo Seifert

In a macroscopic (quantum or classical) Hamiltonian system, we prove the second law of thermodynamics in the forms of the minimum work principle and the law of entropy increase, under the assumption that the initial state is described by a…

Statistical Mechanics · Physics 2007-05-23 Hal Tasaki

The principle of microscopic reversibility is a fundamental element in the formulation of fluctuation relations and the Onsager reciprocal relations. As such, a clear description of whether and how this principle is adapted to the quantum…

Quantum Physics · Physics 2023-10-25 K. Khan , W. F. Magalhaes , Jailson S. Araujo , B. de Lima Bernardo , Gabriel H. Aguilar

In this report I discuss fluctuation theorems and transient violations of the second law of thermodynamics in small systems. Special emphasis is placed on free-energy recovery methods in the framework of non-equilibrium single-molecule…

Statistical Mechanics · Physics 2015-06-24 F. Ritort

Fluctuation theorems are fundamental results in nonequilibrium thermodynamics beyond the linear response regime. Among these, the paradigmatic Tasaki-Crooks fluctuation theorem relates the statistics of the works done in a forward…

Statistical Mechanics · Physics 2024-06-19 Gianluca Francica , Luca Dell'Anna

The concept of work is basic for statistical thermodynamics. To gain a fuller understanding of work and its (quantum) features, it needs to be represented as an average of a fluctuating quantity. Here I focus on the work done between two…

Statistical Mechanics · Physics 2015-06-19 A. E. Allahverdyan

Almost all processes -- highly correlated, weakly correlated, or correlated not at all---exhibit statistical fluctuations. Often physical laws, such as the Second Law of Thermodynamics, address only typical realizations -- as highlighted by…

Statistical Mechanics · Physics 2016-09-09 James P. Crutchfield , Cina Aghamohammadi

We carefully examine the thermodynamic consequences of the repeated partial projection model for coupling a quantum system to an arbitrary series of environments under feedback control. This paper provides observational definitions of heat…

Quantum Physics · Physics 2017-02-01 David M. Rogers

Stochastic thermodynamics extends the notions and relations of classical thermodynamics to small systems that experience strong fluctuations. The definitions of work and heat and the microscopically reversible condition are two key concepts…

Statistical Mechanics · Physics 2019-07-23 Geng Li , Z. C. Tu

Two approaches are outlined to characterize the fluctuation behavior of work applied to a system by a slow change of a parameter. One approach uses the adiabatic theorems of quantum and classical mechanics, the other one is based on the…

Statistical Mechanics · Physics 2022-01-11 Juyeon Yi , Peter Talkner

When engineering microscopic machines, increasing efficiency can often come at a price of reduced reliability due to the impact of stochastic fluctuations. Here we develop a general method for performing multi-objective optimisation of…

Quantum Physics · Physics 2021-01-04 Harry J. D. Miller , Mohammad Mehboudi

The thermodynamic properties of quantum heat engines are stochastic owing to the presence of thermal and quantum fluctuations. We here experimentally investigate the efficiency and nonequilibrium entropy production statistics of a spin-1/2…

Quantum Physics · Physics 2021-04-29 Tobias Denzler , Jonas F. G. Santos , Eric Lutz , Roberto Serra

Characterizing fluctuations of work in coherent quantum systems is notoriously problematic. Here we reveal the ultimate source of the problem by proving that ($\mathfrak{A}$) energy conservation and ($\mathfrak{B}$) the Jarzynski…

Quantum Physics · Physics 2024-05-08 Karen V. Hovhannisyan , Alberto Imparato

The second law of thermodynamics tells us which state transformations are so statistically unlikely that they are effectively forbidden. Its original formulation, due to Clausius, states that "Heat can never pass from a colder to a warmer…

One of the most important goals in quantum thermodynamics is to demonstrate advantages of thermodynamic protocols over their classical counterparts. For that, it is necessary to (i) develop theoretical tools and experimental set-ups to deal…

Quantum Physics · Physics 2019-05-01 Elisa Bäumer , Matteo Lostaglio , Martí Perarnau-Llobet , Rui Sampaio

We study temperature fluctuations in mesoscopic $N$-body systems undergoing non-equilibrium processes from the perspective of stochastic thermodynamics. By introducing a stochastic differential equation, we describe the evolution of the…

Statistical Mechanics · Physics 2026-05-19 Zhaoyu Fei , Yu-Han Ma

The second law of thermodynamics posits that in closed macroscopic systems the rate of entropy production must be positive. However, small systems can exhibit negative entropy production over short timescales, seemingly in contradiction…

Quantum Gases · Physics 2023-08-08 Rama Sharma , Tapio P. Simula , Andrew J. Groszek