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We show that the conservation and the non-additivity of the information, together with the additivity of the entropy make the entropy increase in an isolated system. The collapse of the entangled quantum state offers an example of the…
The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…
We show that the collapse of the entangled quantum state makes the entropy increase in an isolated system. The second law of thermodynamics is thus proven in its most general form.
The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy…
We show that systems with negative specific heat can violate the zeroth law of thermodynamics. By both numerical simulations and by using exact expressions for free energy and microcanonical entropy it is shown that if two systems with the…
The Second Law of Thermodynamics states that the entropy of a closed system is non-decreasing. Discussing the Second Law in the quantum world poses new challenges and provides new opportunities, involving fundamental…
The entropy shows an unavoidable tendency of disorder in thermostatistics according to the second thermodynamics law. This provides a minimization entropy principle for quantum thermostatistics with the von Neumann entropy and nonextensive…
The second law of classical thermodynamics, based on the positivity of the entropy production, only holds for deterministic processes. Therefore the Second Law in stochastic quantum thermodynamics may not hold. By making a fundamental…
We study two small quantum systems coupled to the same reservoir which is in thermal equilibrium. By studying the particle density and the energy density in the two systems before and after they contact each other, we find that the two…
A version of the second law of thermodynamics states that one cannot lower the energy of an isolated system by a cyclic operation. We prove this law without introducing statistical ensembles and by resorting only to quantum mechanics. We…
Evidence implies that basic laws of thermodynamics must be tested by experiments. In this paper, an experiment is designed to measure the entropy of a system with at least one known (measurable) equation of state, especially the gas…
This pedagogical comment highlights three misconceptions concerning the usefulness of the concept of negative temperature; being derived from the usual, often termed Boltzmann, definition of entropy. First, both the Boltzmann and Gibbs…
It exists a large class of systems for which the traditional notion of extensivity breaks down. From experimental examples we induce two general hypothesis concerning such systems. In the first the existence of an internal coordinate system…
The recent experimental realization of exotic matter states in isolated quantum systems and the ensuing controversy about the existence of negative absolute temperatures demand a careful analysis of the conceptual foundations underlying…
We establish quantum thermodynamics for open quantum systems weakly coupled to their reservoirs when the system exhibits degeneracies. The first and second law of thermodynamics are derived, as well as a finite-time fluctuation theorem for…
This paper is the second part of a previous paper (Marquet, 2019) dealing with the need to define the entropy with an absolute way, by using the third law of thermodynamics. In this second part it is shown that there is a need and interest…
Entanglement is central both to the foundations of quantum theory and, as a novel resource, to quantum information science. The theory of entanglement establishes basic laws, such as the non-increase of entanglement under local operations,…
We investigate the validity of the generalized second law of thermodynamics, in the cosmological scenario where dark energy interacts with both dark matter and radiation. Calculating separately the entropy variation for each fluid component…
In black hole physics, the second law of thermodynamics is generally valid whether the black hole is a static or a non-static one. Considering the universe as a thermodynamical system the second law of black hole dynamics extends to the…
We consider the particle creation scenario in the dynamical Chern-Simons modified gravity in the presence of perfect fluid equation of state $p=(\gamma-1)\rho$. By assuming various modified entropies (Bekenstein, logarithmic, power law…