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Using the embedded-atom method, the structure of small copper clusters on Au(111) electrodes has been investigated both by static and dynamic calculations. By varying the size of roughly circular clusters, the edge energy per atom is…

Materials Science · Physics 2007-05-23 M. G. Del Popolo , E. P. M. Leiva , W. Schmickler

Density-functional theory based global geometry optimization is used to scrutinize the possibility of using endohedrally-doped hydrogenated Si clusters as building blocks for constructing highly magnetic materials. In contrast to the known…

Materials Science · Physics 2013-07-26 Dennis Palagin , Karsten Reuter

Our ab initio calculations of CO adsorption energies on low miller index (111), (100), stepped (211), and kinked (532) gold surfaces show a strong dependence on local coordination with a reduction in Au atom coordination leading to higher…

Materials Science · Physics 2009-11-13 F. Mehmood , A. Kara , T. S. Rahman , C. R. Henry

The dynamical response of metallic clusters up to $10^3$ atoms is investigated using the restricted molecular dynamics simulations scheme. Exemplarily, sodium like material is considered. Correlation functions are evaluated to investigate…

Atomic and Molecular Clusters · Physics 2015-05-28 Thomas Raitza , Heidi Reinholz , Igor Morozov , Gerd Röpke

This article describes the optical properties of nanostructures composed of silver particles embedded into a gold matrix. In previous studies these materials were shown to exhibit temperature dependent transitions to a highly conductive and…

\emph{Ab-initio} calculations were performed on the scheelite type MGeO$_4$ (M = Hf, and Zr) compounds which find wide range of applications such as in x-ray imaging. We have studied the high pressure structural stability, elastic…

Materials Science · Physics 2014-05-30 G. Shwetha , V. Kanchana , K. Ramesh Babu , G. Vaitheeswaran , M. C. Valsakumar

Composition, atomic structure, and electronic properties of TM$_x$Mg$_y$O$_z$ clusters (TM = Cr, Ni, Fe, Co, $x+y \leq 3$) at realistic temperature $T$ and partial oxygen pressure $p_{\textrm{O}_2}$ conditions are explored using the {\em ab…

We study the thermally activated oscillations, or capillary waves, of a neutral metal cluster within the liquid drop model. These deformations correspond to a surface roughness which we characterize by a single parameter $\Delta$. We derive…

Condensed Matter · Physics 2009-10-30 N. Pavloff , C. Schmit

C58 fullerenes were adsorbed onto room temperature Au(111) surface by low-energy (~6 eV) cluster ion beam deposition under ultrahigh vacuum conditions. The topographic and electronic properties of the deposits were monitored by means of…

The lowest-energy structure, distribution of isomers, and their molecular properties depend significantly on the geometry and temperature. The total energy computations under DFT methodology are typically carried out at zero temperature;…

Results from first principles density functional theory (DFT) calculations and classical molecular dynamics (CMD) simulations are presented on moire-corrugation of graphene (gr). We find that the moire-corrugated graphene could be…

Materials Science · Physics 2014-03-11 P. Süle

Atomically-thin magnetic crystals have been recently isolated experimentally, greatly expanding the family of two-dimensional materials. In this Article we present an extensive comparative analysis of the electronic and magnetic properties…

Strongly Correlated Electrons · Physics 2019-09-06 Guido Menichetti , Matteo Calandra , Marco Polini

The atomic and electronic structure of a set of proposed thin (1.6 nm in diameter) silicon/silica quantum nanodots and nanowires with narrow interface, as well as parent metastable silicon structures (1.2 nm in diameter), was studied in…

Non-fullerene acceptors (NFAs) are excellent light harvesters, yet the origin of such high optical extinction is not well understood. In this work, we investigate the absorption strength of NFAs by building a database of time-dependent…

Small clusters of the As/Sb-S/Se system that is of importance for simulation of elementary structure units of chalcogenide glasses are calculated using DFT technique. Different structures of As2Xn- and Sb2Xn- (X=S,Se) with proper hydrogen…

Materials Science · Physics 2015-04-02 V. Gurin , O. Shpotyuk , V. Boyko

Titanium-carbide molecular clusters are thought to form in the circumstellar envelopes (CSEs) of carbon-rich Asymptotic Giant Branch stars (AGBs) but, to date, their detection has remained elusive. To facilitate the astrophysical…

Astrophysics of Galaxies · Physics 2021-10-04 Sergio Gámez-Valenzuela , Julio A. Alonso , Gonzalo Santoro , José I. Martínez

The hyper-radial barrier strongly hinders formation of more than three clusters. We investigate how well the dominating cluster components in $^7$He and $^8$He, respectively can be described as $\alpha$+$n$+$^2n$ and $\alpha$+$^2n$+$^2n$,…

Nuclear Theory · Physics 2025-09-23 E. Garrido , A. S. Jensen

Molybdenum clusters, characterised by their unique structure and intriguing catalytic properties, have gained significant attention in recent years. In several existing studies density functional theory (DFT) methods have been used to find…

Materials Science · Physics 2023-10-03 Yao Wei , Lev Kantorovich

Analytical relationships for the surface and curvature energies of oblate and prolate semi-spheroidal atomic clusters have been obtained. By modifying the cluster shape from a spheroid to a semi-spheroid the most stable shape was changed…

Atomic and Molecular Clusters · Physics 2007-09-18 D. N. Poenaru , R. A. Gherghescu , A. V. Solov'yov , W. Greiner

First principles based DFT calculations performed to insight structural and electronic properties of Boron doped Magnesium atom decorated graphene sheet for application of hydrogen storage. The four H2 molecules stably binds magnesium atom…

Materials Science · Physics 2020-03-31 Baliram Lone